Inhibition Behavior of a Nano-corrosion Inhibitor Capsule Prepared from MOFs and BTA for Copper

doi:10.11902/1005.4537.2021.288

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (6): 1058-1064 DOI: 10.11902/1005.4537.2021.288

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Inhibition Behavior of a Nano-corrosion Inhibitor Capsule Prepared from MOFs and BTA for Copper

LIAN Yubo(

), ZHANG Qingzhu, HAN Chuanghui, LI Wenjuan, WENG Huatao, JIANG Wei

Xi'an Changqing Chemical Group Co. Ltd., Xi'an 710018, China

Cite this article:

LIAN Yubo, ZHANG Qingzhu, HAN Chuanghui, LI Wenjuan, WENG Huatao, JIANG Wei. Inhibition Behavior of a Nano-corrosion Inhibitor Capsule Prepared from MOFs and BTA for Copper. Journal of Chinese Society for Corrosion and protection, 2022, 42(6): 1058-1064.

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Abstract

A three-dimensional metal organic frame material (MOF-5) was synthesized by hydrothermal method, and then, the corrosion inhibitor benzotriazole (BTA) molecule was loaded into MOF-5 to form corrosion inhibitor capsules. The structures and corrosion inhibition properties of the prepared BTA@MOF-5 was characterized by means of TEM, SEM, FT-IR, XRD and electrochemical testing techniques. The results show that the prepared MOF-5 can be an ideal candidate as an inhibitor carrier, while the BTA molecules were successfully loaded into MOF-5. Furthermore, the acquired BTA@MOF-5 had the characteristics of slow release for corrosion inhibitor benzotriazole, which could provide corrosion protection for copper.

Key words: BTA@MOF-5 corrosion inhibitor capsule sustained release metal protection

Received: 19 October 2021

ZTFLH:

TG174.42

About author: LIAN Yubo, E-mail: 14533362@qq.com

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	Yubo LIAN
	Qingzhu ZHANG
	Chuanghui HAN
	Wenjuan LI
	Huatao WENG
	Wei JIANG

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https://www.jcscp.org/EN/10.11902/1005.4537.2021.288 OR https://www.jcscp.org/EN/Y2022/V42/I6/1058

Fig.1 Micro-structures of MOF-5 (a, b) and of BTA@MOF-5 (c, d)

Fig.2 FT-IR spectra of BTA, MOF-5 and BTA@MOF-5

Fig.3 XRD patterns of BTA, MOF-5 and BTA@MOF-5

Fig.4 TGA curves of BTA, MOF-5 and BTA@MOF-5

Fig.5 Standard absorbance curves (a) and concentration standard curve diagram (b) of BTA

Fig.6 UV-vis spectra of BTA released from MOF-5 for different time

Table 1 Absorbance and concentration parameters of BTA after immersion for different time in 100 mg/L BTA@MOF-5 solution

Fig.7 Nyquist plots (a) and fitting equivalent circuit (b) of pure copper immersed for different time in 3.5%NaCl solutions without and with BTA

Sample	R_ct / Ω·cm²	C_dl		R_f / Ω·cm²	C_f		η / %
Sample	R_ct / Ω·cm²	Y₀₁ / Sⁿ ·Ω^-1·cm^-2	$n 1$	R_f / Ω·cm²	Y₀₂ / Sⁿ ·Ω^-1·cm^-2	n₂	η / %
Blank	172.3	33.85×10^-6	0.8397	0.32×10⁴	54.81×10^-5	0.4253	---
MOF-5	52.74	10.08×10^-6	0.7673	0.59×10⁴	151.6×10^-5	0.4314	---
@-1 h	3515	5.823×10^-6	0.8558	1.36×10⁴	2.372×10^-5	0.4962	80.5
@-2 h	3554	5.301×10^-6	0.8565	1.68×10⁴	2.085×10^-5	0.5129	83.4
@-3 h	3710	4.958×10^-6	0.8534	2.19×10⁴	2.039×10^-5	0.4824	87.0
@-4 h	4678	4.659×10^-6	0.8527	2.40×10⁴	1.751×10^-5	0.5171	88.4
@-5 h	5486	4.441×10^-6	0.8507	2.62×10⁴	1.452×10^-5	0.5454	89.5
@-6 h	6095	4.076×10^-6	0.8537	2.89×10⁴	1.263×10^-5	0.569	90.5

Table 2 Fitting electrochemical parameters of EIS of Cu in 3.5%NaCl solutions without and with BTA

Fig.8 Polarization curves of pure copper in 3.5%NaCl solutions without and with BTA

Table 3 Fitting parameters of polarization curves of pure copper in 3.5%NaCl solutions without and with BTA

Fig.9 SEM micrographs of pure copper immersed for 24 h in 3.5%NaCl solutions without (a) and with (b) 100 mg/L BTA@MOF-5

