Research Progress of Nanofillers for Epoxy Anti-corrosion Coatings

doi:10.11902/1005.4537.2022.087

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (2): 220-230 DOI: 10.11902/1005.4537.2022.087

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Research Progress of Nanofillers for Epoxy Anti-corrosion Coatings

YU Fang, WANG Xiang, ZHANG Zhao(

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Center of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University, Hangzhou 310027, China

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Abstract

Organic coatings play a significant role in corrosion protection of metallic materials due to their convenient operation and low cost. Among them, epoxy resin is the most widely used as coating substrate due to its excellent adhesion to materials to be coated, remarkable chemical inertness and mechanical properties. However, voids and conductive channels would form due to shrinkage or solvent evaporation during its curing process. To cope with it, nanoparticles, which can be effectively filled in the tiny pores of epoxy resins are added, thereby improving the barrier and anti-corrosion properties of the coating. However, nanoparticles are prone to agglomeration owing to their high specific surface area, and therefore have poor dispersibility in organic resins. Therefore, surface-modification is required to improve their compatibility with resins and therefore to achieve specific performance. In this paper, nano-fillers currently used for epoxy anti-corrosion coatings are summarized and classified into three categories, namely non-metallic nano-fillers (including inorganic non-metallic nano-fillers and organic nano-fillers), metallic nano-fillers and new nano-fillers (MOFs and MXene materials), also, the properties and modification strategies of nano-fillers are introduced in detail. Finally, the challenges and outlook of nano-fillers are discussed.

Key words: epoxy resin nanofiller anti-corrosion

Received: 29 March 2022 32134.14.1005.4537.2022.087

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About author: ZHANG Zhao, E-mail: eaglezzy@zju.edu.cm

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Cite this article:

YU Fang, WANG Xiang, ZHANG Zhao. Research Progress of Nanofillers for Epoxy Anti-corrosion Coatings. Journal of Chinese Society for Corrosion and protection, 2023, 43(2): 220-230.

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.087 OR https://www.jcscp.org/EN/Y2023/V43/I2/220

Fig.1 Repairing of intrinsic defects in graphene by polydopamine^[15]

Fig.2 Synthesis mechanism of SiO₂@MoS₂ nanoparticles with core-shell structure^[56]

Fig.3 Schematic diagram of the synthesis of ultra-highly exfoliated graphene modified with PDA and BTA (PBG) and the healing performance of the epoxy resin coating added with PBG (EPBG)^[34]

Fig.4 Schematic representation of the BTA encapsulation and the possible interactions in BTA@Zn-BTC MOF^[115]

