ZINC-NICKEL ALLOY ELECTROPLATING IN AN ALKALINE BATH

Journal of Chinese Society for Corrosion and protection

2012, Vol. 32

Issue (6): 443-448 DOI:

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ZINC-NICKEL ALLOY ELECTROPLATING IN AN ALKALINE BATH

LU Wenshan¹, XU Tianfeng¹, CHEN Yu¹, ZHANG Zhao¹, ZHANG Jianqing^1,2

1. Department of Chemistry, Zhejiang University, Hangzhou 310027

2. State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Science Shenyang 110016

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Abstract

Zinc-nickel alloy coatings were electroplated from an alkaline electrolyte using direct current, the influences of principal technological parameters on the composition of zinc-nickel alloy coatings were studied using energy dispersive spectrometer (EDS). The results show that the content of nickel in Zn-Ni deposits kept between 11% and 13% and the co-deposition of zinc and nickel behaved anomalously. The microstructure of the optimized deposition was characterized by scanning transmission electron microscope (SEM), atomic force microscope (AFM) and X-ray diffractometer (XRD), the results showed that the Zn-Ni deposits consisted mainly of the γ-phase(NiZn₃) and the film was compact and fine-grained. Meanwhile, the Tafel plot measurements proved the coating had good corrosion resistance.

Key words: zinc-nickel alloy electroplating alkaline anomalous co-deposition corrosion resistance

Received: 28 November 2011

ZTFLH:

O646

Corresponding Authors: ZHANG Zhao E-mail: eaglezzy@zju.edu.cn

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Cite this article:

LU Wenshan, XU Tianfeng, CHEN Yu, ZHANG Zhao, ZHANG Jianqing. ZINC-NICKEL ALLOY ELECTROPLATING IN AN ALKALINE BATH. Journal of Chinese Society for Corrosion and protection, 2012, 32(6): 443-448.

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https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2012/V32/I6/443

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