[1]	Pan Y, Sun L, Yang S C, et al. Research progress of pipeline corrosion and protection [J]. Corros. Sci. Prot. Technol., 2014, 26: 77
	(潘一, 孙林, 杨双春等. 国内外管道腐蚀与防护研究进展 [J]. 腐蚀科学与防护技术, 2014, 26: 77)
[2]	Kear G, Barker B D, Walsh F C. Electrochemical corrosion of unalloyed copper in chloride media—a critical review [J]. Corros. Sci., 2004, 46: 109 doi: 10.1016/S0010-938X(02)00257-3
[3]	Zhang N. Corrosion detection technology and anticorrosion measures for oil and gas pipelines [J]. Total Corros. Control, 2018, 32(7): 108
	(张宁. 油气管道腐蚀检测技术与防腐措施 [J]. 全面腐蚀控制, 2018, 32(7): 108)
[4]	Ding Q M, Gao Y N, Hou W L, et al. Influence of Cl^- concentration on corrosion behavior of reinforced concrete in Soil [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 705
	(丁清苗, 高宇宁, 侯文亮等. Cl^-浓度对钢筋混凝土在土壤中腐蚀行为的影响 [J]. 中国腐蚀与防护学报, 2021, 41: 705)
[5]	Finšgar M, Jackson J. Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: a review [J]. Corros. Sci., 2014, 86: 17 doi: 10.1016/j.corsci.2014.04.044
[6]	Wen J X, Zhang X, Liu Y X, et al. Preparation and performance of smart coating doped with nanocontainers of BTA@MSNs-SO₃H-PDDA for anti-corrosion of carbon steel [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 309
	(文家新, 张欣, 刘云霞等. 掺杂pH敏感性智能纳米容器BTA@MSNs-SO₃H-PDDA碳钢智能防腐涂层的制备及性能研究 [J]. 中国腐蚀与防护学报, 2022, 42: 309)
[7]	Qian B, Liu C B, Song Z W, et al. Anticorrosion performance of epoxy coating modified with nanocontainers [J]. J. Chin. Soc. Corros. Prot., 2018, 38: 133
	(钱备, 刘成宝, 宋祖伟等. 纳米容器改性环氧涂层对Q235碳钢的防腐蚀性能 [J]. 中国腐蚀与防护学报, 2018, 38: 133)
[8]	Chen T, Yang N W, Fu J J. Controlled release of cargo molecules from hollow mesoporous silicananoparticles based on acid and base dual-responsive cucurbit[7]uril pseudorotaxanes [J]. Chem. Commun., 2013, 49: 6555 doi: 10.1039/c3cc43221a
[9]	Sun S Q, Zhao X Y, Cheng M, et al. Facile preparation of redox-responsive hollow mesoporous silica spheres for the encapsulation and controlled release of corrosion inhibitors [J]. Prog. Org. Coat., 2019, 136: 105302
[10]	Hong C Y, Li X, Pan C Y. Fabrication of smart nanocontainers with a mesoporous core and a pH-responsive shell for controlled uptake and release [J]. J. Mater. Chem., 2009, 19: 5155 doi: 10.1039/b820534e
[11]	Abdullayev E, Lvov Y. Clay nanotubes for corrosion inhibitor encapsulation: release control with end stoppers [J]. J. Mater. Chem., 2010, 20: 6681 doi: 10.1039/c0jm00810a
[12]	Guo L, Zhu S H, Zhang S T, et al. Theoretical studies of three triazole derivatives as corrosion inhibitors for mild steel in acidic medium [J]. Corros. Sci., 2014, 87: 366 doi: 10.1016/j.corsci.2014.06.040
[13]	Zhou S Q, Cao C N. The synergistic effect of organic amines and chloride ion on the corrosion inhibition of iron in acidic solution [J]. J. Chin. Soc. Corros. Prot., 1986, 6: 283
	(周盛奇, 曹楚南. 酸性溶液中有机胺和氯离子对铁缓蚀的协同作用 [J]. 中国腐蚀与防护学报, 1986, 6: 283)
[14]	Cao K Y, Yu Z X, Yin D, et al. Fabrication of BTA-MOF-TEOS-GO nanocomposite to endow coating systems with active inhibition and durable anticorrosion performances [J]. Prog. Org. Coat., 2020, 143: 105629
[15]	Farha O K, Eryazici I, Jeong N C, et al. Metal-organic framework materials with ultrahigh surface areas: is the sky the limit? [J]. J. Am. Chem. Soc., 2012, 134: 15016 doi: 10.1021/ja3055639 pmid: 22906112
[16]	Koh K, Wong-Foy A G, Matzger A J. A porous coordination copolymer with over 5000 m²/g BET surface area [J]. J. Am. Chem. Soc., 2009, 131: 4184 doi: 10.1021/ja809985t
[17]	Gao X C, Cui R X, Ji G F, et al. Size and surface controllable metal-organic frameworks (MOFs) for fluorescence imaging and cancer therapy [J]. Nanoscale, 2018, 10: 6205 doi: 10.1039/C7NR08892B
[18]	Liu Y Y, Ng Z, Khan E A, et al. Synthesis of continuous MOF-5 membranes on porous α-alumina substrates [J]. Microporous Mesoporous Mater., 2009, 118: 296 doi: 10.1016/j.micromeso.2008.08.054
[19]	Liu X J, Li W H, Wang W, et al. Synthesis and characterization of pH-responsive mesoporous chitosan microspheres loaded with sodium phytate for smart water-based coatings [J]. Mater. Corros., 2018, 69: 736
[20]	Cao C N, Zhang J Q. An Introduction to Electrochemical Impedance Spectroscopy [M]. Beijing: Science Press, 2002
	(曹楚南, 张鉴清. 电化学阻抗谱导论 [M]. 北京: 科学出版社, 2002)
[21]	Xie D M, Tong S P, Cao J L. Fundamental Knowledge of Applied Electrochemistry [M]. Beijing: Chemical Industry Press, 2013
	(谢德明, 童少平, 曹江林. 应用电化学基础 [M]. 北京: 化学工业出版社, 2013)

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