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中国腐蚀与防护学报  1996, Vol. 16 Issue (2): 115-121    
  研究报告 本期目录 | 过刊浏览 |
有、无外磁场下铁在碳酸氢钠溶液中的阳极极化行为
吕战鹏;陈俊明
中国科学院上海冶金研究所
ANODIC POLAIZATION BEHAVIOR OF IRON IN SODIUM BICARBONATE SOLUTIONS IN THE PRESENCE OR ABSENCE OF MAGNETIC FIELD
Lu Zhangpeng ;Chen Junming(Shanghai Institute of Metallurgy;Chinese Academy of Sciences)
全文: PDF(607 KB)  
摘要: 用动电位扫描法测得的有、无外磁场下纯铁在一系列(1×10(-2)~1lmol/L)NaHCO3溶液中30℃下的阳极极化曲线表明:铁在NaHCO3中具有活化-钝化-过钝化特征;曲线有三种类型,从热力学看系由于NaHCO3浓度的变化导致在铁上发生不同的电化学反应的结果;外磁场不改变电化学反应机制,但会增大电流密度;由于磁场的作用与钝化膜的作用相互制约,在不同浓度的NaHCO3溶液中磁场的作用程度有所不同。
关键词 磁场Fe在NaHCO_3溶液中阳极极化曲线    
Abstract:Anodic polarhation curves of iron in (0.01~1 mol/L) NaHCO3 solution were measured using potentiodynamic method in the presence or absence of 0.4T magnetic field. It was shown that iron in these solution exhibited act ive-passive-transpassive characteristics. Three types of polarization curves obtaniedcould be explained thermodynamically on the assumption that the variation of NaHCO3 concentration caused different electrochemical reactions occurring on iron. Imposed magnetic field did not change the electrochemical reaction mechanism but would increase current density at the given potential. Interaction between the effect of magnetic field and the effect of passive film resulted in different efficiency of magnetic field in different concentrations of NaHCO3 solutions.
Key words Magnetic field    Iron in NaHCO3 solution    Anodic polarization curve
收稿日期: 1996-04-25     

引用本文:

吕战鹏;陈俊明. 有、无外磁场下铁在碳酸氢钠溶液中的阳极极化行为[J]. 中国腐蚀与防护学报, 1996, 16(2): 115-121.
. ANODIC POLAIZATION BEHAVIOR OF IRON IN SODIUM BICARBONATE SOLUTIONS IN THE PRESENCE OR ABSENCE OF MAGNETIC FIELD. J Chin Soc Corr Pro, 1996, 16(2): 115-121.

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y1996/V16/I2/115

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