富镍导电涂层在模拟海水中的耐蚀性能研究

doi:10.11902/1005.4537.2016.140

中国腐蚀与防护学报

2017, Vol. 37

Issue (2): 189-194 DOI: 10.11902/1005.4537.2016.140

研究报告

本期目录 | 过刊浏览

富镍导电涂层在模拟海水中的耐蚀性能研究

张心华¹,周仲康¹,徐群杰²,陈晓春¹,闫爱军³,廖强强²(

),葛红花²

1 国网安徽省电力公司电力科学研究院合肥 230601
2 上海电力学院上海市电力材料防护与新材料重点实验室上海 200090
3 中国大唐集团科学技术研究院有限公司西北分公司西安 710065

Anti-corrosion Performance of Nickel-rich Conductive Coatings in Simulated Seawater

Xinhua ZHANG¹,Zhongkang ZHOU¹,Qunjie XU²,Xiaochun CHEN¹,Aijun YAN³,Qiangqiang LIAO²(

),Honghua GE²

1 State Grid Anhui Electric Power Company Electric Power Research Institute, Hefei 230601, China
2 Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai 200090, China
3 China Datang Corporation Science and Technologic Research Institute Co., Ltd, Northwest Branch,Xi'an 710065, China

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摘要:

在高黏度的丙烯酸树脂中加入镍粉、消泡剂及其它助剂制备出具有导电功能的防腐涂料并涂覆在作为船舶材料的20#碳钢上。通过测试涂层的表面接触电阻来表征涂层的导电性,研究发现镍粉含量越高,涂层的导电性越好。用电化学阻抗谱研究了不同镍粉含量的导电涂层在模拟海水中的耐蚀性,并用扫描电镜 (SEM) 观察了浸泡90 d后涂层的表面形貌。结果表明,随浸泡时间的延长,镍粉的含量越高,涂层的容抗弧、阻抗、相位角、|Z |_0.05越小;且下降的越快;从Tafel极化曲线可知,镍粉含量越高,涂层的腐蚀电流越大;从涂层表面的SEM像可知,镍粉含量越高,涂层表面腐蚀越严重。在所研究的体系中,镍粉的含量约在20% (质量分数) 时,具有较好的导电性能和耐蚀性能。

关键词 ：导电涂料, 镍粉, 导电性, 耐蚀性

Abstract：

Conductive anticorrosion coatings were prepared with high viscosity acrylic resin as matrix, Ni- powder and defoamer etc. as additives, and then applied on 20# carbon steel. The electrical conductivity and the anti-corrosion performance in simulated seawater of the coatings with different Ni-powder content were characterized by means of surface contact resistance measurement, electrochemical impedance spectroscopy, and scanning electron microscopy respectively. Results show that with the increasing amount of Ni-powder, the electrical conductivity of the coatings increased. While, as the longer of the immersion time and the higher amount of the Ni-powder are, the lower of the capacitive reactance arc, the impedance, the phase angle and |Z |_0.05 of the coatings are. For a desired immersion time, the higher amount of the Ni-powder is, the faster decline of the capacitive reactance arc, the impedance, the phase angle and the |Z |_0.05 of the coatings is. According to Tafel polarization result, the higher amount of the Ni-powder is, the greater of the corrosion current of coatings is. It is concluded that with the higher amount of Ni-powder, the coatings exhibit better electrical conductivity, but the lower of the viscosity and worse corrosion resistance. A coating with about 20% Ni-powder possesses a comprehensive performance with better electrical conductivity and corrosion resistance.

Key words： conductive coating nickel powder electrical conductivity anti-corrosion performance

收稿日期: 2016-09-01

基金资助:上海市科委项目 (14DZ2261000) 和国家电网公司科技项目(5226SX13044J)

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引用本文:

张心华,周仲康,徐群杰,陈晓春,闫爱军,廖强强,葛红花. 富镍导电涂层在模拟海水中的耐蚀性能研究[J]. 中国腐蚀与防护学报, 2017, 37(2): 189-194.
Xinhua ZHANG, Zhongkang ZHOU, Qunjie XU, Xiaochun CHEN, Aijun YAN, Qiangqiang LIAO, Honghua GE. Anti-corrosion Performance of Nickel-rich Conductive Coatings in Simulated Seawater. Journal of Chinese Society for Corrosion and protection, 2017, 37(2): 189-194.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2016.140 或 https://www.jcscp.org/CN/Y2017/V37/I2/189

图1 导电涂层的表面接触电阻率与镍粉含量的关系

图2 不同Ni含量涂层在3.5%NaCl溶液中浸泡2,16和36 d后的Bode图

图3 不同Ni含量涂层的|Z |0.05随浸泡时间的变化

图4 不同Ni含量涂层的极化曲线

表1 不同Ni含量涂层在3.5%NaCl溶液中的Tafel曲线拟合结果

图5 不同Ni含量涂层在3.5%NaCl溶液中浸泡40 d后表面的SEM像

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