Please wait a minute...
Journal of Chinese Society for Corrosion and protection  2022, Vol. 42 Issue (1): 34-38    DOI: 10.11902/1005.4537.2020.234
Current Issue | Archive | Adv Search |
Effect of SO42- on Corrosion of Stainless Steel in Solutions Containing Cl-
YIN Yangyang1, LIU Jianfeng1,2,3(), MIAO Keji1, WANG Ting1, NING Kai1, PAN Weiguo1,2, YUAN Binxia1,3, YIN Shibin3,4
1.College of Energy and Mechanical Engineering, Shanghai University of Electric Power, Shanghai 200090, China
2.Key Laboratory of Environmental Protection Technology for Clean Power Generation in Machinery Industry, Shanghai 200090, China
3.Key Laboratory of New Processing Technology for Non-ferrous Metals and Materials (Ministry of Education), Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, Nanning 530004, China
4.Guangxi University College of Chemistry and Chemical Engineering, Nanning 530004, China
Download:  HTML  PDF(622KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

The research progress of the influence of Cl- and SO42- on the corrosion of austenitic stainless steel is reviewed. The corrosion mechanism of austenitic stainless steel and the influence of Cl- and SO42- on the corrosion of stainless steel are described, meanwhile, the reasons why SO42- can inhibit the corrosion of stainless steel in chloride solutions proposed by different researchers and their opinions differ are summarized and discussed . Finally, suggestions for future research directions are put forward.

Key words:  austenitic stainless steel      stainless steel corrosion      Cl-      SO42-     
Received:  11 November 2020     
ZTFLH:  TG174  
Fund: Open Fund of Guangxi University Key Laboratory of Nonferrous Metals and Characteristic Materials Processing(2020GXYSOF17)
Corresponding Authors:  LIU Jianfeng     E-mail:  janice.liujianfeng@gmail.com
About author:  LIU Jianfeng, E-mail: janice.liujianfeng@gmail.com

Cite this article: 

YIN Yangyang, LIU Jianfeng, MIAO Keji, WANG Ting, NING Kai, PAN Weiguo, YUAN Binxia, YIN Shibin. Effect of SO42- on Corrosion of Stainless Steel in Solutions Containing Cl-. Journal of Chinese Society for Corrosion and protection, 2022, 42(1): 34-38.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2020.234     OR     https://www.jcscp.org/EN/Y2022/V42/I1/34

Fig.1  Schematic diagram of corrosion mechanism
1 Li X D. Corrosion crystallization mechanism research of 316L stainless steel equipments of ammonium sulfate crystallization devices [D]. Shanghai: East China University of Science and Technology, 2011
李小东. 硫铵结晶装置中316L不锈钢设备腐蚀机理的研究 [D]. 上海: 华东理工大学, 2011
2 Malik A U, Kutty P C M, Siddiqi N A, et al. The influence of pH and chloride concentration on the corrosion behaviour of AISI 316L steel in aqueous solutions [J]. Corros. Sci., 1992, 33: 1809
3 Wang Z, Zhou Z Q, Zhang L, et al. Effect of pH on the electrochemical behaviour and passive film composition of 316L stainless steel [J]. Acta Metall. Sin. (Engl. Lett.), 2019, 32: 585
4 Deng B, Jiang Y M, Liao J X, et al. Dependence of critical pitting temperature on the concentration of sulphate ion in chloride-containing solutions [J]. Appl. Surf. Sci., 2007, 253: 7369
5 Qiu X L, Xue Y N, Wang R. Corrosion behavior of low chromium steel in 3.5% sodium chloride solution [J]. Mater. Prot., 2014, 47(3): 12
秋兴利, 薛玉娜, 王荣. 3Cr钢在3.5%NaCl溶液中的腐蚀行为 [J]. 材料保护, 2014, 47(3): 12
6 Yin Z F, Feng Y R, Zhao W Z, et al. Pitting corrosion behaviour of 316L stainless steel in chloride solution with acetic acid and CO2 [J]. Corros. Eng. Sci. Technol., 2011, 46: 56
