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Study on the corrosion properties of SPV50Q steel in H2S-containing sour environment |
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南京工业大学 |
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Abstract The corrosion properties of SPV50Q steel were performed in H2S-containing sour environment by potentiodynamic polarization measurement and electrochemical impedance spectroscopy (EIS). The results show that the presence of H2S considerably influences the corrosion process of SPV50Q steel and its corrosion tate increases with increasing H2S cotent. With decreasing pH and increasing in temperature of the testing solutio, the corrosion of this steel is also enhanced. Although the semicircular diameter of capacitive loop increases with immersion time, its variation amplitude is not obviously great and begins to diminish after certain periodic time, suggesting that the sulfide film formed on the surface can not effectively prevent SPV50Q steel for avoiding the further corrosion.
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Received: 12 January 2006
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[1]Brown A,Jones C L.Hydrogen induced cracking in pipeline steels[J].Corrosion,1984,40(7):330-336 [2]Hara T,Asahi H.Conditions under which cracks occur in modified 13%chromium steel in wet hydrogen sulfide environments[J].Corrosion,2000,56(5):533-542 [3]Cheng X L,Ma H Y,Chen S H,et al.Electrochemical behaviour of chromium in acid solutions with H2S[J].Corros.Sci.,1999,41:773-788 [4]Cheng X L,Ma H Y,Chen S H,et al.Corrosion of nickel in acid solutions with hydrogen sulphide[J].Corros.Sci.,2000,42:299-311 [5]Tsay L W,Lin W L.Hydrogen sulphide stress corrosion cracking of weld overlays for desulfurization reactors[J].Corros.Sci.,1998,40:577-591 [6]Zhou X,Yang H Y,Cai D C,et al.The corrosion and inhibition of mild steel in monoethanolamine solution abounded with H2S[J].J.Chin.Soc.Corros.Prot.,2005,25(2):79-83(周欣,杨怀玉,蔡铎昌等.低碳钢在富含H2S乙醇胺溶液中的腐蚀及缓蚀剂抑制[J].中国腐蚀与防护学报,2005,25(2):79-83) [7]Cantwell J E.LPG storage vessel cracking experience[J].Mater.Perf.,1988,27(10):79-82 [8]Trivedi D K,Gupta S C.Cracking in liquid petroleum gas Horton spheres[J].Mater.Perf.,1997,36(7):59-61 [9]Yao Q.From the crack of spherical tank for LPG to see the hidden danger[J].China Safety Science Journal,1988,8(2):49-53(姚钦.从液化石油气球罐裂纹看球罐隐患[J].中国安全科学学报,1988,8(2):49-53) [10]Sun H G.Cause analysis of formation of surface cracking on liq-uefied petroleum spherical vessels[J].J.Chemical Industry&Engineering,1999,20(2):27-29(孙华光.液化气球罐表面裂纹成因分析[J].化学工业与工程技术,1999,20(2):27-29) [11]Tsai S Y,Shih H C.A statistical failure distribution and life as-sessment of the HSLA steel plates in H2S containing environments[J].Corros.Sci.,1996,38:705-719 [12]GB/T11060.1-1998.Natural gas-determination of hydrogen sulfide content-iodometric titration method[S].(GB/T11060.1-1998.天然气中硫化氢含量的测定—碘量法[S]) [13]Yang H Y,Chen J J,Cao C N,et al.Study on corrosion and inhibition mechanism in H2S aqueous solutionsⅠ.Corrosion behav-ior of carbon steel and growth of sulfide film on it in acidic solu-tion containing H2S[J].J.Chin.Soc.Corros.Prot.,2000,20(1):1-7(杨怀玉,陈家坚,曹楚南等.H2S水溶液中的腐蚀与缓蚀作用机理的研究Ⅰ.酸性H2S溶液中碳钢的腐蚀行为及硫化膜生长[J].中国腐蚀与防护学报,2000,20(1):1-7) [14]Morris D R,Sampaleanu L P,Veysey D N.The corrosion of steel by aqueous solution of hydrogen sulfide[J].J.Electrochem.Soc.,1988,127(6):1228-1235 [15]Ma H Y,Cheng X L,Li G Q et al.The influence of hydrogen sulfide on the corrosion of iron under different conditions[J].Corros.Sci.,2000,42:1669-1683 [16]Huang H H,Tsai W T,Lee J T.Electrochemical behavior of the simulated heat-affected zone of A516carbon steel in H2S solution[J].Electrochim.Acta,1996,41:1191-1199 [17]Veloz M A,González I.Electrochemical study of carbon steel corrosion in buffered acetic acid solution with chlorides and H2S[J].Electrochim.Acta,2002,48:135-144 [18]Yang H Y,Chen J J,Cao C N,et al.Study on the corrosion andinhibition mechanism in H2S aqueous solutionsⅢ.Electrochemical behavior of carbon steel in the different pH solutions containing H2S[J].J.Chin.Soc.Corros.Prot.,2000,20(2):97-104(杨怀玉,陈家坚,曹楚南等.H2S水溶液中的腐蚀与缓蚀作用机理研究Ⅲ.不同pH值H2S溶液中碳钢的腐蚀电化学行为[J].中国腐蚀与防护学报,2000,20(2):97-104) [19]Cao C N,Zhang J Q.An Introduction to Electrochemical Impedance Spectroscopy[M].Beijing:Science Press,2002(曹楚南,张鉴清.电化学阻抗谱导论[M].北京:科学出版社) |
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