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中国腐蚀与防护学报  2004, Vol. 24 Issue (4): 249-256     
  综述 本期目录 | 过刊浏览 |
大气腐蚀研究方法进展
林翠
The progress of Research Methods on Atmospheric Corrosion
全文: PDF(292 KB)  
摘要: 综述了近几十年来国内外大气腐蚀研究方法的发展,重点介绍了大气腐蚀的加速试验方法、电化学研究方法和实时监测技术。湿热试验、盐雾试验、周期喷雾复合腐蚀试验、干湿周浸循环试验和多因子复合加速腐蚀试验是目前使用较多的加速试验,而多因子复合加速试验是模拟大气腐蚀加速试验方法以后发燕尾服的方向;发展了研究薄液膜的电化学测试技术,大气腐蚀监测电池ACM和Kelvin探头参比电极技术,极化和阻抗测量方法通常用于干湿交替加速试验中,也用于测试带锈试样在浸渍液中的电化学行为;原位动态实时监测技术的发展促进了从微观水平对材料大气腐蚀机理的研究工作的开展,最后提出了今后大气腐蚀研究方法的发展趋势。
关键词 大气腐蚀室内加速试验电化学测试实时监    
Abstract:The present status and development of research methods on atmospheric corrosion were comprehensively reviewed. Acclelerated laboratory test, electrochemical measurements and in-situ monitor tecnology were emphatically introduced. Wet and hot test, salt spray test, periodic spray complex test, wet and dry intermittent immersion cyclic test, multi-factor complex accelerated corrosion test. While multi-factor complex accelerated corrosion test is the development trend in the future;electrochemical measurement technology for studying the corrosion mechamism in the thin layer electrolyte was generated:atmospheric corrosion monitor and kelvin probe vibrating capacitor technique, polarization and impedance measurement methods was usually used to cyclic wet and dry accelerated test and also used to test electrochemical behavior of sample wit rust in the immersion solution;the application of in-situ monitor technology contributed to launch the research on the mechanism of atmospheric corrosion from microcosmic aspect. In the end, this article puts forward the development trend of the future of atmospheric corrosion research methods.
Key wordsatmospheric corrosion    accelerated laboratory test    electrochemical measurements    in-situ monitor techn
收稿日期: 2002-08-15     
ZTFLH:  TG172.3  

引用本文:

林翠 . 大气腐蚀研究方法进展[J]. 中国腐蚀与防护学报, 2004, 24(4): 249-256 .

链接本文:

https://www.jcscp.org/CN/Y2004/V24/I4/249

[1]WangZY .Thereviewofatmosphericcorrosionresearchonmetalmate rials[J].GeneralCorrosionControl,1995,(4):1-3(王振尧.金属材料大气腐蚀研究动态[J].全面腐蚀控制,1995,(4):1-3)
[2]FeliuS ,MorcilloM ,ChicoB .Effectofdistancefromseaonatmosphericcorrosionrate[J].Corrosion,1999,55(9):883-891
[3]WangGY ,WangHJ ,LiXL ,etal.CorrosionandProtectionofNaturalEnvironment-Atmosphere·SeaWater·Soil[M].Beijing:ChemicalIn dustryPress,1997(王光雍,王海江,李兴濂等编著.自然环境的腐蚀与防护—大气·海水·土壤[M].北京:化学工业出版社,1997)
[4]LiXL .Thereviewanddevelopmentsuggestionoftestresearchinatmo sphericcorrosionstationofourcountry[J].Mater.Prot.,2000,33(1):20-22(李兴濂.我国大气腐蚀网站试验研究回顾及发展建议[J].材料保护,2000,33(1):20-22)
