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Journal of Chinese Society for Corrosion and protection  2016, Vol. 36 Issue (4): 363-369    DOI: 10.11902/1005.4537.2015.167
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Microstructure and Properties of Seawater Corrosion Resistant Rebar Steel 00Cr10MoV
Jianchun ZHANG1(),Longfei ZUO1,Jinyang JIANG2,Han MA1,Dan SONG2
1. Institute of Research of Iron & Steel, Shasteel, Zhangjiagang 215625, China
2. School of Material Science and Engineering, Southeast University, Nanjing 211189, China
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Abstract  

The microstructure and mechanical properties of the seawater corrosion resistant rebar steel 00Cr10MoV was investigated, while its corrosion resistance was studied by salt-spray test, periodical immersion test, electrochemical impedance spectroscopy and polarization curve measurements. The results show that the microstructure of 00Cr10MoV composed of ferrite and bainite with yield strength above 400 MPa. Compared with 20MnSiV, 00Cr10MoV had excellent corrosion resistance in simulated marine environment. The charge-transfer resistance of 00Cr10MoV was 1.37×105 Ωcm2, 100 times more than 20MnSiV. Its corrosion products consist of major phases α-FeOOH, β-FeOOH and γ-FeOOH, minor phase Fe3O4 and trace phases Na3CrCl16 and Fe+3O(OH, Cl).

Key words:  seawater corrosion resistant rebar      microstructure      periodical immersion test      electrochemical impedance spectroscopy     

Cite this article: 

Jianchun ZHANG,Longfei ZUO,Jinyang JIANG,Han MA,Dan SONG. Microstructure and Properties of Seawater Corrosion Resistant Rebar Steel 00Cr10MoV. Journal of Chinese Society for Corrosion and protection, 2016, 36(4): 363-369.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2015.167     OR     https://www.jcscp.org/EN/Y2016/V36/I4/363

Steel C Si Mn P S Cr Mo V Fe
00Cr10MoV ≤0.03 0.40~0.60 1.40~1.60 ≤0.01 ≤0.01 9.5~10.5 0.9~1.2 0.03~0.10 Bal.
20MnSiV 0.21 0.49 1.44 0.019 0.007 --- --- 0.028 Bal.
Table 1  Chemical compositions of two tested steels (mass fraction/ %)
Sample Rp0.2 / MPa Rm / MPa A / % Agt / %
1 452 656 25.1 11.7
2 458 654 24.6 10.3
3 450 651 24.2 10.9
Average 453 654 24.6 11.0
Table 2  Mechanical properties of 00Cr10MoVrebar
Fig.1  Microstructures of the center (a) and R/4 region from the surface (b) for 00Cr10MoV rebar
Fig.2  SEM image of 00Cr10MoV rebar (a) and corresponding EPMA maps of Cr (b), Mo (c) and Mn (d)
Fig.3  Corrosion rates of two tested rebars in differentcorrosion conditions
Fig.4  Corrosion morphologies of 20MnSiV (a, b) and 00Cr10MoV (c, d) rebars before (a, c) and after(b, d) removal of corrosion products formed after 360 h salt-spray test
Fig.5  Corrosion morphologies of 20MnSiV (a, b) and00Cr10MoV (c, d) rebars before (a, c) and after(b, d) removal of corrosion products formed after 360 h periodical immersion test
Fig.6  XRD spectra of the corrosion products of 20MnSiV(a) and 00Cr10MoV (b) rebars after 360 h periodical immersion test
Fig.7  Polarization curves of 20MnSiV and 00Cr10MoVrebars
Fig.8  Nyquist (a), impedance module (b) and phase angle (c) plots and fitted curves of 20MnSiV and 00Cr10MoV steels
Fig.9  Equivalent circuit for EIS
Sample Rs
Ωcm2
Qdl-Yo
Ssncm-2
Qdl-n
(0~1)
Rt
Ωcm2
00Cr10MoV 3.981 4.84×10-5 0.9164 1.37×105
20MnSiV 2.633 8.36×10-4 0.835 1.11×103
Table 3  Fitting data of EIS of 20MnSiV and00Cr10MoV steels
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