7 Huang S X. Study on the corrosion behavior of 304 stainless steel in simulated pits solution [D]. Nanchang: Nanchang Hangkong University, 2016
黄世新. 304不锈钢在蚀孔模拟溶液中的腐蚀行为研究 [D]. 南昌: 南昌航空大学, 2016
8 Hong T, Nagumo M. The effect of SO42- concentration in NaCl solution on the early stages of pitting corrosion of type 430 stainless steel [J]. Corros. Sci., 1997, 39: 961
9 Yang L J, Xu Y Z, Zhu Y S, et al. Evaluation of interaction effect of sulfate and chloride ions on reinforcements in simulated marine environment using electrochemical methods [J]. Int. J. Electrochem. Sci., 2016, 11: 6943
10 Munis A, Zheng M S, Zhao T Y. Effect of sulfate and meta-silicate ions on pitting corrosion of stainless steel-316 in chloride containing simulated coal gasifier aqueous effluents [J]. Mater. Res. Express, 2019, 6: 076541
11 Niu L B, Nakada K. Effect of chloride and sulfate ions in simulated boiler water on pitting corrosion behavior of 13Cr steel [J]. Corros. Sci., 2015, 96: 171
12 Chou Y L, Wang Y C, Yeh J W, et al. Pitting corrosion of the high-entropy alloy Co1.5CrFeNi1.5Ti0.5Mo0.1 in chloride-containing sulphate solutions [J]. Corros. Sci., 2010, 52: 3481
13 Gong X Z. The behavior of metastable pitting of stainless steel and the relation between metastable pitting and stable pitting [D]. Beijing: Beijing University of Chemical Technology, 2002
龚小芝. 不锈钢亚稳态孔蚀行为及其与稳态孔蚀的关系 [D]. 北京: 北京化工大学, 2002
14 Shahryari A, Kamal W, Omanovic S. The effect of surface roughness on the efficiency of the cyclic potentiodynamic passivation (CPP) method in the improvement of general and pitting corrosion resistance of 316LVM stainless steel [J]. Mater. Lett., 2008, 62: 3906
15 Scheiner S, Hellmich C. Finite Volume model for diffusion- and activation-controlled pitting corrosion of stainless steel [J]. Comput. Methods Appl. Mech. Eng., 2009, 198: 2898
16 Zhang Z W, Liu S F. Corrosion failure cause analysis and microstructure characterization of 304 austenitic stainless steel [J]. Heat Treat. Met., 2019, 44(S1): 96
张志伟, 刘素芬. 304奥氏体不锈钢腐蚀失效原因分析及组织表征 [J]. 金属热处理, 2019, 44(S1): 96
17 Frankel G S. Pitting corrosion of metals: a review of the critical factors [J]. J. Electrochem. Soc., 1998, 145: 2186
18 Burstein G T, Pistorius P C, Mattin S P. The nucleation and growth of corrosion pits on stainless steel [J]. Corros. Sci., 1993, 35: 5762
19 Zuo Y, Wang H T. Electrochemical study on metastable pitting of metals and alloys [J]. Corros. Sci. Prot. Technol., 1999, 11(1): 44
左禹, 王海涛. 金属亚稳态孔蚀行为的电化学研究 [J]. 腐蚀科学与防护技术, 1999, 11(1): 44
20 Zhang J, Ju P F, Wang C L, et al. Corrosion behaviour of 316L stainless steel in hot dilute sulphuric acid solution with sulphate and NaCl [J]. Prot. Met. Phys. Chem. Surf., 2019, 55: 148
21 Zhang Y. Research on corrosion behavior of 304L stainless steel in the role of Cl- [J]. J. Funct. Mater., 2015, 46: 13053
张瑜. 304L不锈钢在Cl-作用下腐蚀行为的研究 [J]. 功能材料, 2015, 46: 13053
22 Chang L, Wang F T, Zhang X N, et al. Analysis on the corrosion causes of stainless steel tubes in condensers of 600 MW unit [J]. Ind. Water Treat., 2019, 39(6): 111
常亮, 王锋涛, 张小霓等. 600 MW机组凝汽器不锈钢管腐蚀原因分析 [J]. 工业水处理, 2019, 39(6): 111
23 Liao K X, Cao Z H, He Z F. Influence of chloride ion on critical pitting temperature of 316L stainless steel [J]. Corros. Prot., 2017, 38: 446
廖柯熹, 曹增辉, 贺站锋. 氯离子对316L不锈钢临界点蚀温度的影响 [J]. 腐蚀与防护, 2017, 38: 446
24 Han Y J, Chen Y Y. Electrochemistry corrosion behaviors of 316L stainless steel in different electric conductivity seawaters and NaCl solutions [J]. Mater. Rev., 2012, 26(20): 57
韩亚军, 陈友媛. 316L不锈钢在不同电导率海水和NaCl溶液中的电化学腐蚀行为 [J]. 材料导报, 2012, 26(20): 57
25 Liu D Y, Wang M M, Zhang L, et al. Localized corrosion law of 316L stainless steel in deep seawater [J]. Equip. Environ. Eng., 2019, 16(1): 102
