Fabrication and Photocathodic Protection Performance of Bi2S3/TiO2 Nanocomposites for 304 Stainless Steel

doi:10.11902/1005.4537.2023.270

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (4): 901-908 DOI: 10.11902/1005.4537.2023.270

Current Issue | Archive | Adv Search

Fabrication and Photocathodic Protection Performance of Bi₂S₃/TiO₂ Nanocomposites for 304 Stainless Steel

YU Jiahui, WANG Tongtong, GAO Yun, GAO Rongjie(

)

School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China

Cite this article:

YU Jiahui, WANG Tongtong, GAO Yun, GAO Rongjie. Fabrication and Photocathodic Protection Performance of Bi₂S₃/TiO₂ Nanocomposites for 304 Stainless Steel. Journal of Chinese Society for Corrosion and protection, 2024, 44(4): 901-908.

Download:

HTML

PDF(5844KB)
Export: BibTeX | EndNote (RIS)

Abstract

TiO₂ nanotube arrays are decorated with Bi₂S₃ by a successive ionic layer adsorption and reaction (SILAR) method, aiming to enhance the photoelectric conversion ability of TiO₂ and photogenerated cathodic protection performance of TiO₂ nanotube arrays for 304 stainless steel. B-(x)/TiO₂ nanotubes (x = 1,3,5,7) were prepared by changing the number of deposition cycles of Bi₂S₃. The morphology, structure, light response ability and photogenerated carrier separation efficiency of Bi₂S₃/TiO₂ nanocomposites were examined by means of XRD, SEM and XPS. At the same time, the photoelectrochemical properties of Bi₂S₃/TiO₂ nanocomposites were tested under simulated sunlight. In addition, the effect of the number of deposition cycles of Bi₂S₃ on the photocathodic protection performance of TiO₂ nanocomposites was also studied. After Bi₂S₃ modification, the band gap of the composites decreases, and the recombination rate of photogenerated carriers decreases greatly. When a 5 cyclic deposition of Bi₂S₃ is adopted, the photoelectrochemical properties of the prepared nanocomposites are the best. Of which the band gap is reduced to 2.9 eV, and the photocurrent density is increased from 200 μA·cm^-2 to 550 μA·cm^-2 under the condition of turning on light, which is 2.75 times that of the bare TiO₂ nanotube arrays. After coupling the modified nanocomposite with 304 stainless steel, the coupling potential can be reduced to -1.0 V under simulated sunlight, which is about 80 mV lower than the coupling potential before modification, which can further improve the photogenerated cathodic protection effect on 304 stainless steel.

Key words: photogenerated cathodic protection modification Bi₂S₃/TiO₂ 304 stainless steel

Received: 31 August 2023 32134.14.1005.4537.2023.270

ZTFLH:

TG174

Fund: National Natural Science Foundation of China-Shandong Joint Fund(U1706221)

Corresponding Authors: GAO Rongjie, E-mail: dmh206@ouc.edu.cn

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	YU Jiahui
	WANG Tongtong
	GAO Yun
	GAO Rongjie

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2023.270 OR https://www.jcscp.org/EN/Y2024/V44/I4/901

Fig.1 Schematic diagram of the preparation process of TiO₂ nanotube arrays

Fig.2 Schematic diagram of the preparation process of Bi₂S₃/TiO₂ nanocomposites

Fig.3 Schematic diagram of electrochemical testing device

Fig.4 XRD patterns of TiO₂ nanotube_{arrays and Bi₂S₃/TiO₂ nanocomposite}

Fig.5 SEM images of TiO₂nanotube (a), B-1/TiO₂ (b), B-3/TiO₂ (c), B-5/TiO₂ (d) and B-7/TiO₂ (e) nanocomposites, and EDS spectrum of B-5/TiO₂ nanocomposite (f)

Fig. 6 EDS elemental mappings of B-5/TiO₂ nanocomposite: (a) Ti, (b) O, (c) Bi, (d) S

Fig.7 XPS spectra of B-5/TiO₂ nanocomposite: (a) survey spectrum, (b) Ti 2p, (c) O 1s, (d) Bi 4f, (e) S 2p

Fig.8 Tauc curves of UV-Vis diffuse reflectance spectra of TiO₂ nanotube and B-5/TiO₂ nanocomposite

Fig.9 Photoluminescence spectra of TiO₂ nanotube and B-x/TiO₂ nanocomposites

Fig.10 Photocurrent density-time curves of TiO₂ nanocomposites under intermittent visible light

