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J Chin Soc Corr Pro  2003, Vol. 23 Issue (2): 107-111     DOI:
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GREY THEORY STUDY ON INHIBITION OF COMPOUNDS OFBENZENE NITRILES TO CARBON STEEL IN CHLORHYDRIC ACID
Xuejun Xie;Shunan Cao;Junfeng Liu
武汉大学化学与分子科学学院
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Abstract  The relations between inhibition efficiency of carb on steel in hydrochloric acid and molecular structure of compounds of benzene ni t riles were studied by constructing the grey inhibition model of inhibition syste m.Benzene nitriles studied included parent benzene nitriles(cinnamonitrile,benzo nitrile,benzeneacetonitrile,isopropyl benzeneacetonitrile) and para-chloro ben zene nitriles(para-chloro cinnamonitrile,para-chloro benzonitrile,para-chloro be nzeneacetonitrile,para-chloroisopropyl benzeneacetonitrile).Results showed that the relations between inhibition efficiency of carbon steel in hydrochloric acid and molecular structure of compounds of benzene nitriles could be expressed by GM(0,3).The expressions of GM(0,3) were η(1)1=04640E(1) LUMO-32777σ(1)N+04683(for parent benzene nitriles) and η  (1)Ⅱ=01256E(1)LUMO-73096σ(1)N-00759(for pa ra-chloro benzene nitriles).The expressions of GM(0,3) described the relations b etween inhibition efficiency of carbon steel in hydrochloric acid and molecular s tructure of compounds of benzene nitriles.Inhibition efficiency of compounds of benzene nitriles to carbon steel in hydrochloric acid mainly related to σ N and ELUMO,and the more the σN (absolute value) and the less t he ELUMO,the more the inhibition efficiency. 
Key words:  compounds of benzene nitriles      carbon steel      inhibition      grey theory      
Received:  06 August 2001     
ZTFLH:  TG174.42  
Corresponding Authors:  Xuejun Xie   

Cite this article: 

Xuejun Xie; Shunan Cao; Junfeng Liu. GREY THEORY STUDY ON INHIBITION OF COMPOUNDS OFBENZENE NITRILES TO CARBON STEEL IN CHLORHYDRIC ACID. J Chin Soc Corr Pro, 2003, 23(2): 107-111 .

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https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2003/V23/I2/107

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