[5]WangFP ,ZhangXY ,DuYL .Thereviewofatmosphericcorrosionre search[J].Corros.Sci.Prot.Technol.,2000,12(2):104-108(王凤平,张学元,杜元龙.大气腐蚀研究动态与进展[J].腐蚀科学与防护技术,2000,12(2):104-108
[6]HouW ,LiangC .Eight-yearatmosphericcorrosionexposureofsteelsinChina[J].Corrosion,1999,55(1):65-73
[7]OdnellI ,LeygrafC .Seasonalvariationsincorrosionrateandrunoffrateofcopperroofsinanurbanandaruralatmosphericenvironment[J].Corros.Sci.,2001,432:379-396
[8]OdnevallI.Atmosphericcorrosionoffieldexposedzinc-Amultianalyti calcharacterizationofcorrosionproductsfrominitialfilmstofullydevel opedlayers[D].DoctoralThesis:RoyalInstituteofTechnology,Sweden,1994
[9]SunZH ,LiJG ,LiMZ .Futureofacceleratedatmosphericcorrosiontestingofmetalmaterials[J].Mater.Eng.,1995,(12):41-42(孙志华,李金桂,李牧铮.金属材料大气腐蚀加速试验研究的发展趋势[J].材料工程,1995,(12):41-42)
[10]JinL ,TangQH ,PengCH ,etal.Acceleratedtestingforsimulatingacidicpollutionandmarineenvironmentinducedatmosphericcorrosion[J].Corros.Sci.Prot.Technol.,1995,7(3):214-215(金蕾,唐其环,彭长灏等.大气腐蚀的模拟加速试验方法(摘要)[J].腐蚀科学与防护技术,1995,7(3):214-215)
[11]KhobaibM ,ChangFC ,KeppleEE ,etal.Acceleratedatmospheric-corrosiontesting[A].ASymposiumSponsoredbyASTMCommitteeG -1onCorrosionofMetals[C].DenverColo,1980
[12]DamianL ,FakoR .WeatheringstructuralsteelscorrosioninatmosphericofvariousdegreesofpollutioninRomania[J].Mater.Corros.,2000,51(8):574-578
[13]MirandaLRM ,SathierL ,NogueiraR ,etal.AtmosphericcorrosiontestsinBrazilianlegalAmazon-fieldandlaboratorytests[J].Mater.Corros.,2000,51(3):182-185
[14]JohanssonLG ,VannerbergNG .Theatmosphericcorrosionofunpro tectedcarbonsteel-Acomparisonbetweenfieldstudyandlaboratorytest[J].WerkstoffeUndKorrosion,1981,32:265-268
[15]BoelenB ,SchmitzB ,DefournyJ ,etal.Aliteraturesurveyonthedevel opmentofanacceleratedlaboratorytestmethodforatmosphericcorro sionofprecoatedsteelproducts[J].Corros.Sci.,1993,34(11):1923-1931
[16]KobusJ .Long-termatmosphericcorrosionmonitoring[J].Mater.Cor ros.,2000,51(2):104-108
[17]JohnsonJB ,ElliottP ,WinterbottomMA ,etal.Short-termatmosphericcorrosionofmildsteelattwoweatherandpollutionmonitoredsites[J].Corros.Sci.,1977,17:691-700
[18]BragardAA ,BonnarensHE .Predictionatlongtermsoftheatmospher iccorrosionofstructuralsteelsfromshort-termexperimentaldata[A].ASymposiumSponsoredbyASTMCommitteeG -1onCorrosionofMetals[C].DenverColo,1980
[19]MouXL ,TianYE ,WangXH .Therelativityofthesimulatedacceler atedtestofcarbonsteelandlowalloysteelandatmosphericcorrosiontest[J].Environ.Technol.,2000,(4):14-17(牟献良,田月娥,汪学华.碳钢和低合金钢模拟加速试验与大气腐蚀试验的相关性[J].环境技术,2000,(4):14-17)