Fig.11 Potential changes of 304 stainless steel coupled with TiO₂ nanocomposites under intermittent visible light

Fig.12 Nyquist plots (a) and equivalent circuit diagram (b) of TiO₂ nanocomposites under simulated sunlight

Table 1 Fitting parameters of EIS

Fig.13 Schematic diagram of the energy band structures of Bi₂S₃ and TiO₂ semiconductors

[1]	Zhang Y, Yin X Y, Yan F Y. Effect of halide concentration on tribocorrosion behaviour of 304SS in artificial seawater [J]. Corros. Sci., 2015, 99: 272
[2]	Zhang Y, Yin X Y, Yan Y F, et al. Tribocorrosion behaviors of 304SS: effect of solution pH [J]. RSC Adv., 2015, 5: 17676
[3]	Jiang J H, Zhang X Y, Jin Z Q. Research progress in photochemical cathodic protection technology [J]. Mar. Sci., 2021, 45(12): 150
	蒋继宏, 张小影, 金祖权. 光电化学阴极保护技术研究进展 [J]. 海洋科学, 2021, 45(12): 150
[4]	Chen F W, Liu B, Jian D H, et al. Research progress and existing problems of photocathodic protection technology [J]. J. Mater. Eng., 2021, 49(12): 83
	陈凡伟, 刘斌, 蹇冬辉等. 光生阴极保护技术的研究进展及其存在的问题 [J]. 材料工程, 2021, 49(12): 83 doi: 10.11868/j.issn.1001-4381.2021.000469
[5]	Subasri R, Shinohara T. Application of the photoeffect in TiO₂ for cathodic protection of copper [J]. Electrochemistry, 2004, 72: 880
[6]	Kumar S G, Devi L G. Review on modified TiO₂ photocatalysis under UV/Visible light: selected results and related mechanisms on interfacial charge carrier transfer dynamics [J]. J. Phys. Chem., 2011, 115A: 13211
[7]	Guo H X, Li L L, Su C, et al. Effective photocathodic protection for 304 stainless steel by PbS quantum dots modified TiO₂ nanotubes [J]. Mater. Chem. Phys., 2021, 258: 123914
[8]	Zheng L X, Teng F, Ye X Y, et al. Photo/electrochemical applications of metal sulfide/TiO₂ heterostructures [J]. Adv. Energy Mater., 2020, 10: 1902355
[9]	Luo J H, Wei H Y, Huang Q L, et al. Highly efficient core-shell CuInS₂-Mn doped CdS quantum dot sensitized solar cells [J]. Chem. Commun., 2013, 49: 3881
[10]	Yang L, Ma Y P, Liu J H, et al. Improving the performance of solid-state quantum dot-sensitized solar cells based on TiO₂/CuInS₂ photoelectrodes with annealing treatment [J]. RSC Adv., 2016, 6: 92869
[11]	Yang Y Y, Zhang W W, Xu Y, et al. Ag₂S decorated TiO₂ nanosheets grown on carbon fibers for photoelectrochemical protection of 304 stainless steel [J]. Appl. Surf. Sci., 2019, 494: 841
[12]	Cheng L Y, Ding H M, Chen C H, et al. Ag₂S/Bi₂S₃ co-sensitized TiO₂ nanorod arrays prepared on conductive glass as a photoanode for solar cells [J]. J. Mater. Sci., 2016, 27: 3234
[13]	Hu J, Guan Z C, Liang Y, et al. Bi₂S₃ modified single crystalline rutile TiO₂ nanorod array films for photoelectrochemical cathodic protection [J]. Corros. Sci., 2017, 125: 59
[14]	Li H, Wang X T, Wei Q Y, et al. Photocathodic protection of 304 stainless steel by Bi₂S₃/TiO₂ nanotube films under visible light [J]. Nanoscale Res. Lett., 2017, 12: 80
[15]	Li X L, Yang M, Zhu D, et al. Preparation of TiO₂/Bi₂S₃ composite photo-anode through ultrasound-assisted successive ionic layer adsorption and reaction method for improving the photoelectric performance [J]. J. Electron. Mater., 2020, 49: 3242
