Corrosion Inhibition Performance and Mechanism of Tween-80 on a Cold Rolled Steel in NH2SO3H Solution

doi:10.11902/1005.4537.2024.076

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (6): 1538-1546 DOI: 10.11902/1005.4537.2024.076

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Corrosion Inhibition Performance and Mechanism of Tween-80 on a Cold Rolled Steel in NH₂SO₃H Solution

TANG Liqing¹, LI Xianghong¹, ZHU Ping¹^,², WU Zhongfa¹, LEI Ran¹, XU Juan¹(

)

1. National Joint Engineering Research Center for Highly-Efficient Utilization Technology of Forestry Resources, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China
2. Yunnan Provincial Special Equipment Safety Testing and Research Institute, Kunming 650228, China

Cite this article:

TANG Liqing, LI Xianghong, ZHU Ping, WU Zhongfa, LEI Ran, XU Juan. Corrosion Inhibition Performance and Mechanism of Tween-80 on a Cold Rolled Steel in NH₂SO₃H Solution. Journal of Chinese Society for Corrosion and protection, 2024, 44(6): 1538-1546.

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Abstract

The corrosion inhibition performance of Tween-80 for a cold rolled steel in amino sulfonic acid solution was studied by mass loss method, potentiodynamic polarization measurement, atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS), as well as measuring the conductivity and surface tension of corrosion inhibitor containing solutions. The results showed that Tween-80 had a good corrosion inhibition effect on cold-rolled steel in amino sulfonic acid solution. The corrosion inhibition efficiency of Tween-80 in 0.10 mol/L amino sulfonic acid solution at 30^oC can reach as high as 94.33%. The standard adsorption Gibbs free energy (ΔG) is -29.94~-33.79 kJ/mol for the inhibitor adsorption on the surface of cold-rolled steel, it indicates that Tween-80 is a mixed adsorption dominated by chemisorption, and it follows the Langmuir adsorption isotherm equation. Therefore, Tween-80 is a mixed inhibitory corrosion inhibitor. After adding Tween-80, the surface tension of the solution decreases sharply. With the progress of corrosion inhibition of the steel, the conductivity of the solution increases, then gradually decreases and tends to be flat, which finally slightly lower than the conductivity before the steel immersion in the solution. AFM and XPS results confirmed that Tween-80 can effectively suppress the corrosion, while form an adsorption film on the surface of steel to achieve corrosion inhibition effect.

Key words: Tween-80 NH₂SO₃H cold rolled steel adsorption corrosion relief

Received: 08 March 2024 32134.14.1005.4537.2024.076

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52161016);Research Project for Distinguished Young Scholars in Yunnan Province(202001AV070008);Joint Key Project of Agricultural Fundamental Research in Yunnan Province(202101BD070001-017);Open Fund Project of National Joint Engineering Research Center for Highly-Efficient Utilization Technology of Forestry Resources, Southwest Forestry University(2023-GC09);Yunnan University Student Innovation and Entrepreneurship Training Program(20210153041)

Corresponding Authors: XU Juan, E-mail: 58045846@qq.com

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	TANG Liqing
	LI Xianghong
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	XU Juan

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https://www.jcscp.org/EN/10.11902/1005.4537.2024.076 OR https://www.jcscp.org/EN/Y2024/V44/I6/1538

Fig.1 Structural formula of Tween-80

Fig.2 Corrosion rates (a) and corrosion inhibition rates (b) of cold-rolled steel in 0.10 mol/L NH₂SO₃H solutions at different temperatures as a function of the concentration of Tween-80

Fig.3 Fitting straight lines of c/θ-c curves of cold-rolled steel at different temperatures

Table 1 Linear fitting parameters of c/θ-c curves of cold-rolled steel at different temperatures

Fig.4 Fitting straight lines of lnv-T^-1 (a) and ln (v/T)-T^-1 (b) curves of cold-rolled steel in 0.10 mol/L NH₂SO₃H solutions containing different concen-trations of Tween-80

Fig.5 Effects of the concentration of Tween-80 on the corrosion kinetic parameters of cold-rolled steel

Fig.6 Dynamic polarization curves of cold-rolled steel in 0.10 mol/L^{NH₂SO₃H solutions containing different concentrations of Tween-80 at 30^oC}

Table 2 Fitting parameters of dynamic polarization curves of cold-rolled steel

Fig.7 Variations of Tween-80 concentration at 30^oC on the surface tension (a) and conductivity (b) of cold-rolled steel before and after soaking in different solutions

Fig.8 AFM surface microtopographies of cold-rolled steel after immersion at 30^oC for 12 h in 0.10 mol/L NH₂SO₃H solution without (a) and with (b) 100 mg/L Tween-80

Table 3 AFM roughness parameters of cold-rolled steel

Fig.9 XPS analysis results of cold-rolled steel immersed in 0.10 mol/L NH₂SO₃H solution containing 100 mg/L Tween-80 for 12 h at 30^oC: (a) survey, (b) Fe 2p, (c) O 1s, (d) C 1s, (e) N 1s, (f) S 2p

Fig.10 Schematic illustration of corrosion inhibition mechanism of Tween-80 on cold-rolled steel

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