刘殿宇, 王毛毛, 张亮等. 316L不锈钢在海洋深水环境中的局部腐蚀规律 [J]. 装备环境工程, 2019, 16(1): 102
26 Xin S S, Li M C, Shen J N. The influence of seawater temperature and concentration on the pitting corrosion of 316L stainless steel [J]. Acta Metall. Sin., 2014, 50: 373
辛森森, 李谋成, 沈嘉年. 海水温度和浓缩度对316L不锈钢点蚀性能的影响 [J]. 金属学报, 2014, 50: 373
27 Zhang M L, Wang D, Wang X F, et al. Influence of Cl- concentrations on the corrosion behavior of 316L stainless steel in ocean environment [J]. Mater. Prot., 2019, 52(1): 34
张鸣伦, 王丹, 王兴发等. 海水环境中Cl-浓度对316L不锈钢腐蚀行为的影响 [J]. 材料保护, 2019, 52(1): 34
28 Shi Y H, Yu Y, Liang P, et al. Corrosion behaviors of 316L austenitic stainless steel in solutions containing chloride ions [J]. Mater. Prot., 2015, 48(8): 29
史艳华, 于洋, 梁平等. 316L不锈钢在氯离子环境中的腐蚀行为 [J]. 材料保护, 2015, 48(8): 29
29 Seman A A, Chan J K, Norazman M A, et al. Corrosion behavior of heat-treated and cryorolled Al 5052 alloys in different chloride ion concentrations [J]. Anti-Corros. Methods Mater., 2020, 67: 7
30 Chen Y, Sridharan K, Allen T. Corrosion behavior of ferritic-martensitic steel T91 in supercritical water [J]. Corros. Sci., 2006, 48: 2843
31 Monteiro R D, van de Wetering J, Krawczyk B, et al. Corrosion behaviour of Type 316L stainless steel in hot caustic aqueous environments [J]. Met. Mater. Int., 2020, 26:630
32 Lin H B, Zhang J W, Li S Y. Effect of temperature on corrosion behavior of 316L stainless steel in 3.5%NaCl solution [J]. J. Liaoning Univ. Pet. Chem. Technol., 2019, 39(2): 54
林海波, 张巨伟, 李思雨. 温度对316L不锈钢在3.5%NaCl溶液中腐蚀行为的影响 [J]. 辽宁石油化工大学学报, 2019, 39(2): 54
33 Gong X Z, Xiao J, Zuo Y, et al. Effect of pH value on metastable pitting behaviour of stainless steel [J]. J. Beijing Univ. Chem. Technol., 2002, 29(4): 29
龚小芝, 肖娟, 左禹等. 溶液pH值对不锈钢亚稳态孔蚀行为的影响 [J]. 北京化工大学学报, 2002, 29(4): 29
34 Xie J J, Ningyu H, Sun X, et al. Corrosion behavior of 316L stainless Steel under Cl- corrosion medium [J]. IOP Conf. Ser.: Mater. Sci. Eng., 2020, 711: 012058
35 Du N, Tian W M, Zhao Q, et al. Effect of SO42- concentration on 304 stainless steel pitting corrosion in NaCl solution [J]. J. Mater. Eng., 2012, (7): 64
杜楠, 田文明, 赵晴等. SO42-浓度对304不锈钢在NaCl溶液中点蚀行为影响的研究 [J]. 材料工程, 2012, (7): 64
36 Tang X, Zhang L, Wang Z, et al. Effect of SO42- on the passive and pitting behavior of 316 L austenite stainless steel in a Cl- containing solution [J]. J. Eng. Sci., 2018, 40: 366
唐娴, 张雷, 王竹等. SO42-对含Cl-溶液中316L奥氏体不锈钢钝化行为及点蚀行为的影响 [J]. 工程科学学报, 2018, 40: 366
37 Marcus P, Maurice V, Strehblow H H. Localized corrosion (pitting): A model of passivity breakdown including the role of the oxide layer nanostructure [J]. Corros. Sci., 2008, 50: 2698
38 Pujar M G, Anita T, Shaikh H, et al. Use of electrochemical noise (EN) technique to study the effect of sulfate and chloride ions on passivation and pitting corrosion behavior of 316 stainless steel [J]. J. Mater. Eng. Perform., 2007, 16: 494
39 Liao J X, Jiang Y M, Wu W W, et al. Influence of SO42- in aqueous solution containing Cl- on the critical pitting corrosion temperature of 316 stainless steel [J]. Acta Metall. Sin., 2006, 42: 1187
廖家兴, 蒋益明, 吴玮巍等. 含Cl-溶液中SO42-对316不锈钢临界点蚀温度的影响 [J]. 金属学报, 2006, 42: 1187
40 Xie Q, Liang L. Corrosion-resistant effect of SO42- in cooling water on stainless steel tubes of condenser [J]. J. Shanghai Univ. Electric Power, 2000, 16(2): 33
解群, 梁磊. 冷却水中SO42-对凝汽器不锈钢管的缓蚀作用 [J]. 上海电力学院学报, 2000, 16(2): 33
[1] AN Yiqiang, WANG Xin, CUI Zhongyu. Effect of Nitric Acid Passivation on Critical Cl- Concentration for Corrosion of 304 Stainless Steel in Simulated Concrete Pore Solution[J]. 中国腐蚀与防护学报, 2021, 41(6): 804-810.
[2] LIU Quanbing, LIU Zongde, GUO Shengyang, XIAO Yi. Galvanic Corrosion Behavior of 5083 Al-alloy and 30CrMnSiA Steel in NaCl solutions[J]. 中国腐蚀与防护学报, 2021, 41(6): 883-891.
[3] XU Guifang, LI Yuan, LEI Yucheng, ZHU Qiang. Effect of Relative Flow Velocity on Corrosion Behavior of High Nitrogen Austenitic Stainless Steel in Liquid Lead-bismuth Eutectic Alloy[J]. 中国腐蚀与防护学报, 2021, 41(6): 899-904.
[4] DING Qingmiao, GAO Yuning, HOU Wenliang, QIN Yongxiang. Influence of Cl- Concentration on Corrosion Behavior of Reinforced Concrete in Soil[J]. 中国腐蚀与防护学报, 2021, 41(5): 705-711.
[5] LV Xianghong, MA Xiaofeng, HU Zhaowei, LI Yuanyuan, WANG Chen. Corrosion Behavior of T/S-52K Straight Seam Pipeline Steel in Solutions of Different NaCl Concentration[J]. 中国腐蚀与防护学报, 2021, 41(4): 555-559.
[6] QIAO Zhongli, WANG Ling, SHI Yanhua, YANG Zongkui. Microstructure and Corrosion Resistance of Welded Joint of 14Cr1MoR Steel[J]. 中国腐蚀与防护学报, 2021, 41(3): 400-404.
[7] ZHANG Huiyun, ZHENG Liuwei, MENG Xianming, LIANG Wei. Effect of Electrochemical Hydrogen Charging on Hydrogen Embrittlement Sensitivity of Cr15 Ferritic and 304 Austenitic Stainless Steels[J]. 中国腐蚀与防护学报, 2021, 41(2): 202-208.
[8] DENG Peichang, ZHONG Jie, WANG Kun, HU Jiezhen, LI Ziyun, CHEN Chuxin, SHEN Xiaohan. Important Influential Factor for Corrosion of High-altitude Marine Engineering Equipment in Atmosphere-chloride Ion Deposition Rate[J]. 中国腐蚀与防护学报, 2020, 40(5): 474-478.
[9] WEN Yang, XIONG Lin, CHEN Wei, XUE Gang, SONG Wenxue. Chloride Penetration Resistance of Polyvinyl Alcohol Fiber Concrete under Dry and Wet Cycle in Chloride Salt Solutions[J]. 中国腐蚀与防护学报, 2020, 40(4): 381-388.
[10] SUN Xiaoguang,HAN Xiaohui,ZHANG Xingshuang,ZHANG Zhiyi,LI Gangqing,DONG Chaofang. Corrosion Resistance and Environmentally-friendly Chemical Passivation of Welded Joints for Ultra-low Carbon Austenitic Stainless Steel[J]. 中国腐蚀与防护学报, 2019, 39(4): 345-352.
[11] Xiwu LIU,Xiaoyan ZHAO,Xin'an CUI,Lanfei XU,Xiaowei LI,Rongqi CHENG. Corrosion Behavior of 304L Stainless Steel in Nitric Acid-Sodium Nitrate Solutions[J]. 中国腐蚀与防护学报, 2018, 38(6): 543-550.
[12] Xiaoyan ZHAO, Xiwu LIU, Xin'an CUI, Fengchang YU. Corrosion Behavior of 304L Steel in Nitric Acid Environment[J]. 中国腐蚀与防护学报, 2018, 38(5): 455-462.
[13] Xiaocheng ZHOU, Qiaoqi CUI, Jinghuan JIA, Zhiyong LIU, Cuiwei DU. Influence of Cl- Concentration on Stress Corrosion Cracking Behavior of 316L Stainless Steel in Alkaline NaCl/Na2S Solution[J]. 中国腐蚀与防护学报, 2017, 37(6): 526-532.
[14] Chao SUN, Xiao YANG, Yuhua WEN. Effect of High-Al Austenitic Stainless Alloy Coatings Prepared by Magnetron Sputtering on High Temperature Oxidation Resistance of 316 Stainless Steel[J]. 中国腐蚀与防护学报, 2017, 37(6): 590-596.
[15] Shuan LIU,Kaihe ZHOU,Yunhui FANG,Xiaozhong XU,Jiong JIANG,Xiaoping GUO,Wenru ZHEN,Jibin PU,Liping WANG. Effect of Environmental Factors on Corrosion Behavior of Zn in Saturated Zn(OH)2 Solution I—Cl- Concentration and pH Values[J]. 中国腐蚀与防护学报, 2016, 36(6): 522-528.
No Suggested Reading articles found!