玻璃钢复合材料耐海水腐蚀性能及抗Cl<sup>-</sup>渗透寿命预测

doi:10.11902/1005.4537.2015.173

中国腐蚀与防护学报

2016, Vol. 36

Issue (4): 357-362 DOI: 10.11902/1005.4537.2015.173

研究报告

本期目录 | 过刊浏览

玻璃钢复合材料耐海水腐蚀性能及抗Cl^-渗透寿命预测

聂亚楠¹,沈浩²,谷坤鹏¹,王成启¹(

)

1. 中交上海三航科学研究院有限公司上海 200032
2. 上海宏韵新型建材有限公司上海 201500

Seawater Corrosion Resistance and Service Life Prediction of Glass Fiber Reinforced Plastic Composites

Yanan NIE¹,Hao SHEN²,Kunpeng GU¹,Chengqi WANG¹(

)

1. CCCC Shanghai Third Harbor Engineering Science & Technology Research Institute Co., Ltd., Shanghai 200032, China
2. Shanghai HongYun New Construction Materials Co., Ltd., Shanghai 201500, China

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摘要:

采用70 ℃、3.5% (质量分数) 的海盐溶液对不饱和聚酯玻璃钢及环氧乙烯基酯玻璃钢进行加速老化实验,研究了玻璃钢的耐海水腐蚀性能,并对2 mm厚的玻璃钢防护层的抗Cl^-渗透寿命进行了预测。结果表明：不饱和聚酯玻璃钢在海水中容易发生水解腐蚀,其抗Cl^-渗透寿命约为30 a;而环氧乙烯基酯玻璃钢的抗Cl^-渗透寿命约为70 a,具有更好的耐海水腐蚀性能。

关键词 ：玻璃钢, 加速老化, 抗Cl-渗透, 寿命预测

Abstract：

The anti-corrosion performance of glass fiber reinforced plastic (GFRP) composites was evaluated by immersion test in 3.5% (mass fraction) sea salt solutions at 70 ℃ in terms of the decreasing trend of the pH value of the solution, the mass variation rate, and the bending strength retention rate of GFRP composites with time. While the surface morphology of the fractured surface of the composites, especially the glass fiber/resin interface before and after corrosion was examined by SEM. The concrete sample wrapped with GFRP composites was used to examine the time when Cl^- penetrated through the GFRP layer. And, the life of resistance to Cl^- penetration of 2 mm thick GFRP composites was predicted. Results showed that the life of resistance to Cl^- penetration for the unsaturated ester based GFRP composite was about 30 a; while the epoxy vinyl ester based GFRP composite was about 70 a.

Key words： glass fiber reinforced plastic accelerated aging resistance to Cl- penetration life prediction

基金资助:中国交通建设股份有限公司科技开发项目 (2012-ZJKJ-13)资助

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聂亚楠,沈浩,谷坤鹏,王成启. 玻璃钢复合材料耐海水腐蚀性能及抗Cl^-渗透寿命预测[J]. 中国腐蚀与防护学报, 2016, 36(4): 357-362.
Yanan NIE, Hao SHEN, Kunpeng GU, Chengqi WANG. Seawater Corrosion Resistance and Service Life Prediction of Glass Fiber Reinforced Plastic Composites. Journal of Chinese Society for Corrosion and protection, 2016, 36(4): 357-362.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2015.173 或 https://www.jcscp.org/CN/Y2016/V36/I4/357

图1 质量变化率与加速老化时间的关系

图2 弯曲强度保留率与加速老化时间的关系

图3 189不饱和聚酯玻璃钢加速老化前后断面SEM像

图4 MFE-2环氧乙烯基酯玻璃钢加速老化前后断面SEM像

图5 自然海洋环境下玻璃钢的弯曲强度保留率与老化时间的关系[13]

