Please wait a minute...
中国腐蚀与防护学报  2002, Vol. 22 Issue (5): 257-263     
  研究报告 本期目录 | 过刊浏览 |
碳钢在高温环烷酸介质中冲刷腐蚀行为
吴欣强;敬和民;郑玉贵
中科院金属所
STUDY ON CORROSION AND EROSION-CORROSIONBEHAVIORS OF CARBON STEEL IN NAPHTHENICACID MEDIUMS AT HIGH TEMPERATURE
Xinqiang Wu;Hemin Jing;Yugui Zheng
中科院金属所
全文: PDF(268 KB)  
摘要: 研究了A3碳钢在高温环烷酸介质中的冲刷腐蚀行为,并考察 了其在工业炼油环境中的抗冲蚀性能.结果表明:酸值、温度、流速是影响碳钢环烷酸冲刷 腐蚀行为的主要因素,它们通过影响环烷酸分子向金属表面的传输、在金属表面的吸附、表 面活性反应及腐蚀产物的剥离等过程来影响冲刷腐蚀的程度.
关键词 碳钢环烷酸冲刷腐蚀    
Abstract:The corrosion and erosion-corrosion behaviors of A3 carbon steel in naphthenic acid mediums at high temperature were studied in det ail.The erosion-corrosion resistance of A3 carbon steel in industrial oil-refini ng environment was also investigated.The results revealed that the total acid nu mber (TAN),the temperature and the velocity of flow play important roles in affe cting the naphthenic acid corrosion (NAC)and erosion-corrosion (NAEC)behaviors o f carbon steel,which influence the degree of NAC and NAEC by influencing the tra nsportation of naphthenic acid molecules toward the metal surface,the absorption of naphthenic acid molecules on the metal surface,the active reaction on the me tal surface,and the spallation of corrosion products from the metal surface.In g iven corrosion mediums,the control step of NAC process is mainly dependent on th e temperature.The carbon steel has little resistance to the NAC and NAEC,so this material should be used cautiously in industry oil-refining installation,especi ally in the places where the temperature,the TAN and the velocity of flow are ra ther high.
Key wordscarbon steel    naphthenic acid    erosion-corrosion
收稿日期: 2001-06-29     
ZTFLH:  TG174.2  
通讯作者: 吴欣强   
Corresponding author: Xinqiang Wu   

引用本文:

吴欣强; 敬和民; 郑玉贵 . 碳钢在高温环烷酸介质中冲刷腐蚀行为[J]. 中国腐蚀与防护学报, 2002, 22(5): 257-263 .
Xinqiang Wu, Hemin Jing, Yugui Zheng. STUDY ON CORROSION AND EROSION-CORROSIONBEHAVIORS OF CARBON STEEL IN NAPHTHENICACID MEDIUMS AT HIGH TEMPERATURE. J Chin Soc Corr Pro, 2002, 22(5): 257-263 .