[1]	Park S M, Shon M Y. Effects of multi-walled carbon nano tubes on corrosion protection of zinc rich epoxy resin coating [J]. J. Ind. Eng. Chem., 2015, 21: 1258
[2]	Zheng S L, Bellido-Aguilar D A, Hu J, et al. Waterborne bio-based epoxy coatings for the corrosion protection of metallic substrates [J]. Prog. Org. Coat., 2019, 136: 105265
[3]	Dagdag O, Hsissou R, El Harfi A, et al. Fabrication of polymer based epoxy resin as effective anti-corrosive coating for steel: computational modeling reinforced experimental studies [J]. Surf. Interf., 2020, 18: 100454
[4]	Ramezanzadeh B, Moghadam M H M, Shohani N, et al. Effects of highly crystalline and conductive polyaniline/graphene oxide composites on the corrosion protection performance of a zinc-rich epoxy coating [J]. Chem. Eng. J., 2017, 320: 363 doi: 10.1016/j.cej.2017.03.061
[5]	Zhu B F, Liu Z H, Liu J, et al. Preparation of fluorinated/silanized polyacrylates amphiphilic polymers and their anticorrosion and antifouling performance [J]. Prog. Org. Coat., 2020, 140: 105510
[6]	Yang X Y, Yang Y T, Lu X P, et al. Research progress of corrosion inhibitor for Mg-alloy [J]. J. Chin. Soc. Corros. Prot.. 2022, 42: 435
	(杨欣宇, 杨云天, 卢小鹏等. 镁合金缓蚀剂研究进展 [J]. 中国腐蚀与防护学报, 2022, 42: 435)
[7]	Yin M, Hou L F, Wang Z W, et al. Self-generating construction of applicable corrosion-resistant surface structure of magnesium alloy [J]. Corros. Sci., 2021, 184: 109378 doi: 10.1016/j.corsci.2021.109378
[8]	Xie Y K, Liu W Q, Liang L Y, et al. Enhancement of anticorrosion property and hydrophobicity of modified epoxy coatings with fluorinated polyacrylate [J]. Colloids Surf., 2019, 579A: 123659
[9]	Auepattana-Aumrung K, Phakkeeree T, Crespy D. Polymer-corrosion inhibitor conjugates as additives for anticorrosion application [J]. Prog. Org. Coat., 2022, 163: 106639
[10]	Feghali E, Van De Pas D J, Parrott A J, et al. Biobased epoxy thermoset polymers from depolymerized native hardwood lignin [J]. ACS Macro Lett., 2020, 9: 1155 doi: 10.1021/acsmacrolett.0c00424 pmid: 35653206
[11]	Javidparvar A A, Naderi R, Ramezanzadeh B. Epoxy-polyamide nanocomposite coating with graphene oxide as cerium nanocontainer generating effective dual active/barrier corrosion protection [J]. Composites, 2019, 172B: 363
[12]	Liu X W, Xiong J P, Lv Y W, et al. Study on corrosion electrochemical behavior of several different coating systems by EIS [J]. Prog. Org. Coat., 2009, 64: 497 doi: 10.1016/j.porgcoat.2008.08.012
[13]	Zmozinski A V, Peres R S, Freiberger K, et al. Zinc tannate and magnesium tannate as anticorrosion pigments in epoxy paint formulations [J]. Prog. Org. Coat., 2018, 121: 23
[14]	Liu S Y, Wang X W, Yin Q, et al. A facile approach to fabricating graphene/waterborne epoxy coatings with dual functionalities of barrier and corrosion inhibitor [J]. J. Mater. Sci. Technol., 2022, 112: 263 doi: 10.1016/j.jmst.2021.07.061
[15]	Zheng Z Q, Xiao L L, Huang P, et al. Polydopamine improved anticorrosion of graphene on copper: inhibiting galvanic corrosion and healing structure defects [J]. Appl. Mater. Today, 2021, 24: 101069
[16]	Sun W, Wu T T, Wang L D, et al. The role of graphene loading on the corrosion-promotion activity of graphene/epoxy nanocomposite coatings [J]. Composites, 2019, 173B: 106916
[17]	Schriver M, Regan W, Gannett W J, et al. Graphene as a long-term metal oxidation barrier: worse than nothing [J]. ACS Nano, 2013, 7: 5763 doi: 10.1021/nn4014356 pmid: 23755733
[18]	Jing Y J, Wang P Q, Yang Q B, et al. MoS₂ decorated with ZrO₂ nanoparticles through mussel-inspired chemistry of dopamine for reinforcing anticorrosion of epoxy coatings [J]. Colloids Surf., 2021, 608A: 125625
[19]	Ding J H, Zhao H R, Zhou M, et al. Super-anticorrosive inverse nacre-like graphene-epoxy composite coating [J]. Carbon, 2021, 181: 204 doi: 10.1016/j.carbon.2021.05.017
[20]	Yan H, Zhang L, Li H, et al. Towards high-performance additive of Ti₃C₂/graphene hybrid with a novel wrapping structure in epoxy coating [J]. Carbon, 2020, 157: 217 doi: 10.1016/j.carbon.2019.10.034
