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中国腐蚀与防护学报  2026, Vol. 46 Issue (3): 663-670     CSTR: 32134.14.1005.4537.2025.183      DOI: 10.11902/1005.4537.2025.183
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核电厂蒸汽发生器表面腐蚀与防护的研究进展
刘虎1, 李序东1, 周兆辉2, 王金龙2(), 陈明辉2, 王福会2
1.中国核工业核动力运行研究所 武汉 430073
2.东北大学材料科学与工程学院 腐蚀与防护研究中心 沈阳 110819
Research Progress on Surface Corrosion and Protection of Steam Generator Surface in Nuclear Power Plants
LIU Hu1, LI Xudong1, ZHOU Zhaohui2, WANG Jinlong2(), CHEN Minghui2, WANG Fuhui2
1.Research Institute of Nuclear Power Operation China National Nuclear Corporation, Wuhan 430073, China
2.Corrosion and Protection Center, School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China
引用本文:

刘虎, 李序东, 周兆辉, 王金龙, 陈明辉, 王福会. 核电厂蒸汽发生器表面腐蚀与防护的研究进展[J]. 中国腐蚀与防护学报, 2026, 46(3): 663-670.
Hu LIU, Xudong LI, Zhaohui ZHOU, Jinlong WANG, Minghui CHEN, Fuhui WANG. Research Progress on Surface Corrosion and Protection of Steam Generator Surface in Nuclear Power Plants[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(3): 663-670.

全文: PDF(1136 KB)   HTML
摘要: 

蒸汽发生器作为压水堆核电厂一、二回路的关键连接设备,长期承受高温、高压及多相流腐蚀环境,其表面腐蚀问题直接威胁核电站的安全性与经济性。本文综述了蒸汽发生器表面腐蚀机制与防护技术的最新研究进展,讨论了核电厂蒸汽发生器在贮存、运输和运行等过程中的环境因素,分析了影响蒸汽发生器表面发生腐蚀的原因,指出了蒸汽发生器表面的特殊防护需求,详细介绍了相关防护涂料技术的发展现状,旨在为蒸汽发生器表面的腐蚀与防护提供参考。

关键词 核电蒸汽发生器涂料防护技术    
Abstract

The steam generator (SG), serving as the critical junction between the primary and secondary circuits in pressurized water reactor (PWR) nuclear power plants, is subjected to long-term exposure to high-temperature, high-pressure, and multiphase flow corrosive environments. Surface corrosion issues in SGs pose a direct threat to the safety and economic viability of nuclear power stations. This paper reviews the latest research progress on the corrosion mechanisms and protection technologies for SG surfaces. It discusses the environmental factors affecting SGs during storage, transportation, and operation, analyzes the causes of surface corrosion, and points out the specialized protection requirements for SG surfaces. The paper also provides a comprehensive overview of the current development status of coating protection technologies, aiming to serve as a reference for addressing corrosion and protection challenges on steam generator surfaces.

Key wordsnuclear power    steam generator    coating    protection technology
收稿日期: 2025-06-17      32134.14.1005.4537.2025.183
ZTFLH:  TG174  
基金资助:中央高校基本科研业务费(N25DCG001)
通讯作者: 王金龙,E-mail:wangjinlong@mail.neu.edu.cn,研究方向为特种防护涂层
Corresponding author: WANG Jinlong, E-mail: wangjinlong@mail.neu.edu.cn
作者简介: 刘 虎,男,1981年生,高级工程师
图1  蒸汽发生器的结构
图2  大亚湾核电蒸汽发生器各部位的温度变化
CountryRadiation resistanceDesign basis accidentRadioactive decontaminationChemical resistance
AmericaASTM D 4082ASTM D 3911ASTM D 3912
FranceNF T 30-903NF T 30-900NF T 30-901
China

EJ/T 1111

NB/T 20133.3

EJ/T 1086

NB/T 20133.2

EJ/T 1112

NB/T 20133.4

EJ/T 1087

NB/T 20133.5

OthersISO 8690ISO 2812-1
表1  核电站防护涂层的标准规范[39]
BrandProperty

Steam Generator of M310 Reactor

CARBOLINE 4674

1. Modified silicone resin base, Single component

2. Continuous temperature resistance of 399 ℃; Instantaneous temperature resistance of 538 ℃;

3. Low volatility of VOC, maximum 640 g/L;

4. Fine radiation resistance;

5. Not suitable for immersion and exposure to splashing and spilling acid and alkali solvents

Steam Generator of AP1000 Reactor

Ameron Dimetcoat D6N/D9

1. Two component moisture curable ethyl silicate zinc rich primer;

2. Continuous temperature resistance of 400 ℃; Instantaneous temperature resistance of 540 ℃;

3. Low volatility of VOC, maximum 480 g/L;

4. Good low temperature curing performance, impact resistance and wear resistance;

5. Fine radiation resistance;

6. Not suitable for immersion and exposure to splashing and spilling acid and alkali solvents.

Steam Generator of Hualong-1 Reactor

Xinhe Hi-Temp primer 7501; Xinhe Hi-Temp topcoat 7506

1. Organic silicate ester paint, zinc powder, temperature resistant filler;

2. Continuous temperature resistance of 550 ℃;

3. Good low temperature curing performance, impact resistance and wear resistance;

4. Fine radiation resistance.

表2  核电站蒸汽发生器表面涂料使用情况[48]
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