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2002/V22/I5/257

[1]SlavchevaE ,ShoneB ,TurnbullA .Reviewofnaphthenicacidcorrosioninoilrefining[J].Br.Corro.J.,1999,34(2):125-131
[2]KaneRD ,CayardMS .Understandingcriticalfactorsthatinfluencere finerycrudecorrosiveness[J].MaterialsPerformance,1999,38(7):48-54
[3]WuXQ ,JingHM ,ZhengYG ,YaoZM ,KeW .Thetestingequipmentsimulatinghigh-temperatureandhigh-velocitysituationsinindustryoilrefineryandtheselectionofitsexperimentalparameters[J].J.Chi neseSocietyforCorrosionandProtection,2002,22(1):1-7(吴欣强,敬和民,郑玉贵,姚治铭,柯伟.模拟工业炼油环境高温高流速状态的循环测试装置及其实验参数选择[J].中国腐蚀与防护学报,2002,22(1):1-7)
[4]GaoYM ,ChengJJ ,YuG ,YangHY ,CaoDZ ,ZhuYJ.CorrosionmechanismofA3steelinnaphthenicacid[J].Corro.Sci.Prote.Tech nol.,2000,12(1):27-29(高延敏,陈家坚,余刚,杨怀玉,曹殿珍,祝英剑.环烷酸对A3钢腐蚀机理的研究[J].腐蚀科学与防护技术,2000,12(1):27-29)
[5]GutzeitJ .Naphthenicacidcorrosioninoilrefineries[J].MaterialsPerfor mance,1977,16(10):24-25
[6]CaoCN .CorrosionElectrochemistry[M].Beijing:ChemistryIndustryPress,1994,141(曹楚南.腐蚀电化学[M].北京:化学工业出版社,1994,141)
[7]PiehlRL .Naphthenicacidcorrosionincrudedistillationunits[J].Mate rialsPerformance,1988,27(1):37-43
[8]TurnbullA ,SlavchevaE ,ShoneB .Factorscontrollingnaphthenicacidcorrosion[J].Corrosion,1998,54(11):922-930
[9]ZhengYG ,YaoZM ,KeW .Reviewontheeffectsofhydrodynamicfac torsonerosion-corrosion[J].Corro.Sci.Prote.Technol.,2000,12(1):36-40(郑玉贵,姚治铭,柯伟.流体力学因素对冲刷腐蚀的影响机制[J].腐蚀科学与防护技术,2000,12(1):36-40)
[10]PoulsonB .Electrochemicalmeasurementsinflowingsolutions[J].Cor ros.Sci.,1983,23(4):391-430
[11]KappesserR ,CornetI,GriefR .Masstransfertoaroughrotatingcylin der[J].J.ElectrochemicalSociety,1971,118(12):1957-1959
[12]GabeDR ,MakanjuolaPA .Enhancedmasstransferusingroughenedrotatingcylinderelectrodesinturbulentflow[J].JournalofAppliedElectrochemistry,1987,17(2):370-3843
[1] 张晨, 陆原, 赵景茂. CO2/H2S腐蚀体系中咪唑啉季铵盐与3种阳离子表面活性剂间的缓蚀协同效应[J]. 中国腐蚀与防护学报, 2020, 40(3): 237-243.
[2] 许萍,张硕,司帅,张雅君,汪长征. EPS的主要成分-蛋白质、多糖抑制碳钢腐蚀机理研究[J]. 中国腐蚀与防护学报, 2019, 39(2): 176-184.
[3] 钟显康,扈俊颖. 恒定的pH值和Fe2+浓度下X65碳钢的CO2腐蚀行为[J]. 中国腐蚀与防护学报, 2018, 38(6): 573-578.
[4] 王力, 郭春云, 肖葵, 吐尔逊·斯拉依丁, 董超芳, 李晓刚. Q235和Q450钢在吐鲁番干热大气环境中长周期暴晒时的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2018, 38(5): 431-437.
[5] 乔越, 朱志平, 杨磊, 刘志峰. 高温状态下锅炉给水氧化还原电位监测与模拟实验研究[J]. 中国腐蚀与防护学报, 2018, 38(5): 487-494.
[6] 彭晚军, 丁纪恒, 陈浩, 余海斌. 生物基缓蚀剂糠醇缩水甘油醚的缓蚀性能及机理[J]. 中国腐蚀与防护学报, 2018, 38(3): 303-308.
[7] 钱备, 刘成宝, 宋祖伟, 任俊锋. 纳米容器改性环氧涂层对Q235碳钢的防腐蚀性能[J]. 中国腐蚀与防护学报, 2018, 38(2): 133-139.
[8] 偶国富, 赵露露, 王凯, 王宽心, 金浩哲. 10#碳钢在HCl-H2O环境中的露点腐蚀行为[J]. 中国腐蚀与防护学报, 2018, 38(1): 33-38.
[9] 张杰, 胡秀华, 郑传波, 段继周, 侯保荣. 海洋微藻环境中钙质层对Q235碳钢腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2018, 38(1): 18-25.
[10] 孟晓波,蒋武斌,廖永力,李锐海,郑志军,高岩. 输电杆塔材料在模拟工业环境中的大气腐蚀行为研究[J]. 中国腐蚀与防护学报, 2017, 37(5): 460-466.
[11] 程庆利,陶彬,刘栓,刘全桢,张卫华,田松柏,王立平. 原油沉积水对Q235B碳钢的腐蚀影响[J]. 中国腐蚀与防护学报, 2017, 37(2): 126-134.
[12] 郝永胜,Luqman Abdullahi SANI,宋立新,徐国宝,葛铁军,方庆红. 中性和酸性溶液中Q235碳钢表面沉积植酸转化膜的耐蚀行为研究[J]. 中国腐蚀与防护学报, 2016, 36(6): 549-558.
[13] 王吉会,闫华杰,胡文彬. 钼酸盐插层锌铝铈水滑石的制备与缓蚀性能研究[J]. 中国腐蚀与防护学报, 2016, 36(6): 637-644.
[14] 刘宏伟,熊福平,吕亚林,葛承宣,刘宏芳,胡裕龙. 动态条件下十二胺对Q235碳钢CO2腐蚀的缓蚀行为研究[J]. 中国腐蚀与防护学报, 2016, 36(6): 645-651.
[15] 王春霞,陈敬平,张晓红,王赪胤. 溴化N-辛烷异喹啉在盐酸溶液中对Q235碳钢的缓蚀行为[J]. 中国腐蚀与防护学报, 2016, 36(3): 245-252.