[21]	Su Y, Qiu S H, Wei J Y, et al. Sulfonated polyaniline assisted hierarchical assembly of graphene-LDH nanohybrid for enhanced anticorrosion performance of waterborne epoxy coatings [J]. Chem. Eng. J., 2021, 426: 131269 doi: 10.1016/j.cej.2021.131269
[22]	Sun W, Wang L D, Yang Z Q, et al. A facile method for the modification of graphene nanosheets as promising anticorrosion pigments [J]. Mater. Lett., 2018, 228: 152 doi: 10.1016/j.matlet.2018.05.105
[23]	Qiu S H, Liu G, Li W, et al. Noncovalent exfoliation of graphene and its multifunctional composite coating with enhanced anticorrosion and tribological performance [J]. J. Alloy. Compd., 2018, 747: 60 doi: 10.1016/j.jallcom.2018.03.007
[24]	Shi H Y, Liu W Q, Xie Y K, et al. Synthesis of carboxymethyl chitosan-functionalized graphene nanomaterial for anticorrosive reinforcement of waterborne epoxy coating [J]. Carbohydr. Polym., 2021, 252: 117249 doi: 10.1016/j.carbpol.2020.117249
[25]	Liu C B, Li J Y, Jin Z Y, et al. Synthesis of graphene-epoxy nanocomposites with the capability to self-heal underwater for materials protection [J]. Compos. Commun., 2019, 15: 155 doi: 10.1016/j.coco.2019.07.011
[26]	Ren F, Zhu G M, Ren P G, et al. In situ polymerization of graphene oxide and cyanate ester–epoxy with enhanced mechanical and thermal properties [J]. Appl. Surf. Sci., 2014, 316: 549 doi: 10.1016/j.apsusc.2014.07.159
[27]	Keshmiri N, Najmi P, Ramezanzadeh B, et al. Nano-Scale P, Zn-codoped reduced-graphene oxide incorporated epoxy composite; synthesis, electronic-level DFT-D modeling, and anti-corrosion properties [J]. Prog. Org. Coat., 2021, 159: 106416
[28]	Lv X D, Li X T, Li N, et al. ZrO₂ nanoparticle encapsulation of graphene microsheets for enhancing anticorrosion performance of epoxy coatings [J]. Surf. Coat. Technol., 2019, 358: 443 doi: 10.1016/j.surfcoat.2018.11.045
[29]	Zhang C Y, Li W, Liu C, et al. Effect of covalent organic framework modified graphene oxide on anticorrosion and self-healing properties of epoxy resin coatings [J]. J. Colloid Interface Sci., 2022, 608: 1025 doi: 10.1016/j.jcis.2021.10.024
[30]	Li Z J, He Y, Yan S M, et al. A novel silk fibroin-graphene oxide hybrid for reinforcing corrosion protection performance of waterborne epoxy coating [J]. Colloids Surf., 2022, 634A: 127959
[31]	Zhu Q S, Li E, Liu X H, et al. Synergistic effect of polypyrrole functionalized graphene oxide and zinc phosphate for enhanced anticorrosion performance of epoxy coatings [J]. Composites, 2020, 130A: 105752
[32]	Wu H, Cheng L, Liu C B, et al. Engineering the interface in graphene oxide/epoxy composites using bio-based epoxy-graphene oxide nanomaterial to achieve superior anticorrosion performance [J]. J. Colloid Interface Sci., 2021, 587: 755 doi: 10.1016/j.jcis.2020.11.035
[33]	Zhou S G, Wu Y M, Zhao W J, et al. Designing reduced graphene oxide/zinc rich epoxy composite coatings for improving the anticorrosion performance of carbon steel substrate [J]. Mater. Des., 2019, 169: 107694 doi: 10.1016/j.matdes.2019.107694
[34]	Chen G Y, Jin B, Li Y L, et al. A smart healable anticorrosion coating with enhanced loading of benzotriazole enabled by ultra-highly exfoliated graphene and mussel-inspired chemistry [J]. Carbon, 2022, 187: 439 doi: 10.1016/j.carbon.2021.11.048
[35]	Yan D S, Liu J L, Zhang Z H, et al. Dual-functional graphene oxide-based nanomaterial for enhancing the passive and active corrosion protection of epoxy coating [J]. Composites, 2021, 222B: 109075
[36]	Cao K Y, Yu Z X, Yin D, et al. Fabrication of BTA-MOF-TEOS-GO nanocomposite to endow coating systems with active inhibition and durable anticorrosion performances [J]. Prog. Org. Coat., 2020, 143: 105629
[37]	Dhamodharan D, Dhinakaran V, Nagavaram R, et al. Experimental and numerical study on smectic aligned zirconium phosphate decorated graphene oxide hybrids effects over waterborne epoxy multi-functional properties enhancement [J]. J. Ind. Eng. Chem., 2022, 107: 165 doi: 10.1016/j.jiec.2021.11.043