[16]	Zumeta-Dubé I, Ruiz-Ruiz V F, Díaz D, et al. TiO₂ sensitization with Bi₂S₃ quantum dots: the inconvenience of sodium ions in the deposition procedure [J]. J. Phys. Chem., 2014, 118C: 11495
[17]	Wang Q Y, Liu Z Y, Jin R C, et al. SILAR preparation of Bi₂S₃ nanoparticles sensitized TiO₂ nanotube arrays for efficient solar cells and photocatalysts [J]. Sep. Purif. Technol., 2019, 210: 798
[18]	Zhou M J, Zeng Z O, Zhong L. Photogenerated cathode protection properties of nano-sized TiO₂/WO₃ coating [J]. Corros. Sci., 2009, 51: 1386
[19]	Kubo T, Nakahira A. Local structure of TiO₂-derived nanotubes prepared by the hydrothermal process [J]. J. Phys. Chem., 2008, 112C: 1658
[20]	Antony R P, Mathews T, Dash S, et al. X-ray photoelectron spectroscopic studies of anodically synthesized self aligned TiO₂ nanotube arrays and the effect of electrochemical parameters on tube morphology [J]. Mater. Chem. Phys., 2012, 132: 957
[21]	He H C, Berglund S P, Xiao P, et al. Nanostructured Bi₂S₃/WO₃ heterojunction films exhibiting enhanced photoelectrochemical performance [J]. J. Mater. Chem., 2013, 1A: 12826
[22]	Weng B, Zhang X, Zhang N, et al. Two-dimensional MoS₂ nanosheet-coated Bi₂S₃ discoids: synthesis, formation mechanism, and photocatalytic application [J]. Langmuir, 2015, 31: 4314 doi: 10.1021/la504549y pmid: 25625414
[23]	Chen L, He J, Yuan Q, et al. CuS-Bi₂S₃ hierarchical architectures: controlled synthesis and enhanced visible-light photocatalytic performance for dye degradation [J]. RSC Adv., 2015, 5: 33747
[24]	Lin Z Q, Lai Y K, Hu R G, et al. A highly efficient ZnS/CdS@TiO₂ photoelectrode for photogenerated cathodic protection of metals [J]. Electrochim. Acta, 2010, 55: 8717
[25]	Li X L, Wang X Y, Liu J L, et al. Bismuth sulfide decorated TiO₂ arrays heterojunction assembly for enhanced photoelectrochemical performance [J]. Optik, 2022, 252: 168522
[26]	Su N, Ye M Y, Li J M, et al. Fabrication of ZIF-8/TiO₂ composite film and its photogeneration cathodic protection performance [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 267
	苏娜, 叶梦颖, 李建民等. ZIF-8/TiO₂纳米复合材料的制备及光生阴极保护性能 [J]. 中国腐蚀与防护学报, 2022, 42: 267
[27]	Wang W C, Wang X T, Wang N, et al. Bi₂Se₃ sensitized TiO₂ nanotube films for photogenerated cathodic protection of 304 stainless steel under visible light [J]. Nanoscale Res. Lett., 2018, 13: 295
[28]	Jiao Z B, Zhang Y, Chen T, et al. TiO₂ nanotube arrays modified with Cr-Doped SrTiO₃ nanocubes for highly efficient hydrogen evolution under visible light [J]. Chem. Eur. J., 2014, 20: 2654
[29]	Bao C Y, Li J M, Ye M Y, et al. Preparation of TiO₂ nanotube arrays in composite electrolytes and their photogenerated cathodic protection performance [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 759
	鲍晨宇, 李建民, 叶梦颖等. 复合电解液中TiO₂纳米管阵列的制备及光生阴极保护性能 [J]. 中国腐蚀与防护学报, 2022, 42: 759 doi: 10.11902/1005.4537.2021.255
[30]	Cai F G. Fabrication and photoelectrochemical properties study of Bi₂S₃/PbS-sensitized TiO₂nanotube arrays [D]. Chengdu: Southwest Jiaotong University, 2013
	蔡芳共. Bi₂S₃、PbS敏化TiO₂纳米管阵列的制备及其光电性能研究 [D]. 成都: 西南交通大学, 2013
[31]	Wang B, Cao J T, Dong Y X, et al. An in situ electron donor consumption strategy for photoelectrochemical biosensing of proteins based on ternary Bi₂S₃/Ag₂S/TiO₂NT arrays [J]. Chem. Commun., 2018, 54: 806

