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中国腐蚀与防护学报  2021, Vol. 41 Issue (4): 535-541    DOI: 10.11902/1005.4537.2020.139
  研究报告 本期目录 | 过刊浏览 |
高钢级油井管在高温高压气井全生命周期环境中的腐蚀行为及寿命预测
赵密锋1, 付安庆2(), 胡芳婷1, 谢俊峰1, 龙岩2, 耿海龙1
1.中国石油塔里木油田公司油气工程研究院 库尔勒 841000
2.中国石油集团石油管工程技术研究院 石油管材及装备材料服役行为与结构安全国家重点实验室 西安 710077
Corrosion Behavior and Life Prediction of High Grade OCTG in Full-life-cycle Environment of High Temperature High Pressure Gas Well
ZHAO Mifeng1, FU Anqing2(), HU Fangting1, XIE Junfeng1, LONG Yan2, GENG Hailong1
1.Oil and Gas Engineering Research Institute, Petro China Tarim Oilfield Company, Korla 841000, China
2.State Key Laboratory for Performance and Structure Safety of Petroleum Tubular Goods and Equipment Materials, CNPC Tubular Goods Research Institute, Xi'an 710077, China
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摘要: 

采用高温高压腐蚀测试系统研究了140ksi高钢级油井管在高温高压气井全生命周期单环境和连续多环境中的腐蚀行为。结果表明,140ksi高钢级油井管在全生命周期单环境和连续多环境中的腐蚀速率均呈现为CR鲜酸>CR残酸>CR地层水>CR凝析水的趋势,其中连续多环境中腐蚀行为表现出一定的“遗传效应”。地层水腐蚀介质中,140ksi高钢级油井管在单环境和连续多环境的腐蚀速率均随实验周期增加而减小,60 d后腐蚀速率趋于稳定。基于点蚀速率结果,采用有限元方法计算得到不同腐蚀状态下140ksi高钢级油井管的服役寿命。

关键词 高钢级油井管全生命周期单环境连续多环境寿命    
Abstract

The corrosion behavior of 140ksi high grade steels, namely the so-called oil country tubular goods (OCTG), in the single environment and multi-consecutive environment in the full-life-cycle of high pressure and high temperature gas wells was systematically studied via high pressure and high temperature corrosion testing system. The results showed that the decreasing trend of corrosion rates of 140ksi high grade OCTG steels in both single environment tests and multi-consecutive environment tests could be ranked as follows: CRfresh acid>CRused acid>CRformation water>CRcondensate water, and some “genetic effects” were also observed in the multi-consecutive environment tests. The corrosion rates of 140ksi high grade OCTG steels decreased with the increase of test time in the formation water for both single environment tests and multi-consecutive environment tests, which tended to be stable after 60 d exposure. Based on the pitting rates, the service life of 140ksi high grade OCTG steels under different corrosion conditions was calculated using the finite element method.

Key wordshigh grade OCTG    full-life-cycle    single environment    multi-consecutive environment    lifetime
收稿日期: 2020-08-01     
ZTFLH:  TG174  
基金资助:国家重点研发计划(2019YFF0217502);中石油重大科技专项(2018E-1809)
通讯作者: 付安庆     E-mail: fuanqing@cnpc.com.cn
Corresponding author: FU Anqing     E-mail: fuanqing@cnpc.com.cn
作者简介: 付安庆,男,1981年生,博士,高级工程师

引用本文:

赵密锋, 付安庆, 胡芳婷, 谢俊峰, 龙岩, 耿海龙. 高钢级油井管在高温高压气井全生命周期环境中的腐蚀行为及寿命预测[J]. 中国腐蚀与防护学报, 2021, 41(4): 535-541.
Mifeng ZHAO, Anqing FU, Fangting HU, Junfeng XIE, Yan LONG, Hailong GENG. Corrosion Behavior and Life Prediction of High Grade OCTG in Full-life-cycle Environment of High Temperature High Pressure Gas Well. Journal of Chinese Society for Corrosion and protection, 2021, 41(4): 535-541.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.139      或      https://www.jcscp.org/CN/Y2021/V41/I4/535