[38]	Kumar A M, Jose J, Hussein M A. Novel polyaniline/chitosan/reduced graphene oxide ternary nanocomposites: feasible reinforcement in epoxy coatings on mild steel for corrosion protection [J]. Prog. Org. Coat., 2022, 163: 106678
[39]	Nayak S R, Mohana K N, Hegde M B. Anticorrosion performance of 4-fluoro phenol functionalized graphene oxide nanocomposite coating on mild steel [J]. J. Fluorine Chem., 2019, 228: 109392 doi: 10.1016/j.jfluchem.2019.109392
[40]	Liu J H, Yu Q, Yu M, et al. Silane modification of titanium dioxide-decorated graphene oxide nanocomposite for enhancing anticorrosion performance of epoxy coatings on AA-2024 [J]. J. Alloy. Compd., 2018, 744: 728 doi: 10.1016/j.jallcom.2018.01.267
[41]	Lin Y T, Don T M, Wong C J, et al. Improvement of mechanical properties and anticorrosion performance of epoxy coatings by the introduction of polyaniline/graphene composite [J]. Surf. Coat. Technol., 2019, 374: 1128 doi: 10.1016/j.surfcoat.2018.01.050
[42]	Rajitha K, Mohana K N S. Synthesis of graphene oxide-based nanofillers and their influence on the anticorrosion performance of epoxy coating in saline medium [J]. Diamond Relat. Mater., 2020, 108: 107974 doi: 10.1016/j.diamond.2020.107974
[43]	Aghili M, Yazdi M K, Ranjbar Z, et al. Anticorrosion performance of electro-deposited epoxy/ amine functionalized graphene oxide nanocomposite coatings [J]. Corros. Sci., 2021, 179: 109143 doi: 10.1016/j.corsci.2020.109143
[44]	Ye Y W, Zhang D W, Liu T, et al. Improvement of anticorrosion ability of epoxy matrix in simulate marine environment by filled with superhydrophobic POSS-GO nanosheets [J]. J. Hazard. Mater., 2019, 364: 244 doi: S0304-3894(18)30949-X pmid: 30368062
[45]	Xue X Z, Zhang J Y, Zhou D, et al. In-situ bonding technology and excellent anticorrosion activity of graphene oxide / hydroxyapatite nanocomposite pigment [J]. Dyes Pigment., 2019, 160: 109 doi: 10.1016/j.dyepig.2018.07.057
[46]	Zhu X B, Zhao H C, Wang L P, et al. Bioinspired ultrathin graphene nanosheets sandwiched between epoxy layers for high performance of anticorrosion coatings [J]. Chem. Eng. J., 2021, 410: 128301 doi: 10.1016/j.cej.2020.128301
[47]	Cen H Y, Cao J J, Chen Z Y. Functionalized carbon nanotubes as a novel inhibitor to enhance the anticorrosion performance of carbon steel in CO₂-saturated NaCl solution [J]. Corros. Sci., 2020, 177: 109011 doi: 10.1016/j.corsci.2020.109011
[48]	Li J C, Chen P, Wang Y, et al. Corrosion resistance of surface texturing epoxy resin coatings reinforced with fly ash cenospheres and multiwalled carbon nanotubes [J]. Prog. Org. Coat., 2021, 158: 106388
[49]	Shen W N, Feng L J, Liu X, et al. Multiwall carbon nanotubes-reinforced epoxy hybrid coatings with high electrical conductivity and corrosion resistance prepared via electrostatic spraying [J]. Prog. Org. Coat., 2016, 90: 139
[50]	Rahmani P, Shojaei A, Tavandashti N P. Nanodiamond loaded with corrosion inhibitor as efficient nanocarrier to improve anticorrosion behavior of epoxy coating [J]. J. Ind. Eng. Chem., 2020, 83: 153 doi: 10.1016/j.jiec.2019.11.023
[51]	Xia Y Q, Zhang N G, Zhou Z P, et al. Incorporating SiO₂functionalized g-C₃N₄sheets to enhance anticorrosion performance of waterborne epoxy [J]. Prog. Org. Coat., 2020, 147: 105768
[52]	Steffi A P, Balaji R, Prakash N, et al. Incorporation of SiO₂ functionalized g-C₃N₄ sheets with TiO₂ nanoparticles to enhance the anticorrosion performance of metal specimens in aggressive Cl^- environment [J]. Chemosphere, 2022, 290: 133332 doi: 10.1016/j.chemosphere.2021.133332
[53]	Xia Y Q, He Y, Chen C L, et al. Co-modification of polydopamine and KH560 on g-C₃N₄nanosheets for enhancing the corrosion protection property of waterborne epoxy coating [J]. React. Funct. Polym., 2020, 146: 104405 doi: 10.1016/j.reactfunctpolym.2019.104405
[54]	Li S X, Du F F, Lin Y X, et al. Excellent anti-corrosion performance of epoxy composite coatings filled with novel N-doped carbon nanodots [J]. Eur. Polym. J., 2022, 163: 110957 doi: 10.1016/j.eurpolymj.2021.110957