[1]	LI Hongling, LANG Wuke. Environmentally Friendly Anticorrosive Materials-Preparation and Research Progress of Polyaniline Nanocomposites[J]. 中国腐蚀与防护学报, 2024, 44(4): 874-882.
[2]	QIAO Ze, LI Qingquan, LIU Xiaohang, LI Yizhou. Effect of Nitrate and Galvanic Couple on Crevice Corrosion Behavior of 7075-T651 Al-alloy in Neutral NaCl Solution[J]. 中国腐蚀与防护学报, 2024, 44(4): 1047-1054.
[3]	LI Shuo, LI Xichao, ZHAO Jingxiang, DAI Zuoqiang, XU Bin, SUN Mingyue, ZHENG Lili. Research Progress on Life-extension of Gun Barrel Based on Coating Modification[J]. 中国腐蚀与防护学报, 2024, 44(2): 295-302.
[4]	YE Mengying, YU Jiahui, WANG Tongtong, GAO Rongjie. Fabrication and Photocathodic Protection Performance of Bi₂S₃/CdS/TiO₂ Nanocomposites for 304 Stainless Steel[J]. 中国腐蚀与防护学报, 2024, 44(2): 372-380.
[5]	LI Danhong, YANG Tengxun, SUN Tianxiang, LI Xinglinmao, MA Chengcheng, ZHANG Yue, CHEN Shougang. Preparation and Anti-corrosion Properties of Silica Aerogel-modified Polyurethane Composite Coatings[J]. 中国腐蚀与防护学报, 2024, 44(1): 167-174.
[6]	CAO Jingyi, LI Jing, YIN Wenchang, MENG Fandi, LIU Li. Histamine-modified Epoxy Resin and its Effect on Properties of Organic Coatings[J]. 中国腐蚀与防护学报, 2024, 44(1): 151-158.
[7]	CHEN Shirun, CHEN Wenge, QIAN Ying, ZHANG Hui. Preparation and Perfromance of Rare Earth Cerium Modified Graphene Oxide / Waterborne Epoxy Resin Composite Coating[J]. 中国腐蚀与防护学报, 2024, 44(1): 107-118.
[8]	REN Wankai, LIAN Zhouyang, ZHOU Kang, LUO Zhengwei, WEI Wuji, ZHANG Xueying. Influence of Ammonia Desulfurization Liquid Components on Localized Corrosion Development Stage of 304 Stainless Steel[J]. 中国腐蚀与防护学报, 2023, 43(6): 1392-1398.
[9]	MAO Feixiong, ZHOU Yuting, YAO Wenqing, SHEN Xiang, XIAO Long, LI Minghui. Growth Kinetics of Steady-state Passive Film on Type 304 Stainless Steel Based on Point Defect Model[J]. 中国腐蚀与防护学报, 2023, 43(4): 911-921.
[10]	ZOU Wenjie, DING Li, ZHANG Xuejiao, CHEN Jun. Epoxy/Organosiloxane Modified Cationic Acrylic Emulsion Composite Coating[J]. 中国腐蚀与防护学报, 2023, 43(4): 922-928.
[11]	JIANG Fangfang, YUN Hong, PENG Li, ZHANG Yihao, LI Weishun, DAI Wenjing, WANG Baofeng, XU Qunjie. Protective Performance of NiFe-LDH Composite Coatings Modified by insitu Polymerized Polyaniline[J]. 中国腐蚀与防护学报, 2023, 43(2): 312-320.
[12]	LIU Ling, SHAO Ziya, JIA Tianyue, LIU Guoqiang, LEI Bing, MENG Guozhe. Research Progress on Application of Halloysite Nanotubes for Modification of Smart Anti-corrosion Coating[J]. 中国腐蚀与防护学报, 2022, 42(4): 523-530.
[13]	GE Chengyue, LUO Xiangping, WANG Jing, DUAN Jizhou, WANG Ning, HOU Baorong. Properties of KH550 and Hydroxyl Silicone Oil Co-modified Epoxy Resin and Its Mg-rich Primer[J]. 中国腐蚀与防护学报, 2022, 42(4): 590-596.
[14]	CHEN Zhijian, ZHOU Xuejie, CHEN Hao. Corrosion Behavior of Riveted Pair of 6A01 Al-alloy-/304 Stainless Steel-plate Used for High-speed Train[J]. 中国腐蚀与防护学报, 2022, 42(3): 507-512.
[15]	LIU Xuanxuan, YU Jinshan, GAO Yan, ZHAO Peng, WANG Qiwei, DU Zhuoling, ZHANG Junxi. Effect of APTES Modified Montmorillonite on Protective Property of Hybrid Sol-gel Coating on Mg-alloy[J]. 中国腐蚀与防护学报, 2022, 42(3): 464-470.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed