含CO2 地层水环境温度变化对J55钢腐蚀行为的影响

doi:10.11902/1005.4537.2025.047

中国腐蚀与防护学报

2025, Vol. 45

Issue (6): 1689-1697 CSTR: 32134.14.1005.4537.2025.047 DOI: 10.11902/1005.4537.2025.047

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含CO₂ 地层水环境温度变化对J55钢腐蚀行为的影响

赵彪¹, 张永强²^,³, 田会云¹(

), 逄昆¹, 崔中雨¹

1 中国海洋大学材料科学与工程学院青岛 266404
2 陕西省二氧化碳封存与提高采收率重点实验室西安 710065
3 陕西延长石油(集团)有限责任公司研究院西安 710065

Effect of Temperature Variation on Corrosion Behavior of J55 Steel in an Artificial CO₂-saturated Formation Water

ZHAO Biao¹, ZHANG Yongqiang²^,³, TIAN Huiyun¹(

), PANG Kun¹, CUI Zhongyu¹

1 School of Materials Science and Engineering, Ocean University of China, Qingdao 266404, China
2 Shaanxi Key Laboratory of Carbon Dioxide Sequestration and Enhanced Oil Recovery, Xi'an 710065, China
3 Shaanxi Yanchang Petroleum (Group) Limited Corperation Research Institute, Xi'an 710065, China

引用本文:

赵彪, 张永强, 田会云, 逄昆, 崔中雨. 含CO₂ 地层水环境温度变化对J55钢腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2025, 45(6): 1689-1697.
Biao ZHAO, Yongqiang ZHANG, Huiyun TIAN, Kun PANG, Zhongyu CUI. Effect of Temperature Variation on Corrosion Behavior of J55 Steel in an Artificial CO₂-saturated Formation Water[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(6): 1689-1697.

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摘要:

为了探究含CO₂地层水环境下不同温度对油井管钢腐蚀行为的影响，对J55钢石油套管钢在含CO₂溶液中浸泡10、30和50 d后的腐蚀性能进行了研究。结果表明，在不同温度下，随着浸泡时间的延长，J55钢腐蚀速率均呈现先降低后升高的趋势，其中在25 ℃时腐蚀速率最高，-20 ℃时最低。XRD结果显示，试样腐蚀产物主要由FeCO₃组成，同时伴有Fe₂O₃、α-FeOOH和γ-FeOOH。SEM结果显示，在常温条件下，不同浸泡时间的试样表面均覆盖一层疏松多孔的锈层，而低温条件下，试样表面附着腐蚀产物较少且多呈团聚状态。试样表面三维形貌分析表明，所有试样均表现出点蚀特征，不同温度下，随着浸泡时间的延长，蚀坑深度和最大体积均逐渐增加。

关键词 ： J55钢, CO₂腐蚀, 温度变化, 油田地层水

Abstract：

The influence of temperature on the corrosion behavior of J55 petroleum casing steel in an artificial CO₂-containing formation water was studied by immersion test at 25, 0 and -20 ^oC for 10, 30, and 50 d respectively. The results indicate that the corrosion rate of J55 steel at different temperatures decreased in the initial stage and then increased with prolonged immersion time. The highest corrosion rate was observed at 25 ^oC, while the lowest occurred at -20 ^oC. XRD analysis revealed that the corrosion products on the steel consisted mainly of FeCO₃, along with Fe₂O₃, α-FeOOH, and γ-FeOOH. SEM results showed that after corrosion at ambient temperature for different immersion periods, the steel surfaces were covered with a loose and porous rust layer after, whereas at low temperatures, fewer corrosion products adhered to the surface, mostly as agglomerated clusters. 3D surface topography analysis demonstrated that all the test steels exhibited pitting corrosion characteristics. Furthermore, with the increasing immersion time at different temperatures, both the depth and maximum volume of the corrosion pits progressively increased.

Key words： J55 steel CO₂ corrosion temperature change oilfield formation water

收稿日期: 2025-02-17 32134.14.1005.4537.2025.047

ZTFLH:

TG174

基金资助:国家重点研发计划(2023YFB3710300);陕西省二氧化碳封存与提高采收率重点实验室开放课题(YJSYZX25SKF0019)

通讯作者: 田会云，E-mail：tianhuiyun@ouc.edu.cn，研究方向为海洋局部微环境中金属材料的腐蚀与防护

Corresponding author: TIAN Huiyun, E-mail: tianhuiyun@ouc.edu.cn

作者简介: 赵彪，男，1998年生，硕士生

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https://www.jcscp.org/CN/10.11902/1005.4537.2025.047 或 https://www.jcscp.org/CN/Y2025/V45/I6/1689

图1 J55钢显微组织形貌

图2 J55钢在地层水环境中不同温度下浸泡10、30和50 d的腐蚀失重与腐蚀速率

图3 J55钢在不同温度下地层水环境中腐蚀10、30和50 d后的宏观形貌

图4 J55钢在不同温度下地层水环境中腐蚀10、30和50 d后的腐蚀产物微观形貌

图5 J55钢在不同温度下地层水环境中腐蚀10、30和50 d除锈后的微观形貌

图6 J55钢在不同温度下地层水环境中腐蚀50 d后表面XRD谱图

图7 J55钢在不同温度下地层水环境中腐蚀10、30和50 d后表面蚀坑三维形貌图

图8 J55钢在不同温度下地层水环境中腐蚀10、30和50 d后表面蚀坑最大体积、点蚀最大深度以及点蚀平均深度

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