[55]	Li Z Y, Ravenni G, Bi H C, et al. Effects of biochar nanoparticles on anticorrosive performance of zinc-rich epoxy coatings [J]. Prog. Org. Coat., 2021, 158: 106351
[56]	Xia Y Q, He Y, Chen C L, et al. MoS₂ nanosheets modified SiO₂ to enhance the anticorrosive and mechanical performance of epoxy coating [J]. Prog. Org. Coat., 2019, 132: 316
[57]	Jia S S, Deng S L, Luo S, et al. Texturing commercial epoxy with hierarchical and porous structure for robust superhydrophobic coatings [J]. Appl. Surf. Sci., 2019, 466: 84 doi: 10.1016/j.apsusc.2018.10.017
[58]	Zhu B F, Ou R J, Liu J, et al. Fabrication of superhydrophobic surfaces with hierarchical structure and their corrosion resistance and self-cleaning properties [J]. Surf. Interfaces, 2022, 28: 101608
[59]	Cheng M, Jiang H, Wang Z K, et al. Nanocatalyst-mediated oxygen depletion in epoxy coating for active corrosion protection [J]. Chem. Eng. J., 2021, 425: 131649 doi: 10.1016/j.cej.2021.131649
[60]	Wang T, Ge H Y, Zhang K L. A novel core-shell silica@graphene straticulate structured antistatic anticorrosion composite coating [J]. J. Alloy. Compd., 2018, 745: 705 doi: 10.1016/j.jallcom.2018.02.222
[61]	Chen X, Wen S F, Feng T, et al. High solids organic-inorganic hybrid coatings based on silicone-epoxy-silica coating with improved anticorrosion performance for AA2024 protection [J]. Prog. Org. Coat., 2020, 139: 105374
[62]	Atta A M, Mohamed N H, Rostom M, et al. New hydrophobic silica nanoparticles capped with petroleum paraffin wax embedded in epoxy networks as multifunctional steel epoxy coatings [J]. Prog. Org. Coat., 2019, 128: 99
[63]	Matin E, Attar M M, Ramezanzadeh B. Investigation of corrosion protection properties of an epoxy nanocomposite loaded with polysiloxane surface modified nanosilica particles on the steel substrate [J]. Prog. Org. Coat., 2015, 78: 395
[64]	Ghanbari A, Attar M M. A study on the anticorrosion performance of epoxy nanocomposite coatings containing epoxy-silane treated nano-silica on mild steel substrate [J]. J. Ind. Eng. Chem., 2015, 23: 145 doi: 10.1016/j.jiec.2014.08.008
[65]	Yu H D， Geng C D， Liu C M, et al. Near-infrared light photothermally induced shape memory and self-healing effects of epoxy resin coating with polyaniline nanofibers [J]. Syn. Met., 2020, 226:116417
[66]	Hao Y S, Sun W, Jiang L L, et al. Self-healing effect of epoxy coating containing mesoporous polyaniline hollow spheres loaded with benzotriazole [J]. Prog. Org. Coat., 2021, 159: 106445
[67]	Lv Y Q, Zheng Y Q, Zhu H L, et al. Designing a dual-functional material with barrier anti-corrosion and photocatalytic antifouling properties using g-C₃N₄ nanosheet with ZnO nanoring [J]. J. Mater. Sci. Technol., 2022, 106: 56 doi: 10.1016/j.jmst.2021.07.029
[68]	Wang H H, Zhang W J, Ma Y N, et al. Phosphorylated polymer/anionic surfactant doped polypyrrole in waterborne epoxy matrix toward enhanced mechanical and chemical resistance [J]. Prog. Org. Coat., 2020, 143: 105634
[69]	Liu T, Li J Y, Li X Y, et al. Effect of self-assembled tetraaniline nanofiber on the anticorrosion performance of waterborne epoxy coating [J]. Prog. Org. Coat., 2019, 128: 137
[70]	Ma I A W, Sh A, Ramesh K, et al. Anticorrosion properties of epoxy-nanochitosan nanocomposite coating [J]. Prog. Org. Coat., 2017, 113: 74
[71]	Cheng L, Liu C B, Wu H, et al. A two-dimensional nanocontainer based on mesoporous polydopamine coated lamellar hydroxyapatite towards anticorrosion reinforcement of waterborne epoxy coatings [J]. Corros. Sci., 2021, 193: 109891 doi: 10.1016/j.corsci.2021.109891
[72]	Yan H, Cai M, Wang J C, et al. Insight into anticorrosion/antiwear behavior of inorganic-organic multilayer protection system composed of nitriding layer and epoxy coating with Ti₃C₂T_x MXene [J]. Appl. Surf. Sci., 2021, 536: 147974 doi: 10.1016/j.apsusc.2020.147974
[73]	Javidparvar A A, Naderi R, Ramezanzadeh B. Manipulating graphene oxide nanocontainer with benzimidazole and cerium ions: application in epoxy-based nanocomposite for active corrosion protection [J]. Corros. Sci., 2020, 165: 108379 doi: 10.1016/j.corsci.2019.108379
