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J Chin Soc Corr Pro  2008, Vol. 28 Issue (6期): 363-368    DOI:
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EFFECT OF CERIUM ON THE ELECTRONIC PROPERTY OF PASSIVE FILM FORMED ON Fe-3Cr ALLOY
LI Dangguo1;2; FENG Yaorong2; BAI Zhenquan2; ZHENG Maosheng1
1.School of Materials Science and Engineering; Xi′an Jiaotong University; Xi'an 710049;
2.Tubular Goods Research Center; China National Petroleum Corporation; Xi'an 710065
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Abstract  

The influence of Ce on the semi-conductive property of passive film formed on Fe-3Cr alloy in 1 mol/L NaHCO3+ 0.5 mol/L Na2CO3 buffer solution was studied by using capacitance measurement and electrochemical impedance spectroscopy (EIS). The results showed that Ce can decrease the donor density value of the film formed on substrate alloy in the buffer solution, increase the transfer resistance and film resistance, and decrease the diffusion capability of ions in the film. Moreover, the addition of Ce can enhance the corrosion resistance of substrate alloy in the buffer solution.

Key words:  capacitance measurement      electrochemical impedance spectroscopy      semi-conductive property      donor density     
Received:  06 March 2007     
ZTFLH: 

TG172.3

 
Corresponding Authors:  FENG Yaorong   

Cite this article: 

LI Dangguo FENG Yaorong BAI Zhenquan ZHENG Maosheng. EFFECT OF CERIUM ON THE ELECTRONIC PROPERTY OF PASSIVE FILM FORMED ON Fe-3Cr ALLOY. J Chin Soc Corr Pro, 2008, 28(6期): 363-368.

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2008/V28/I6期/363

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