Preparation and Corrosion Resistance of Superamphiphobic Surface on B10 Cu-alloy

doi:10.11902/1005.4537.2023.290

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (4): 909-917 DOI: 10.11902/1005.4537.2023.290

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Preparation and Corrosion Resistance of Superamphiphobic Surface on B10 Cu-alloy

ZHANG Jihao, XU Yacheng, JIA Xueyuan, GAO Rongjie(

)

School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China

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ZHANG Jihao, XU Yacheng, JIA Xueyuan, GAO Rongjie. Preparation and Corrosion Resistance of Superamphiphobic Surface on B10 Cu-alloy. Journal of Chinese Society for Corrosion and protection, 2024, 44(4): 909-917.

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Abstract

A superamphiphobic surface film with good corrosion protection durability was successfully prepared on B10 Cu-alloy by chemical etching with 1.5 mol/L FeCl₃ solution and then modifying with 1H,1H,2H,2H-perfluorodecyltriethoxysilane. The contact angle of water and ethylene glycol on the prepared surface is 158° and 151° respectively. The morphology, chemical composition and corrosion resistance of the superamphiphobic surface film/B10 Cu-alloy were characterized by means of SEM, XRD, EDS and XPS as well as EIS test and Tafel polarization curve and electrochemical test. The results show that compared with the bare B10 Cu-alloy, the corrosion potential of the superamphiphobic surface film/B10 Cu-alloy is positively shifted to -0.248 V, its corrosion current density I_corr = 2.05 × 10^-6 A·cm^-2 decreases by one order of magnitude, and the charge transfer resistance increases by one order of magnitude, showing excellent corrosion resistance. The charge-transfer resistance of the superamphiphobic film/B10 Cu-alloy after immersion in 3.5%NaCl solution for 5 d is still significantly higher than that of the bare Cu-alloy, in other words, it still maintains good corrosion resistance.

Key words: superamphiphobic surface B10 copper alloy chemical etching anti-corrosion

Received: 12 September 2023 32134.14.1005.4537.2023.290

ZTFLH:

TG174

Fund: National Natural Science Foundation of China-Shandong Joint Fund(U1706221)

Corresponding Authors: GAO Rongjie, E-mail: dmh206@ouc.edu.cn

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	ZHANG Jihao
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https://www.jcscp.org/EN/10.11902/1005.4537.2023.290 OR https://www.jcscp.org/EN/Y2024/V44/I4/909

Fig.1 Schematic diagram of preparation process of superamphiphobic surface on B10 copper alloy

Fig.2 Change of contact angle of specimen surface under different concentration (a), temperature (b), etching time (c) and modification time (d)

Table1 Variation of contact angle on samples with different liquids under different processing conditions

Fig.3 Surface morphologies of bare sample (a) and superamphiphobic sample (b-d)

Fig.4 Laser confocal imaging of the surface of bare sample (a) and superamphiphobic sample (b)

Table 2 Surface roughness parameter of the bare sample and superamphiphobic sample

Fig.5 XRD pattern of the superamphiphobic sample

Fig.6 EDS mapping of bare sample in Fig.3a (a) and superamphiphobic sample in Fig.3b (b)

Fig.7 XPS spectra of superamphiphobic sample: (a) survey, (b) F 1s, (c) C 1s, (d) Si 2p

Fig.8 FT-IR spectrum of the as-prepared superamphiphobic surface with PFDTS modification

Fig.9 Potentiodynamic polarization curves of bare sample and superamphiphobic sample

Fig.10 Nyquist (a), impedance module (b) and phase angle (c) plots of the bare sample and superamphiphobic sample in 3.5%NaCl solution and its equivalent circuit (d)