[20]DrazicDM .Thecorrelationbetweenacceleratedlaboratorycorrosiontestsandatmosphericcorrosionstationtestsonsteels[J].Corros.Sci.,1989,29(10):1197-1204
[21]XuNX ,ZhangCD ,DingCH .Anewmethodofacceleratedatmo sphericcorrosiontest[J].J .Chin.Soc.Corros.Prot.,1990,10(3):228-231(徐乃欣,张承典,丁翠红等.加速大气腐蚀试验的一个新方案[J].中国腐蚀与防护学报,1990,10(3):228-231)
[22]LyonSB ,ThompsonGE ,JohnsonJB ,etal.Acceleratedatmosphericcorrosiontestingusingacyclicwet/dryexposuretest:aluminium,galva nizedsteel,andsteel[J].Corrosion,1987,43(12):719-726
[23]ZhuF ,PerssonD ,ThierryD ,etal.Formationofcorrosionproductsonopenandconfinedzincsurfaceexposedtoperiodicwet/dryconditions[J].Corrosion,2000,56(12):1256-1265
[24]ZhuF ,PerssonD ,ThierryD ,etal.Formationofcorrosionproductsonopenandconfinedzincsurfaceexposedtoperiodicwet/dryconditions-Acomparisonbetweenzincandelectrogalvanizedsteel[J].Corrosion,2001,57(7):582-590
[25]WangZY ,ZhengYP ,LiuSR .Behaviourofatmosphericcorrosionofcarbonsteelinartificiallypollutedmedia[J].J.Chin.Soc.Corros.Prot.,1994,14(3):240-246(王振尧,郑逸萍,刘寿荣.A3钢在人造污染介质中的大气腐蚀行为[J].中国腐蚀与防护学报,1994,14(3):240-246)
[26]SunZH ,LiJG ,LiMZ .Investigationonatmosphericcorrosionacceler ated-testofcarbonsteel[J].Mater.Eng.,1996,(7):26-27(孙志华,李金桂,李牧铮.碳钢大气腐蚀加速试验研究[J].材料工程,1996,(7):26-27)
[27]LiJ,LiM ,SunZ .Developmentofanartificialclimaticcomplexacceler atedcorrosiontesterandinvestigationofcomplexacceleratedcorrosiontestmethods[J].Corrosion,1999,55(5):498-502
[28]MattssonE .Corrosion:anelectrochemicalproblem[J].ChemicalTech nology,1985,(4):234-243
[29]PachecoAMG ,FerreiraMGS .Aninvestigationofthedependentofatmosphericcorrosionrateontemperatureusingprinted-circuitironcells[J].Corros.Sci.,1994,36(5):797-813
[30]MansfeldF ,KenkelJV .Electrochemicalmonitoringofatmosphericcor rosionphenomena[J].Corros.Sci.,1976,16:111-122
[31]MansfeldF ,KenkelJV .Electrochemicaloftime-of-wetnessandat mosphericcorrosionrates[J].Corrosion,1977,33(1):13-16
[32]MansfeldF ,TsaiS ,JeanjaqueS ,etal.Reproducibilityofelectrochemi calmeasurementsofatmosphericcorrosionphenomena[A].ASympo siumsponsoredbyASTMCommitteeG -1onCorrosionofMetals[C].DenverColo,1980
[33]MansfeldF ,TsaiS .Laboratorystudiesofatmosphericcorrosion-1.weightlossandelectrochemicalmeasurements[J].Corros.Sci.,1980,20:853-872
[34]WangFP ,ZhangXY ,LeiLG ,etal.TheroleofcarbondioxideintheatmosphericcorrosionofA3steel[J].ActaMetall.Sin.,2000,36(1):55-58(王凤平,张学元,雷良才等.二氧化碳在A3钢大气腐蚀中的作用[J].金属学报,2000,36(1):55-58)
[35]WangFP ,ZhangXY ,DuYL .EffectofCO2 onatmosphericcorrosionofUNSsteelunderthinelectrolytefilm[J].ChemicalResearchinChi neseResearch,2000,16(1):36-41
