Influence of DMF Modified TiO2 Film on the Photogenerated Cathodic Protection Behavior

doi:10.11902/1005.4537.2017.078

Journal of Chinese Society for Corrosion and protection

2018, Vol. 38

Issue (3): 289-295 DOI: 10.11902/1005.4537.2017.078

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Influence of DMF Modified TiO₂ Film on the Photogenerated Cathodic Protection Behavior

Ping QIU(

), Lianjie YANG, Yu SONG, Hongfei YANG

Beijing Key Laboratory of Failure, Corrosion and Protection of Oil/Gas Facilities, Department of Materials Science and Engineering, China University of Petroleum, Beijing 102249, China

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Abstract

TiO₂ film surface normally presents micro porous after annealing treatment, which is one of the key factors on restraining the application of photogenerated cathodic protection of it. This study has prepared DMF modified TiO₂ film by sol-gel and dip-coating method on the substrate of FTO glass. The influence of DMF on the corresponding film composition, microstructure and surface wettability are explored by XRD, Raman spectroscopy and SEM. The property of photo response and cathodic protection behavior of the film coupled with 316 stainless steel are studied under UV illumination. The results indicated that the addition of DMF has essentially improved the compact continuity of the TiO₂ film, which supplies effective inhibition on the corrosive ions migration to the substrate. And the modified film presents comparable photogenerated cathodic protection property to that of pure TiO₂ film.

Key words: photogenerated cathodic protection modified TiO₂ film stainless steel DMF

Received: 16 May 2017

ZTFLH:

TG174.41

Fund: Supported by National Natural Science Foundation of China (51301199) and Elite Young Researcher Foundation of China University of Petroleum (2462015YQ0602)

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Ping QIU, Lianjie YANG, Yu SONG, Hongfei YANG. Influence of DMF Modified TiO₂ Film on the Photogenerated Cathodic Protection Behavior. Journal of Chinese Society for Corrosion and protection, 2018, 38(3): 289-295.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2017.078 OR https://www.jcscp.org/EN/Y2018/V38/I3/289

Fig.1 XRD spectra of pure TiO₂ film and TiO₂ film with DMF addition after annealing treatment at 450 ℃ (a) and corresponding (101) diffraction peak fitting as Lorentzian distribution (b)

Fig.2 Raman spectra of pure TiO₂ film and TiO₂ film with DMF addition after annealing treatment at 450 ℃ (a) and corresponding Raman shift of 151 cm^-1 band (b)

Fig.3 Images of pure TiO₂ sol (a) and TiO₂ sol with DMF addition (b) after 4 h aging

Fig.4 SEM images of pure TiO₂ film (a) and TiO₂ film with DMF addition (b) after annealing treatment at 450 ℃

Fig.5 Contact angle images of pure TiO₂ film (a) and TiO₂ film with DMF addition (b) after annealing treatment at 450 ℃

Fig.6 Time dependences of open circuit potential of 316L SS coupled with pure TiO₂ film and TiO₂ film with DMF addition in 3.5%NaCl solution under the illumination and dark conditions

Fig.7 Nyquist (a) and Bode (b) plots of 316L SS electrode uncoupled and coupled with pure and DMF added TiO₂ films in 3.5%NaCl solution under the dark and illumination conditions

Fig.8 Equivalent circuits used to fit EIS spectra of 316L SS electrode uncoupled (a) and coupled (b) with pure and DMF added TiO₂films in 3.5%NaCl solution under the dark and illumination conditions

Table 1 Impedance parameters obtained by fitting EIS data according to the equivalent circuits in Fig.8

Fig.9 Polarization curves of 316L SS electrode uncoupled and coupled with pure and DMF added TiO₂ films in 3.5%NaCl solution in the dark and illumination conditions

Table 2 Fitting electrochemical parameters of polarization curves

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