[74]	He Y, Zhang C L, Wu F, et al. Fabrication study of a new anticorrosion coating based on supramolecular nanocontainer [J]. Synth. Met., 2016, 212: 186 doi: 10.1016/j.synthmet.2015.10.022
[75]	Asaad M A, Raja P B, Huseien G F, et al. Self-healing epoxy coating doped with Elaesis guineensis/silver nanoparticles: a robust corrosion inhibitor [J]. Constr. Build. Mater., 2021, 312: 125396 doi: 10.1016/j.conbuildmat.2021.125396
[76]	Udoh I I, Shi H W, Liu F C, et al. Microcontainer-based waterborne epoxy coatings for AA2024-T₃: Effect of nature and number of polyelectrolyte multilayers on active protection performance [J]. Mater. Chem. Phys., 2020, 241: 122404 doi: 10.1016/j.matchemphys.2019.122404
[77]	Jin Z Y, Zhao Z L, Zhao T, et al. One-step preparation of inhibitor-loaded nanocontainers and their application in self-healing coatings [J]. Corros. Commun., 2021, 2: 63 doi: 10.1016/j.corcom.2021.10.001
[78]	Yao Y C, Sun H, Zhang Y L, et al. Corrosion protection of epoxy coatings containing 2-hydroxyphosphonocarboxylic acid doped polyaniline nanofibers [J]. Prog. Org. Coat., 2020, 139: 105470
[79]	Liu T F, Li W, Zhang C Y, et al. Preparation of highly efficient self-healing anticorrosion epoxy coating by integration of benzotriazole corrosion inhibitor loaded 2D-COF [J]. J. Ind. Eng. Chem., 2021, 97: 560 doi: 10.1016/j.jiec.2021.03.012
[80]	Zhang M L, Yu X, Lin Y N, et al. Anti-corrosion coatings with active and passive protective performances based on v-COF/GO nanocontainers [J]. Prog. Org. Coat., 2021, 159: 106415
[81]	Zhou C L, Li Z, Li J, et al. Epoxy composite coating with excellent anticorrosion and self-healing performances based on multifunctional zeolitic imidazolate framework derived nanocontainers [J]. Chem. Eng. J., 2020, 385: 123835 doi: 10.1016/j.cej.2019.123835
[82]	Yan H, Fan X Q, Cai M, et al. Amino-functionalized Ti₃C₂T_x loading ZIF-8 nanocontainer@benzotriazole as multifunctional composite filler towards self-healing epoxy coating [J]. J. Colloid Interface Sci., 2021, 602: 131 doi: 10.1016/j.jcis.2021.06.004
[83]	Cheng M, Li F T, Wang Z K, et al. New valve-free organosilica nanocontainer for active anticorrosion of polymer coatings [J]. Composites, 2021, 224B: 109185
[84]	Wang J X, Yang H, Meng Z, et al. Epoxy coating with excellent anticorrosion and pH-responsive performances based on DEAEMA modified mesoporous silica nanomaterials [J]. Colloids Surf., 2022, 634A: 127951
[85]	El-Faham A, Atta A M, Osman S M, et al. Silver-embedded epoxy nanocomposites as organic coatings for steel [J]. Prog. Org. Coat., 2018, 123: 209
[86]	Shen W N, Zhang T F, Ge Y F, et al. Multifunctional AgO/epoxy nanocomposites with enhanced mechanical, anticorrosion and bactericidal properties [J]. Prog. Org. Coat., 2021, 152: 106130
[87]	Radoman T S, Džunuzović J V, Grgur B N, et al. Improvement of the epoxy coating properties by incorporation of polyaniline surface treated TiO₂ nanoparticles previously modified with vitamin B6 [J]. Prog. Org. Coat., 2016, 99: 346
[88]	Pour Z S, Ghaemy M, Bordbar S, et al. Effects of surface treatment of TiO₂ nanoparticles on the adhesion and anticorrosion properties of the epoxy coating on mild steel using electrochemical technique [J]. Prog. Org. Coat., 2018, 119: 99
[89]	Huang W F, Xiao Y L, Huang Z J, et al. Super-hydrophobic polyaniline-TiO₂ hierarchical nanocomposite as anticorrosion coating [J]. Mater. Lett., 2020, 258: 126822 doi: 10.1016/j.matlet.2019.126822
[90]	Talebi H, Olad A, Nosrati R. Fe₃O₄/PANI nanocomposite core-shell structure in epoxy resin matrix for the application as electromagnetic waves absorber [J]. Prog. Org. Coat., 2022, 163: 106665
[91]	Hosseini M G, Sefidi P Y. Electrochemical impedance spectroscopy evaluation on the protective properties of epoxy/DBSAdoped polyaniline-TiO₂ nanocomposite coated mild steel under cathodic polarization [J]. Surf. Coat. Technol., 2017, 331: 66 doi: 10.1016/j.surfcoat.2017.10.043