Table 3 Electrochemical fitting parameters

[1]	Núñez L, Reguera E, Corvo F, et al. Corrosion of copper in seawater and its aerosols in a tropical island [J]. Corros. Sci., 2005, 47: 461
[2]	Zhu M L, Qian H J, Fan W H, et al. Surface lurking and interfacial ion release strategy for fabricating a superhydrophobic coating with scaling inhibition [J]. Petrol. Sci, 2022, 19: 3068
[3]	Yuan S J, Choong A M F, Pehkonen S O. The influence of the marine aerobic Pseudomonas strain on the corrosion of 70/30 Cu–Ni alloy [J]. Corros. Sci., 2007, 49: 4352
[4]	Appa Rao B V, Chaitanya Kumar K. 5-(3-Aminophenyl)tetrazole-A new corrosion inhibitor for Cu–Ni (90/10) alloy in seawater and sulphide containing seawater [J]. Arab. J. Chem., 2017, 10(suppl.2) : S2245
[5]	Jin T Z, Zhang W F, Li N, et al. Surface characterization and corrosion behavior of 90/10 copper-nickel alloy in marine environment [J]. Materials (Basel), 2019, 12: 1869
[6]	Darmanin T, Guittard F. Superhydrophobic and superoleophobic properties in nature [J]. Mater. Today, 2015, 18: 273
[7]	Li Y Q, Si W T, Gao R J. Facile preparation of superamphiphobic aluminum alloy surfaces and their corrosion resistance [J]. Surf. Coat. Technol., 2022, 430: 127997
[8]	Guo Z G, Liu W M. Biomimic from the superhydrophobic plant leaves in nature: Binary structure and unitary structure [J]. Plant Sci., 2007, 172: 1103
[9]	Huang P, Gao R J, Liu W B, et al. Fabrication of superamphiphobic surface for nickel-plate on pipeline steel by salt solution etching and its anti-corrosion properties [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 96
	黄鹏, 高荣杰, 刘文斌等. 盐溶液刻蚀-氟化处理制备X65管线钢镀镍超双疏表面及其耐蚀性研究 [J]. 中国腐蚀与防护学报, 2021, 41: 96
[10]	Liu Y, Han X Y, Chen C, et al. A fluorine-free and nanoparticle-free superhydrophobic coating: A mechanism and self-cleaning application investigation [J]. Appl. Surf. Sci., 2023, 608: 155103
[11]	Feng L B, Yan Z N, Shi X T, et al. Anti-icing/frosting and self-cleaning performance of superhydrophobic aluminum alloys [J]. Appl. Phys., 2018, 124A: 142
[12]	Xu Y H, Li X L, Wang X Y, et al. Synergistic effect of micro-nano surface structure and surface grafting on the efficient fabrication of durable super-hydrophobic high-density polyethylene with self-cleaning and anti-icing properties [J]. Appl. Surf. Sci., 2023, 611: 155654
[13]	Wang W, Dong C X, Liu S R, et al. Super-hydrophobic cotton aerogel with ultra-high flux and high oil retention capability for efficient oil/water separation [J]. Colloid. Surf., 2023, 657A: 130572
[14]	Zhao M Q, Ma X Q, Chao Y X, et al. Super-hydrophobic magnetic fly ash coated polydimethylsiloxane (MFA@PDMS) sponge as an absorbent for rapid and efficient oil/water separation [J]. Polymers (Basel), 2022, 14: 3726
[15]	Khedir K R, Saifaldeen Z S, Demirkan T M, et al. Robust superamphiphobic nanoscale copper sheet surfaces produced by a simple and environmentally friendly technique [J]. Adv. Eng. Mater., 2015, 17: 982
[16]	Liu T, Chen S G, Cheng S, et al. Corrosion behavior of super-hydrophobic surface on copper in seawater [J]. Electrochim. Acta, 2007, 52: 8003
[17]	Bai Z G, Zhu J Y. A facile preparation method for corrosion-resistant copper superhydrophobic surfaces with ordered microstructures by etching [J]. Coatings, 2023, 13: 1151