图6 加速老化条件下不饱和聚酯玻璃钢弯曲强度保留率与老化时间的关系

表1 不同老化时间渗入混凝土表层Cl-含量

[1]	Wu J Q, Qian F F, Wang P, et al.Development of research on steel pipe pile durability and application[J]. J. Ningbo Eng. Univ. Technol., 2010, 22(3): 66
[1]	(吴军强, 钱菲菲, 王鹏等. 钢管桩耐久性研究的发展与应用[J]. 宁波工程学院学报, 2010, 22(3): 66)
[2]	Cheng X D, Sun L F, Cao Z F, et al.Cracking process analysis of concrete cover caused by non-uniform corrosion[J]. J. Chin. Soc. Corros. Prot., 2015, 35(3): 257
[2]	(程旭东, 孙连方, 曹志烽等. 钢筋非均匀锈蚀导致的混凝土保护层锈胀开裂过程分析[J]. 中国腐蚀与防护学报, 2015, 35(3): 257)
[3]	Chang A L, Song S Z.A preliminary on corrosion monitoring and detecting of metal structure in simulated sea splash zone[J]. J. Chin. Soc. Corros. Prot., 2012, 32(3): 247
[3]	(常安乐, 宋诗哲. 模拟海洋环境浪花飞溅区的金属构筑物腐蚀监检测[J]. 中国腐蚀与防护学报, 2012, 32(3): 247)
[4]	Wang D D, Wang C Q, Shi B L, et al.Field sampling, analysis and research on durability of large diameter cylindrical piles[J]. Chin. Harbor Eng., 2008, (1): 39
[4]	(汪冬冬, 王成启, 时蓓玲等. 大管桩现场取样分析与耐久性研究[J]. 中国港湾建设, 2008, (1): 39)
[5]	Cai R H.Discussion on design useful life of 100 years of piled wharfs[J]. Chin. Harbor Eng., 2009, (2): 21
[5]	(蔡锐华. 试论高桩码头设计使用年限100 年[J]. 中国港湾建设, 2009, (2): 21)
[6]	Bian L, Xiao J, Zeng J, et al.Effects of seawater immersion on water absorption and mechanical properties of GFRP composites[J]. J. Compos. Mater., 2012, 46(25): 3151
[7]	Berketis K, Tzetzis D, Hogg P J.The influence of long term water immersion ageing on impact damage behaviour and residual compression strength of glass fibre reinforced polymer (GFRP)[J]. Mater. Des., 2008, 29(7): 1300
[8]	Hiroaki A, Yoshikazu M, Hiromasa N.Long-term exposure test for corrosion control of steel pipe piles [A]. Coast Technology Research Center Symposium[C]. Tokyo, 2006
[9]	Lu X F.Anti-corrosion technology of PHC piles of Donghai bridge [A]. The 14th Asia Pacific Corrosion Control Meeting Modern Bridge Structure Anticorrosion Technology BBS Symposium[C]. Shanghai, 2007
[9]	(陆旭峰. 东海大桥PHC管桩防腐蚀技术 [A]. 第十四届亚太腐蚀控制会议现代桥梁结构防腐蚀技术论坛文集[C]. 上海, 2007)
[10]	Huang G.Behaviors of glass fiber/unsaturated polyester composites under seawater environment[J]. Mater. Des., 2009, 30(4): 1337
[11]	Dai H, Zhou R P.The molecular design of alkali-resisting epoxy vinyl ester resins[J]. Fiber Reinf. Plast./Compos., 2014, (2): 59
[11]	(戴华, 周润培. 耐碱环氧乙烯基酯树脂的分子设计[J]. 玻璃钢/复合材料, 2014, (2): 59)
[12]	Assarar M, Scida D, El Mahi A, et al.Influence of water ageing on mechanical properties and damage events of two reinforced composite materials: Flax-fibres and glass-fibres[J]. Mater. Des., 2011, 32(2): 788
[13]	Zhou J.Properties research of GFRP composites after natural aging of 21 years[J]. Fiber Reinf. Plast./Compos., 1995, (4): 1
[13]	(周杰. 21年玻璃钢自然老化性能研究[J]. 玻璃钢/复合材料, 1995, (4): 1)

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