[36]WangFP .EffectofincreasingCO2 inatmosphereonatmosphericcorro sionofmetals[D].DoctoralThesisofChineseAcademyofSciences,2000(王凤平.大气CO2浓度升高对金属大气腐蚀的影响[D].中国科学院博士学位研究生学位论文,2000)
[37]WalterGW .Laboratorysimulationofatmosphericelectrochemicaltech niquesexampleresults[J].Corros.Sci.,1991,32(12):1331-1352
[38]XuJL ,LiMZ .Theresearchonelectrochemicalmonitorofatmosphericcorrosion[J].J.Chin.Soc.Corros.Prot.,1987,7(1):60-65(徐俊丽,李牧铮.大气腐蚀电化学监测的研究[J].中国腐蚀与防护学报,1987,7(1):60-65)
[39]XiaoYD ,ZhouXJ,ZhangSP .Anelectrochemicalstudyofatmospher iccorrosionoflow-alloysteel[J].Corros.Sci.Prot.Technol.,1995,7(3):200-204(萧以德,周学杰,张三平.低合金钢大气腐蚀的电化学研究[J].腐蚀科学与防护技术,1995,7(3):200-204)
[40]ZhengLQ ,KuaiXM ,CaoCN ,etal.Anintelligentatmosphericcorro sionmonitor[J].Corros.Sci.Prot.Technol.,1994,6(2):184-187(郑立群,蒯晓明,曹楚南等.ACM智能大气腐蚀监测仪的研制[J].腐蚀科学与防护技术,1994,6(2):184-187)
[41]WengYJ ,LiXY .Multiholeplatecellfordetectinggaseouscorrosivity[J].J.Chin.Soc.Corros.Prot.,1991,11(2):146-151(翁永基,李相怡.多孔薄板式气体腐蚀性探测电池[J].中国腐蚀与防护学报,1991,11(2):146-151)
[42]WengYJ.Theintroductionofeletrochemicalmeasurementsystemofmomentcorrosionrateingaseousmedium[J].Corros.Sci.Prot.Tech nol.,1989,1(2):47(翁永基.金属在气体介子中瞬间腐蚀速度的电化学测量系统简介[J].腐蚀科学与防护技术,1989,1(2):47
[43]SunZH ,LiJZ ,LiuMH ,etal.ApplicationofKelvinprobevibrationcapacitortechniqueinstudyofatmosphericcorrosion[J].Corros.Sci.Prot.Technol.,2001,13(增刊):451-453(孙志华,李家柱,刘明辉等.Kelvin探头振动电容法技术在大气腐蚀中的应用[J].腐蚀科学与防护技术,2001,13(增刊):451-453)
[44]WangJ,TsuruTooru.Electrochemicalmeasurementsunderthinelec trolytelayerusingKelvinprobereferenceelectrode[J].J .Chin.Soc.Corros.Prot.,1995,15(3):173-179(王佳,水流彻.使用Kelvin探头参比电极技术进行薄液层下电化学测量[J].中国腐蚀与防护学报,1995,15(3):173-179)
[45]WangJ,TsuruTooru.AninvestigationonoxygenreductionunderthinelectrodelayerusingKelvinprobereferenceelectrode[J].J.Chin.Soc.Corros.Prot.,1995,15(3):180-188(王佳,水流彻.使用Kelvin探头参比电极技术研究液层厚度对氧还原速度的影响[J].中国腐蚀与防护学报,1995,15(3):180-188)
[46]KamimuraT ,StratmannM .Theinfluenceofchromiumontheatmo sphericcorrosionofsteel[J].Corros.Sci.,2001,43:429-447
[47]ChungKW ,KimKB .Astudyoftheeffectofconcentrationbuild-upofelectrolyteontheatmosphericcorrosionofcarbonsteelduringdrying[J].Corros.Sci.,2000,42:517-531
[48]YuJD ,WuYL ,CuiXL ,etal.Mechanismofatmosphericcorrosionre sistanceof08CuPVREsteel[J].J.Chin.Soc.Corros.Prot.,1994,14(1):82-86(于敬敦,吴幼林,崔秀岭等.08CuPVRE钢耐大气腐蚀的机理[J].中国腐蚀与防护学报,1994,14(1):82-86)
[49]LiuJR ,LiuZS .Studyonatmosphericcorrosionresistanceoflowalloysteel[J].SteelResearch,2000,(6):22-26(刘建容,刘正生.低合金钢大气腐蚀性能的研究[J].钢铁研究,2000,(6):22-26)
