A588耐候钢在极寒大气环境下的腐蚀行为研究

doi:10.11902/1005.4537.2025.205

中国腐蚀与防护学报

2026, Vol. 46

Issue (3): 875-882 CSTR: 32134.14.1005.4537.2025.205 DOI: 10.11902/1005.4537.2025.205

研究报告

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A588耐候钢在极寒大气环境下的腐蚀行为研究

冯晨旭¹(

), 崔腾飞¹, 徐璐¹, 张昕宇¹, 崔中雨²

^1.航空工业直升机设计研究所景德镇 333001
^2.中国海洋大学材料科学与工程学院青岛 266100

Corrosion Behavior of A588 Weathering Steel in Extremely Cold Atmospheric Environments

FENG Chenxu¹(

), CUI Tengfei¹, XU Lu¹, ZHANG Xinyu¹, CUI Zhongyu²

^1.China Helicopter Research and Development Institute, Jingdezhen 333001, China
^2.School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China

引用本文:

冯晨旭, 崔腾飞, 徐璐, 张昕宇, 崔中雨. A588耐候钢在极寒大气环境下的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2026, 46(3): 875-882.
Chenxu FENG, Tengfei CUI, Lu XU, Xinyu ZHANG, Zhongyu CUI. Corrosion Behavior of A588 Weathering Steel in Extremely Cold Atmospheric Environments[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(3): 875-882.

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摘要:

针对A588耐候钢在极寒大气环境中暴露12个月后的腐蚀行为进行了系统研究。通过腐蚀失重法测得其年腐蚀速率为11.0  μm/a。SEM观察显示锈层存在裂纹和多孔结构，正面腐蚀程度高于背面。EDS分析表明Cl广泛分布，正面Cl^-富集更明显。XRD结果表明腐蚀产物主要由β-FeOOH、γ-FeOOH、α-FeOOH和Fe₃O₄/γ-Fe₂O₃组成，β-FeOOH占比最高，α/γ*保护性指数较低。Raman光谱揭示锈层物相分层特征显著，α-FeOOH富集于内层，γ-FeOOH主要分布于外层。多种表征结果表明，A588钢在极寒环境下形成的锈层结构存在裂纹和分层现象，影响其长期防护效果。

关键词 ：室外暴露试验, A588耐候钢, 极寒大气环境, 腐蚀行为, 腐蚀产物

Abstract：

The test samples of A588 weathering steel were field-exposed in the test site of the Zhongshan Station in Antarctica (69°22'24" S, 76°22'40" E) for 12 months in terms of the corrosion performance of A588 in an extremely cold atmospheric environment. The results show that the annual corrosion rate of the alloy was determined to be 11.0 μm/a using the weight loss method. SEM observations revealed that there existed cracks and pores within the rust layer, while with the corrosion degree on the upward surface being more severe than that on the downward surface of test samples. EDS analysis indicated widespread distribution of Cl element on the corroded surfaces, with more significant Cl^- enrichment on the upward surface. Furthermore, XRD results showed that the corrosion products mainly consisted of β-FeOOH, γ-FeOOH, α-FeOOH, and Fe₃O₄/γ-Fe₂O₃, among which β-FeOOH was predominant, and the α/γ* protection index was relatively low. Raman spectroscopy further revealed that a distinct stratified distribution of phases within rust layer, with α-FeOOH enriched in the inner layer and γ-FeOOH primarily located in the outer layer. These characterization results collectively suggest that the rust layer formed on A588 steel under extremely cold conditions exhibits cracking and phase stratification, which may compromise its long-term protective performance.

Key words： outdoor exposure tests A588 weathering steel extremely cold atmospheric environments corrosion behavior corrosion products

收稿日期: 2025-06-27 32134.14.1005.4537.2025.205

ZTFLH:

V216.5

通讯作者: 冯晨旭，E-mail：934907310@qq.com，研究方向为直升机环境适应性及腐蚀防护

Corresponding author: FENG Chenxu, E-mail: 934907310@qq.com

作者简介: 冯晨旭，男，1994年生，硕士，工程师

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表1 暴露期间南极中山站的环境参数

图1 A588耐候钢暴露极寒大气环境下12个月后宏观形貌

图2 A588耐候钢暴露极寒大气环境下12个月后的表面微观形貌

图3 极寒大气环境下A588耐候钢暴露12个月截面微观形貌及Cl元素分布图

图4 极寒大气环境下A588耐候钢去除腐蚀产物后的表面腐蚀形貌和CLSM图

图5 A588耐候钢暴露于极寒大气环境12个月后的腐蚀产物物相组成及百分比

图6 A588耐候钢暴露于极寒大气环境下12个月后的腐蚀产物物相分布

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