气相缓蚀剂分析方法研究进展

doi:10.11902/1005.4537.2022.393

中国腐蚀与防护学报

2023, Vol. 43

Issue (6): 1189-1202 CSTR: 32134.14.1005.4537.2022.393 DOI: 10.11902/1005.4537.2022.393

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气相缓蚀剂分析方法研究进展

王泉润¹^,², 侯进², 侯保荣¹, 田惠文¹(

)

^1.中国科学院海洋研究所中国科学院海洋环境腐蚀与生物污损重点实验室青岛 266071
^2.中国海洋大学化学化工学院青岛 266100

Research Progress of Analytical Methods for Vapor Phase Inhibitors

WANG Quanrun¹^,², HOU Jin², HOU Baorong¹, TIAN Huiwen¹(

)

^1.Key Laboratory of Marine Environmental Corrosion and Bio-fouling, IOCAS, Institute of oceanology, Chinese Academy of Sciences, Qingdao 266071, China
^2.College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China

引用本文:

王泉润, 侯进, 侯保荣, 田惠文. 气相缓蚀剂分析方法研究进展[J]. 中国腐蚀与防护学报, 2023, 43(6): 1189-1202.
Quanrun WANG, Jin HOU, Baorong HOU, Huiwen TIAN. Research Progress of Analytical Methods for Vapor Phase Inhibitors[J]. Journal of Chinese Society for Corrosion and protection, 2023, 43(6): 1189-1202.

全文: PDF(774 KB) HTML

摘要:

气相缓蚀剂作为抑制金属大气腐蚀的主要手段之一，其效果出色、经济效益高，得以广泛使用，发展气相缓蚀剂分析方法，对气相缓蚀剂的发展有着重要的指导意义。本文阐述了气相缓蚀剂的分类情况，气相缓蚀剂的特点及性能，根据其性能介绍了对应的检测方法包括：挥发性测试、腐蚀失重法、电化学测试法、表面分析法和构效关系计算等。总结了气相缓蚀剂分析方法并展望了气相缓蚀剂检测方法的发展趋势。

关键词 ：气相缓蚀剂性能, 气相缓蚀剂分类, 分析方法, 电化学测试法, 展望

Abstract：

As one of the main means to inhibit atmospheric corrosion of metal, vapor phase inhibitor is more and more widely used because of its excellent corrosion preventive effect, higher cost performance and easy to use. The development of analytical methods for vapor phase inhibitors has important guiding significance for the mechanism research and development of new vapor phase inhibitors. This paper introduces the classification of two kinds of vapor phase inhibitor, and describes the characteristics, such as volatility, solubility, adsorption and corrosion inhibition of vapor phase inhibitor. In order to test the different properties of vapor phase inhibitors, several analytical methods were introduced. The volatility test is measured in terms of saturated vapor pressure. Due to the advantages of simple operation and intuitive results, mass loss analysis is widely used in the detection of vapor phase inhibitors and to verify the accuracy of other methods. Electrochemical measurements can reveal a lot of features related to the action of vapor phase corrosion inhibitors, has become the mainstream method. Surface morphological techniques can further explore the film forming mechanism of corrosion inhibitor on metal surface. In sum, the current analysis methods of vapor phase inhibitors are summarized, and the future development trend of vapor phase inhibitor analysis methods is prospected.

Key words： performance of vapor phase inhibitor classification of vapor phase inhibitor analytical method electrochemical measurements prospect

收稿日期: 2022-12-10 32134.14.1005.4537.2022.393

ZTFLH:

TG174

基金资助:山东省重点研发计划 (科技示范工程)(2021SFGC0701);烟台市科技 (产业) 创新领军人才项目(2021RC015)

通讯作者: 田惠文，E-mail: tianhuiwen@qdio.ac.cn，研究方向为海洋腐蚀与防护新材料

Corresponding author: TIAN Huiwen, E-mail: tianhuiwen@qdio.ac.cn

作者简介: 王泉润，男，2000年生，硕士生

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