[50]HouWT ,YuJD ,LiangCF .Atmosphericcorrosionofcarbonsteelandlowalloysteel[J].J .Chin.Soc.Corros.Prot.,1993,13(4):291-301(候文泰,于敬敦,梁彩凤.碳钢及低合金钢的大气腐蚀[J].中国腐蚀与防护学报,1993,13(4):291-301)
[51]ChungSC ,LinAS ,ChangJR ,etal.EXAFSstudyofatmosphericcor rosionproductsonzincattheinitialstage[J].Corros.Sci.,2000,42:1599-1610
[52]NishimuraT ,KatayamaH ,NodaK ,etal.Electrochemicalbehaviorofrustformedoncarbonsteelinawet/dryenvironmentcontainingchlorideions[J].Corrosion,2000,56(9):935-941
[53]DeanSW .Planning,instrumentation,andevaluationofatmosphericcor rosiontests(Part4)[J].EnvironmentTreatment&Control,1989,(1):52-54
[54]LaguzziG ,LuvidiL ,BrunoroG .AtmosphericcorrosionofB6bronzee valuatedbythethinlayeractivationtechnique[J].Corros.Sci.,2001,43:747-753
[55]AastrupT ,WadsakM ,SchreinerM ,etal.Experimentalinsitustudiesofcopperexposedtohumidifiedair[J].Corros.Sci.,2000,42:957-967
[56]WadsakM ,SchreinerM ,AastrupT ,etal.Combinedin-situinvestiga tionsofatmosphericcorrosionofcopperwithSFMandIRAScoupledwithQCM[J].Surf.Sci.,2000,454-456:246-250
[57]ItohJ ,SasakiT ,SeoM ,etal.InsitusimultaneousmeasurementwithIR-RASandQCMforcorrosionofcopperinagaseousenvironment[J].Corros.Sci.,1997,39(1):193-197
[58]MasudaH .Effectofmagnesiumchlorideliquidthicknessonatmosphericcorrosionofpureiron[J].Corrosion,2001,57(2):99-109
[59]YanCW ,CaoCN ,LinHC .Applicationofquartzcrystalmicrobalanceinatmosphericcorrosioninvestigation[J].J .Chin.Soc.Corros.Prot.,2001,21(2):123-127(严川伟,曹楚南,林海潮.石英晶体微天平(QCM)在大气腐蚀研究中的应用[J].中国腐蚀与防护学报,2001,21(2):123-127)
[60]WangFP ,YanCW ,ZhangXY ,etal.Quartzcrystalmicrobalanceanditsapplicationinatmosphericcorrosion[J].ChemicalMagazine,2001,(6):382-387(王凤平,严川伟,张学元等.石英晶体微天平(QCM)及其在大气腐蚀研究中的应用[J].化学通报,2001,(6):382-387)
[61]WangFP ,YanCW ,ZhangXY ,etal.CorrosionkineticsofzincunderthineletrolytefilmbymeansofQCM[J].ActaPhys-ChemistrySini ca,2001,17(4):319-323(王凤平等.石英晶体微天平研究Zn在薄液膜下的腐蚀动力学[J].物理化学学报,2001,17(4):319-323)
[62]LegaultRA ,PearsonVP .Thekineticsoftheatmosphericcorrosionofaluminizedsteel[J].Corrosion,1978,34(10):344-349
[63]LegaultRA ,PrebanAG .Kineticsoftheatmosphericcorrosionoflow-alloysteelsinanindustrialenvironment[J].Corrosion,1975,31(4):117-122
[64]ZhangXY ,HanEH ,DanPersson,etal.StudyoncorrosionbehaviourofzincsurfacebyIRASinwet-dryalternativeconditions[J].J.Chin.Soc.Corros.Prot.,2002,22(1):32-35(张学元,韩恩厚,DanPersson等.利用IRAS研究锌表面在湿干交替条件下的腐蚀行为[J].中国腐蚀与防护学报,2002,22(1):32-35)
[65]El-MahdyGA ,NishikataA ,TsuruT .Electrochemicalcorrosionmoni toringofgalvanizedsteelundercyclicwet-dryconditions[J].Corros.Sci.,2000,42:183-194
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