[92]	Tavandashti N P, Almas S M, Esmaeilzadeh E. Corrosion protection performance of epoxy coating containing alumina/PANI nanoparticles doped with cerium nitrate inhibitor on Al-2024 substrates [J]. Prog. Org. Coat., 2021, 152: 106133
[93]	Yu M D, Fan C Q, Han S K, et al. Anticorrosion behavior of superhydrophobic particles reinforced epoxy coatings for long-time in the high salinity liquid [J]. Prog. Org. Coat., 2020, 147: 105867
[94]	Wu F, Li J F, Quan H, et al. Robust polyurea/poly (urea-formalde-hyde) hybrid microcapsules decorated with Al₂O₃ nano-shell for improved self-healing performance [J]. Appl. Surf. Sci., 2021, 542: 148561 doi: 10.1016/j.apsusc.2020.148561
[95]	Zhang C, Chen L, He Y, et al. Designing a high-performance waterborne epoxy coating with passive/active dual self-healing properties by synergistic effect of V₂O₅@polyaniline-tannic acid inhibitors [J]. Prog. Org. Coat., 2021, 151: 106036
[96]	Kang Y T, Wang C C, Chen C Y. Corrosion-protective performance of magnetic CoFe₂O₄/polyaniline nanocomposite within epoxy coatings [J]. J. Taiwan Inst. Chem. Eng., 2021, 127: 357 doi: 10.1016/j.jtice.2021.08.008
[97]	Situ Y, Ji W W, Liu C Y, et al. Synergistic effect of homogeneously dispersed PANI-TiN nanocomposites towards long-term anticorrosive performance of epoxy coatings [J]. Prog. Org. Coat., 2019, 130: 158 doi: 10.1016/j.porgcoat.2019.01.034
[98]	Liu X R, Miao M, Zhang J Y, et al. Surface coordination and excellent anticorrosion performance of strontiumapatite nanocomposite [J]. J. Ind. Eng. Chem., 2019, 80: 656 doi: 10.1016/j.jiec.2019.08.048
[99]	Hosseini M G, Aboutalebi K. Improving the anticorrosive performance of epoxy coatings by embedding various percentages of unmodified and imidazole modified CeO₂ nanoparticles [J]. Prog. Org. Coat., 2018, 122: 56
[100]	Feng Z L, Wan R J, Chen S M, et al. In-situ repair of marine coatings by a Fe₃O₄nanoparticle-modified epoxy resin under seawater [J]. Chem. Eng. J., 2022, 430: 132827 doi: 10.1016/j.cej.2021.132827
[101]	Atta A M, El-Faham A, Al-Lohedan H A, et al. Modified triazine decorated with Fe₃O₄ and Ag/Ag₂O nanoparticles for self-healing of steel epoxy coatings in seawater [J]. Prog. Org. Coat., 2018, 121: 247
[102]	El-Masry M M, Ramadan R, Ahmed M K. The effect of adding cobalt ferrite nanoparticles on the mechanical properties of epoxy resin [J]. Results Mater., 2020, 8: 100160
[103]	Soltani N, Salavati H, Moghadasi A. The role of Na-montmorillonite/cobalt ferrite nanoparticles in the corrosion of epoxy coated AA 3105 aluminum alloy [J]. Surf. Interfaces, 2019, 15: 89 doi: 10.1016/j.surfin.2019.02.006
[104]	Binyaseen A M, Bayazeed A, Al-Nami S Y, et al. Development of epoxy/rice straw-based cellulose nanowhiskers composite smart coating immobilized with rare-earth doped aluminate: photoluminescence and anticorrosion properties for sustainability [J]. Ceram. Int., 2022, 48: 4841 doi: 10.1016/j.ceramint.2021.11.020
[105]	Qiu S H, Su Y, Zhao H C, et al. Ultrathin metal-organic framework nanosheets prepared via surfactant-assisted method and exhibition of enhanced anticorrosion for composite coatings [J]. Corros. Sci., 2021, 178: 109090 doi: 10.1016/j.corsci.2020.109090
[106]	Arunadevi N, Swathika M, Mehala M, et al. New epoxy-Nano metal oxide-based coatings for enhanced corrosion protection [J]. J. Mol. Struct., 2022, 1250: 131790 doi: 10.1016/j.molstruc.2021.131790
[107]	Zhao Y, Yan S M, He Y, et al. Synthesis of ultrathin α-zirconium phosphate functionalized with polypyrrole for reinforcing the anticorrosive property of waterborne epoxy coating [J]. Colloids Surf., 2022, 635A: 128052
[108]	Li M L, Huang H W, Mo R B, et al. Single-step exfoliation, acidification and covalent functionalization of α-zirconium phosphate for enhanced anticorrosion of waterborne epoxy coatings [J]. Surf. Interfaces, 2021, 23: 100887