Full-life-cycle environmentComposition / mg·L-1pHTemperature / ℃Time
Live acid (LA)10%HCl+1.5%HF+3%HAc+5%TG201 corrosion inhibitor10%~20% acid solution1204 h
Spent acid (SA)K+ / 1597.32, Ca2+ / 11693.00, Mg2+ / 3145.63, Cl- / 62738.01, Fe2+/52.402.61805 d
Condensate water (CW)K+ / 7380, Ca2+ / 4.745, Mg2+ / 2.463, Na+ / 1050,HCO3- / 4310, Cl- / 2990, SO42- / 8627.7918010 d
Formation water (FW)K+ / 6620, Ca2+ / 8310, Mg2+ / 561, Na+ / 76500, HCO3- / 189, Cl- / 128000, SO42- / 4306.9818015, 30, 60 and 90 d
表1  气井全生命周期环境的腐蚀介质特征
图1  基于气井全生命周期的油井管腐蚀评价方法
图2  高钢级油井管在气井全生命周期单环境和连续多环境中的腐蚀速率对比
图3  高钢级油井管在气井全生命周期单环境中的微观腐蚀形貌
图4  高钢级油井管在气井全生命周期连续多环境中的微观腐蚀形貌
图5  点蚀深度的累计概率分布
图6  高钢级油井管在气井全生命周期连续多环境中 (60 d地层水) 的点蚀坑
1 He J C, Li C L, Jing Y L. Current situation of special casing and countermeasures of Baotou Steel (Group) Corporation [J]. Sci. Technol. Baotou Steel (Group) Corp., 2007, 33(6): 1
1 贺景春, 李春龙, 井溢龙. 特殊套管国内外发展现状及包钢的对策 [J]. 包钢科技, 2007, 33(6): 1
2 Li P Q, Shi J Q, Zhao G X, et al. Service conditions and current R & D situation of oil tubing and casing (Part I) [J]. Steel Pipe, 2008, 37(4): 6
2 李平全, 史交齐, 赵国仙等. 油套管的服役条件及产品研制开发现状 (上) [J]. 钢管, 2008, 37(4): 6
3 Li P Q, Shi J Q, Zhao G X, et al. Service conditions and current R & D situation of oil tubing and casing (Part II) [J]. Steel Pipe, 2008, 37(5): 11
3 李平全, 史交齐, 赵国仙等. 油套管的服役条件及产品研制开发现状 (下) [J]. 钢管, 2008, 37(5): 11
4 Zhao X W, Liu R, Jiang Y, et al. Analysis of corrosion mechanism of casing damage well in Changqing oilfield and prevention and control technology [A]. The International Petroleum & Petrochemical Technology Conference 2018 [C], 20182074: 1
5 Mu L J, Zhao W Z. Effect of pre-strain states on electronic property of passive film on J55 pipeline steel in Changqing Oilfield Luo-he stratum water [J]. J. Chin. Soc. Corros. Prot., 2010, 30: 491
5 慕立俊, 赵文轸. 预应变状态对J55油套管钢在长庆油田地下洛河水中腐蚀电化学性能的影响 [J]. 中国腐蚀与防护学报, 2010, 30: 491
6 Zhao Y, Qi W L, Xie J F, et al. Investigation of the failure mechanism of the TG-201 inhibitor: Promoting the synergistic effect of HP-13Cr stainless steel during the well completion [J]. Corros. Sci., 2020, 166: 108448
7 Li J P, Zhao G X, Hao S M. Dynamic corrosion behaviors of N80, P105 and SM110 steel [J]. J. Chin. Soc. Corros. Prot., 2005, 25: 241
7 李建平, 赵国仙, 郝士明. 几种因素对油套管钢CO2腐蚀行为影响 [J]. 中国腐蚀与防护学报, 2005, 25: 241
