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Journal of Chinese Society for Corrosion and protection  2022, Vol. 42 Issue (5): 752-758    DOI: 10.11902/1005.4537.2021.246
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Effect of Heat Treatment Process on Corrosion Behavior of Super 13Cr Stainless Steel in CO2-Saturated Oilfield Formation Aqueous Solution
PAN Xin1, REN Ze2, LIAN Jingbao1, HE Chuan1, ZHENG Ping1, CHEN Xu1()
1.College of Petroleum Engineering, Liaoning Petrochemical University, Fushun 113001, China
2.Jining Operation Area, Shandong Operation and Maintenance Center, National Petroleum and Natural Gas Pipeline Network Group Co. Ltd., Jining 272000, China
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Abstract  

The corrosion behavior of super 13Cr stainless steel subjected to different heat treatment processes in CO2-saturated oilfield formation water was assessed by means of metallographic microscope, XRD, electrochemical experiment and slow strain rate tensile method. The results showed that reversed austenite appeared in the super 13Cr SS after tempering at 620 ℃. A secondary tempering treatment could result in the increment of the amount of reversed austenite. There exists a passivation interval on polarization curves in CO2-saturated oilfield formation solution for all the super 13Cr SSs after being subjected to different heat treatments. The tempering process could result in decrease in the corrosion resistance of super 13Cr SS, in the contrast, a secondary tempering could result in an enhancing effect. The corrosion resistance of super 13Cr SS was related to the content of reversed austenite. The oil-quenched 13Cr SS had the highest SCC sensitivity. The SCC mechanism of the quenched 13Cr SS, as well as the 13Cr SSs tempered at 550 and 690 ℃, respectively were all hydrogen induced cracking. The SCC sensitivity of 13Cr SSs after subjected to 620 ℃-tempering and 650 ℃+620 ℃ double-tempering, decreased due to the presence of reversed austenite, accordingly, the cracking mechanism was mixed fracture.
Key words:  super 13Cr stainless steel      heat treatment      oilfield formation solution      CO2 corrosion     
Received:  18 September 2021     
ZTFLH:  TG174  
Fund: "Chunhui" International Cooperation Project of the Ministry of Education and General Program of the Education Department of Liaoning(LJKZ0416)
Corresponding Authors:  CHEN Xu     E-mail:  cx0402@sina.com
About author:  CHEN Xu, E-mail: cx0402@sina.com
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Xin PAN
Ze REN
Jingbao LIAN
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Cite this article: 

PAN Xin, REN Ze, LIAN Jingbao, HE Chuan, ZHENG Ping, CHEN Xu. Effect of Heat Treatment Process on Corrosion Behavior of Super 13Cr Stainless Steel in CO2-Saturated Oilfield Formation Aqueous Solution. Journal of Chinese Society for Corrosion and protection, 2022, 42(5): 752-758.

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https://www.jcscp.org/EN/10.11902/1005.4537.2021.246     OR     https://www.jcscp.org/EN/Y2022/V42/I5/752

Sample numberHeat treatment condition
A1050 ℃×0.5 h oil cooling
B1050 ℃×0.5 h water cooling +550 ℃×6 h furnace cooled
C1050 ℃×0.5 h water cooling+620 ℃×6 h furnace cooled
D1050 ℃×0.5 h water cooling+690 ℃×6 h furnace cooled
E1050 ℃×0.5 h oil cooling+650 ℃×2 h furnace cooled+620 ℃×6 h furnace cooled
Table 1  Heat treatment processes of super 13Cr stainless steel
Fig.1  Diagram of sample size for SSRT (unit: mm)
Fig.2  Microstructure morphologies of super 13Cr stainless steel after heat treatments under the conditions of quenching (a), tempering at 550 ℃ (b), 620 ℃ (c) and 690 ℃ (d), and two-stage tempering (e)
Fig.3  XRD patterns of Super 13Cr stainless steel samples after heat treatments under different conditions
Fig.4  Polarization curves of various heat-treated super 13Cr stainless steel in CO2-saturated oilfield formation solution
Heat treatment conditionIp / μA·cm-2Ep / V
Quenching2.960.05
550 ℃-tempering4.47-0.04
620 ℃-tempering4.26-0.02
690 ℃-tempering4.52-0.12
Two-stage tempering3.890
Table 2  Fitting results of the polarization curves
Fig.5  Nyquist (a), Bode (b) plots of various heat-treated super 13Cr stainless steel in CO2-saturated oilfield formation solution and Equivalent circuit diagram (c)
Heat treatment conditionsRsΩ·cm-2RfΩ·cm-2CPEdlF·cm-2RctΩ·cm-2
quenching5.7329.409.74×10-66.38×104
550 ℃-tempering4.407.641.26×10-53.23×104
620 ℃-tempering4.7016.931.21×10-55.30×104
690 ℃-tempering4.523.221.79×10-52.69×104
Two-stage tempering5.3419.041.14×10-55.52×104
Table 3  EIS fitting results of super 13Cr stainless steel of various heat treatment
Fig.6  SSRT curves (a) and reductions of area and elongations (b) of various heat-treated super 13Cr stainless steel in CO2-saturated oilfield formation solution
Fig.7  SEM images of the main fractures and side fractures of super 13Cr stainless steel with heat treatments under the conditions of quenching (a1, a2), tempering at 550 ℃ (b1, b2), 620 ℃ (c1, c2) and 690 ℃ (d1, d2) and two-stage tempering (e1, e2)
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