[109]	Huang H W, Li M L, Tian Y Q, et al. Exfoliation and functionalization of α-zirconium phosphate in one pot for waterborne epoxy coatings with enhanced anticorrosion performance [J]. Prog. Org. Coat., 2020, 138: 105390
[110]	Haddadi S A, Amini M, Ghaderi S, et al. Synthesis and cation-exchange behavior of expanded MoS₂ nanosheets for anticorrosion applications [J]. Mater. Today: Proc., 2018, 5: 15573
[111]	Gao F, Du A, Ma R N, et al. Improved corrosion resistance of acrylic coatings prepared with modified MoS₂ nanosheets [J]. Colloids Surf., 2020, 587A: 124318
[112]	Duan S, Dou B J, Lin X Z, et al. Influence of active nanofiller ZIF-8 metal-organic framework (MOF) by microemulsion method on anticorrosion of epoxy coatings [J]. Colloids Surf., 2021, 624A: 126836
[113]	Wei R Z, Liu Z, Wei W C, et al. Anticorrosion performance of hydrophobic acid-modified-MOFs/epoxy coatings [J]. Colloid Interface Sci. Commun., 2022, 46: 100580 doi: 10.1016/j.colcom.2021.100580
[114]	Zhao H R, Liu Z, Cheng Z L. Superior compatible interface and non-conductive two dimensional (2D) Co₂(OH)₂BDC nanosheets enabled the robust anti-corrosion and anti-friction performance epoxy coating system [J]. Prog. Org. Coat., 2021, 154: 106181
[115]	Liu C B, Qian B, Hou P M, et al. Stimulus responsive zeolitic imidazolate framework to achieve corrosion sensing and active protecting in polymeric coatings [J]. ACS Appl. Mater. Interfaces, 2021, 13: 4429 doi: 10.1021/acsami.0c22642
[116]	Mohammadpour Z, Zare H R. Fabrication of a pH-sensitive epoxy nanocomposite coating based on a Zn-BTC metal-organic framework containing benzotriazole as a smart corrosion inhibitor [J]. Cryst. Growth Des., 2021, 21: 3954 doi: 10.1021/acs.cgd.1c00284
[117]	Yan H, Li W, Li H, et al. Ti₃C₂ MXene nanosheets toward high-performance corrosion inhibitor for epoxy coating [J]. Prog. Org. Coat., 2019, 135: 156
[118]	Chen J F, Zhao W J. Silk fibroin-Ti₃C₂T_Xhybrid nanofiller enhance corrosion protection for waterborne epoxy coatings under deep sea environment [J]. Chem. Eng. J., 2021, 423: 130195 doi: 10.1016/j.cej.2021.130195
[119]	Li X M, Zhou S X. Epoxy-functionalized Ti₃C₂ nanosheet for epoxy coatings with prominent anticorrosion performance [J]. Prog. Org. Coat., 2022, 162: 106559
[120]	Shen L, Zhao W J, Wang K, et al. GO-Ti₃C₂ two-dimensional heterojunction nanomaterial for anticorrosion enhancement of epoxy zinc-rich coatings [J]. J. Hazard. Mater., 2021, 417: 126048 doi: 10.1016/j.jhazmat.2021.126048
[121]	Nie Y, Huang J K, Ma S Y, et al. MXene-hybridized silane films for metal anticorrosion and antibacterial applications [J]. Appl. Surf. Sci., 2020, 527: 146915 doi: 10.1016/j.apsusc.2020.146915
[122]	Zhao C C, Zhou M, Yu H B. Interfacial combination of Ti₃C₂T_x MXene with waterborne epoxy anticorrosive coating [J]. Appl. Surf. Sci., 2022, 572: 150894 doi: 10.1016/j.apsusc.2021.150894
[123]	Fan X Q, Yan H, Cai M, et al. Achieving parallelly-arranged Ti₃C₂T_x in epoxy coating for anti-corrosive/wear high-efficiency protection [J]. Composites, 2022, 231B: 109581
[124]	Li S H, Huang H W, Chen F, et al. Reinforced anticorrosion performance of waterborne epoxy coating with eco-friendly L-cysteine modified Ti₃C₂T_x MXene nanosheets [J]. Prog. Org. Coat., 2021, 161: 106478
[125]	Cai M, Yan H, Li Y T, et al. Ti₃C₂T_x/PANI composites with tunable conductivity towards anticorrosion application [J]. Chem. Eng. J., 2021, 410: 128310 doi: 10.1016/j.cej.2020.128310
[126]	Yan H, Cai M, Li W, et al. Amino-functionalized Ti₃C₂T_x with anti-corrosive/wear function for waterborne epoxy coating [J]. J. Mater. Sci. Technol., 2020, 54: 144 doi: 10.1016/j.jmst.2020.05.002
[127]	Ding J H, Zhao H R, Yu H B. Structure and performance insights in carbon dots-functionalized MXene-epoxy ultrathin anticorrosion coatings [J]. Chem. Eng. J., 2022, 430: 132838 doi: 10.1016/j.cej.2021.132838
[128]	Zhao H R, Ding J H, Zhou M, et al. Air-stable titanium carbide MXene nanosheets for corrosion protection [J]. ACS Appl. Nano Mater., 2021, 4: 3075 doi: 10.1021/acsanm.1c00219

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