纳秒激光辐照对<strong>17-4PH</strong>不锈钢电化学腐蚀行为的影响

doi:10.11902/1005.4537.2024.398

中国腐蚀与防护学报

2025, Vol. 45

Issue (5): 1417-1424 CSTR: 32134.14.1005.4537.2024.398 DOI: 10.11902/1005.4537.2024.398

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纳秒激光辐照对17-4PH不锈钢电化学腐蚀行为的影响

李萍¹, 时慧杰¹, 裴继斌², 王子健¹, 曹铁山¹, 程从前¹(

), 赵杰¹

1 大连理工大学材料科学与工程学院大连 116024
2 吉林铁道职业技术学院铁道机车车辆学院吉林 132299

Impact of Nanosecond Pulsed Laser Irradiation on Electrochemical Corrosion Behavior of 17-4PH Stainless Steel

LI Ping¹, SHI Huijie¹, PEI Jibin², WANG Zijian¹, CAO Tieshan¹, CHENG Congqian¹(

), ZHAO Jie¹

1 School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
2 School of Railway Locomotive and Vehicle, Jilin Railway Technology College, Jilin 132299, China

引用本文:

李萍, 时慧杰, 裴继斌, 王子健, 曹铁山, 程从前, 赵杰. 纳秒激光辐照对17-4PH不锈钢电化学腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2025, 45(5): 1417-1424.
Ping LI, Huijie SHI, Jibin PEI, Zijian WANG, Tieshan CAO, Congqian CHENG, Jie ZHAO. Impact of Nanosecond Pulsed Laser Irradiation on Electrochemical Corrosion Behavior of 17-4PH Stainless Steel[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(5): 1417-1424.

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摘要:

为发展可替代化学钝化的17-4PH不锈钢激光钝化技术，以点蚀电位为指标开展了激光工艺参数的正交试验；结合电化学阻抗分析、表面腐蚀形貌观察和钝化膜价态测试，探讨纳秒激光辐照对17-4PH不锈钢电化学腐蚀行为的影响。结果表明：最佳激光辐照条件下，样品的点蚀电位和阻抗均高于常规钝化，钝化膜中点缺陷浓度最低，表面氧化膜的铬铁比最高。分析认为，上述现象的形成归因于激光辐照而致的热效应氧化，即在高温短时激光辐照作用下，Cr的热力学氧化优势更加明显，优先形成氧化层以保护基体。

关键词 ： 17-4PH不锈钢, 纳秒脉冲激光, 正交试验, 电化学测试, 耐腐蚀性

Abstract：

The impact of nanosecond laser irradiation on the electrochemical corrosion resistance of 17-4PH stainless steel in 3%NaCl solution was investigated by means of electrochemical impedance analysis, surface corrosion morphology observation, and passivation film valence state testing. The results show that the steel after being subjected to laser irradiation with optimal processing parameters presents pitting potential and impedance higher than those after being passivated in 30%HNO₃solution i.e. conventional passivation. Among others, the concentration of point defects in the passivation film of the former was the lowest. while its Cr/Fe ratio was the highest. These phenomena may be attributed to that the nanosecond laser irradiation can promote the preferential oxidation of Cr to form chromium oxide through instantaneous high-temperature oxidation, while reducing surface defects and roughness, optimizing the passivation film structure, and significantly improving the pitting resistance of stainless steel, so that effectively improving the corrosion resistance of stainless steel.

Key words： 17-4PH stainless steel nanosecond pulse laser orthogonal experiment electrochemical testing corrosion resistance

收稿日期: 2024-12-19 32134.14.1005.4537.2024.398

ZTFLH:

TG178

基金资助:航天发射场可靠性技术重点实验室项目(SYS-2022-12-02)

通讯作者: 程从前，E-mail：cqcheng@dlut.edu.cn，研究方向为不锈钢表面钝化及完整性评价、高温氧化/腐蚀机理、车身轻量化材料腐蚀与可靠性

Corresponding author: CHENG Congqian, E-mail: cqcheng@dlut.edu.cn

作者简介: 李萍，女，1969年生，博士，副教授

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表1 激光处理L9 (33)正交实验参数设置

表2 正交试验结果及极差分析

图1 点蚀电位平均值随各因素、水平的变化曲线

图2 不同条件表面处理的17-4PH不锈钢样品的动电位极化曲线

图3 不同条件下表面处理样品在3.5%NaCl溶液中动电位测试前后表面与点蚀形貌

图4 不同条件表面处理的17-4PH不锈钢在3.5%NaCl溶液中的EIS与等效电路

表3 17-4PH不锈钢在3.5%NaCl溶液中EIS的等效电路拟合结果

图5 不同条件表面处理的17-4PH不锈钢样品在3.5%NaCl溶液中的Mott-Schottky曲线

表4 不同条件表面处理的17-4PH不锈钢在3.5%NaCl溶液中形成的钝化膜的掺杂浓度

图6 不同条件表面处理的17-4PH不锈钢表面钝化膜的XPS光谱

表5 不同条件表面处理的17-4PH不锈钢钝化膜成分的XPS分析结果(相对原子浓度)

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