8 Gong N, Zhang Q L, Li J, et al. New method of casing selection in carbon dioxide corrosion environment and its application [J]. Surf. Technol., 2017, 46(10): 224
8 龚宁, 张启龙, 李进等. 二氧化碳腐蚀环境下套管选材新方法及应用 [J]. 表面技术, 2017, 46(10): 224
9 Feng H Z, Xing X J, Gu L, et al. Corrosion behavior of T95 casing in high temperature, high pressure and high H2S condition [J]. Surf. Technol., 2018, 47(12): 21
9 冯桓榰, 邢希金, 谷林等. 高温高压高含硫气井T95技术套管腐蚀实验研究 [J]. 表面技术, 2018, 47(12): 21
10 Fan Y P, Zhou Y N. Effects of H2S/CO2 corrosion scale on corrosion behavior of T95 casing steel at different temperature [J]. Surf. Technol., 2016, 45(10): 180
10 范亚萍, 周怡诺. 不同温度下H2S/CO2腐蚀产物膜对T95套管腐蚀行为的影响 [J]. 表面技术, 2016, 45(10): 180
11 Yang X T, Xiao W W, Liu H T, et al. Method of evaluating corrosion rate of formates to casing and tubing strings and the influencing factors [J]. Drill. Fluid Complet. Fluid, 2016, 33(6): 51
11 杨向同, 肖伟伟, 刘洪涛等. 甲酸盐对套管/油管腐蚀速率评价方法与影响因素 [J]. 钻井液与完井液, 2016, 33(6): 51
12 Bai H T, Yang M, Dong X W, et al. Research progress on CO2 corrosion product scales of carbon steels [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 295
12 白海涛, 杨敏, 董小卫等. CO2腐蚀产物膜的研究进展 [J]. 中国腐蚀与防护学报, 2020, 40: 295
13 Chen C F, Lu M X, Zhao G X, et al. Behavior of CO2 pitting corrosion of N80 steel [J]. J. Chin. Soc. Corros. Prot., 2003, 23: 21
13 陈长风, 路民旭, 赵国仙等. N80油管钢CO2腐蚀点蚀行为 [J]. 中国腐蚀与防护学报, 2003, 23: 21
14 Li Y, Li C Y, Chen X, et al. Gray relationship analysis on corrosion behavior of super 13Cr stainless steel in environments of marine oil and gas field [J]. J. Chin. Soc. Corros. Prot., 2018, 38: 471
14 李洋, 李承媛, 陈旭等. 超级13Cr不锈钢在海洋油气田环境中腐蚀行为灰关联分析 [J]. 中国腐蚀与防护学报, 2018, 38: 471
15 Zhao G X, Chen C F, Lu M X, et al. The formation of product scale and mass transfer channels during CO2 corrosion [J]. J. Chin. Soc. Corros. Prot., 2002, 22: 363
15 赵国仙, 陈长风, 路民旭等. CO2腐蚀的产物膜及膜中物质交换通道的形成 [J]. 中国腐蚀与防护学报, 2002, 22: 363
16 Lei X W, Fu A Q, Feng Y R, et al. Influence of HAc concentration and temperature on the electrochemical corrosion behavior of Super 13Cr stainless steel [J]. Corros. Prot., 2017, 38: 676
16 雷晓维, 付安庆, 冯耀荣等. 醋酸浓度和温度对超级13Cr不锈钢电化学腐蚀行为的影响 [J]. 腐蚀与防护, 2017, 38: 676
17 Xie J F, Fu A Q, Qin H D, et al. Influence of surface imperfection on corrosion behavior of 13Cr tubing in gas well acidizing process [J]. Surf. Technol., 2018, 47(6): 51
17 谢俊峰, 付安庆, 秦宏德等. 表面缺欠对超级13Cr油管在气井酸化过程中的腐蚀行为影响研究 [J]. 表面技术, 2018, 47(6): 51
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