[18]	Meng X, Wang J L, Zhang J, et al. Electroplated super-hydrophobic Zn-Fe coating for corrosion protection on magnesium alloy [J]. Trans. Nonferrous Met. Soc. China, 2022, 32: 3250
[19]	Xi J M, Feng L, Jiang L. A general approach for fabrication of superhydrophobic and superamphiphobic surfaces [J]. Appl. Phys. Lett., 2008, 92: 053102
[20]	Guo M M, Liu M L, Zhao W, et al. Rapid fabrication of SERS substrate and superhydrophobic surface with different micro/nano-structures by electrochemical shaping of smooth Cu surface [J]. Appl. Surf. Sci., 2015, 353: 1277
[21]	Wan X F, Li Y, Tian C, et al. Fabrication and properties of super-hydrophobic microstructures on magnesium alloys by laser-chemical etching [J]. Appl. Phys., 2022, 128A: 899
[22]	Xiao Y T, Qi Y, Shen X J, et al. Preparation of a lotus-leaf-like coating with robust super-hydrophobicity and UV-resistant ability [J]. J. Inorg. Organomet. Polym. Mater., 2023, 33: 579
[23]	Mohammadshahi S, Breveleri J, Ling H J. Fabrication and characterization of super-hydrophobic surfaces based on sandpapers and nano-particle coatings [J]. Colloid. Surf., 2023, 666A: 131358
[24]	Lü C, Wang F Q, He C X, et al. Preparation of silicone-PCL composite particles with hierarchical structure and the super-hydrophobic fabrics via directly electrostatic spraying [J]. Surf. Coat. Technol., 2022, 449: 128933
[25]	Ma Z Y. Exploitation of the factors influencing chemical reaction rate [J]. Modern Chem. Res., 2017, (2): 7
	马志彦. 探究影响化学反应速率的因素 [J]. 当代化工研究, 2017, (2): 7
[26]	Chu Z L, Seeger S, et al. Superamphiphobic surfaces [J]. Chem. Soc. Rev., 2014, 43: 2784 doi: 10.1039/c3cs60415b pmid: 24480921
[27]	Yang J, Zhang Z Z, Xu X H. Superoleophobic textured aluminum surfaces [J]. New J. Chem., 2011, 35: 2422
[28]	Ghaffari S, Aliofkhazraei M, Barati Darband G, et al. Review of superoleophobic surfaces: Evaluation, fabrication methods, and industrial applications [J]. Surf. Interfaces, 2019, 17: 100340
[29]	Li Y Q, Si W T, Gao R J. Preparation of superamphiphobic surface on Al-alloy and its corrosion resistance [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 966
	李育桥, 司伟婷, 高荣杰. 铝合金超双疏表面的制备及其耐蚀性研究 [J]. 中国腐蚀与防护学报, 2022, 42: 966 doi: 10.11902/1005.4537.2021.339
[30]	Deng R, Hu Y M, Wang L, et al. An easy and environmentally-friendly approach to superamphiphobicity of aluminum surfaces [J]. Appl. Surf. Sci., 2017, 402: 301
[31]	Saleema N, Sarkar D K, Paynter R W, et al. Superhydrophobic aluminum alloy surfaces by a novel one-step process [J]. ACS Appl. Mater. Interfaces, 2010, 2: 2500
[32]	Zheng L, Luo S. Fabrication of a durable superhydrophobic surface with corrosion resistance on copper [J]. Int. J. Electrochem. Sci., 2023, 18: 100093
[33]	Ge B, Zhang Z Z, Men X H, et al. Sprayed superamphiphobic coatings on copper substrate with enhanced corrosive resistance [J]. Appl. Surf. Sci., 2014, 293: 271
[34]	Esmailzadeh S, Khorsand S, Raeissi K, et al. Microstructural evolution and corrosion resistance of super-hydrophobic electrodeposited nickel films [J]. Surf. Coat. Technol., 2015, 283: 337

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