Corrosion Behavior of 316L Stainless Steel in Simulated Oilfield Wastewater

doi:10.11902/1005.4537.2020.255

Journal of Chinese Society for Corrosion and protection

2021, Vol. 41

Issue (5): 625-632 DOI: 10.11902/1005.4537.2020.255

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Corrosion Behavior of 316L Stainless Steel in Simulated Oilfield Wastewater

ZHANG Longhua¹, LI Changjun², PAN Lei², HAN Sike¹, WANG Xin¹, CUI Zhongyu¹(

)

^1.School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
^2.Xinjiang Baomo Environment Engineering Co. Ltd. , Karamay 834000, China

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Abstract

The influence of S^2- concentration on the corrosion behavior of 316L stainless steel in a simulated oilfield wastewater was studied by means of electrochemical technique and X-ray photoelectron spectroscopy (XPS). The results show that the existence of S^2- can accelerate the corrosion of 316L, and with the increase of S^2- concentration, its corrosion tendency increases and the corrosion resistance decreases. XPS results demonstrate that FeS presents in the passive film of 316L stainless steel, which hinders the further growth of the film. Moreover, the outer layer of passive film is loose, therewith the protection performance of the film is deteriorated.

Key words: 316L stainless steel oilfield wastewater sulfide passive film

Received: 09 December 2020

ZTFLH:

TG172

Fund: Key R&D Program Public Welfare Special Fund of Shandong Province(2019GHY112050)

Corresponding Authors: CUI Zhongyu E-mail: cuizhongyu@ouc.edu.cn

About author: CUI Zhongyu, E-mail: cuizhongyu@ouc.edu.cn

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Cite this article:

ZHANG Longhua, LI Changjun, PAN Lei, HAN Sike, WANG Xin, CUI Zhongyu. Corrosion Behavior of 316L Stainless Steel in Simulated Oilfield Wastewater. Journal of Chinese Society for Corrosion and protection, 2021, 41(5): 625-632.

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https://www.jcscp.org/EN/10.11902/1005.4537.2020.255 OR https://www.jcscp.org/EN/Y2021/V41/I5/625

Fig.1 Potentiodynamic cyclic polarization curves of 316L stainless steel in simulated oilfield wastewater with different concentration of sulfide

Fig.2 I-t curves of 316L stainless steel at -0.1 V_SCE (a), -0.2 V_SCE (b), -0.3 V_SCE (c) and -0.4 V_SCE (d) under solutions of various sulfur concentrations

Fig.3 Steady-state current density versus applied potential plot with different concentration of S^2-

Fig.4 Nyquist (a, c, e, g) and Bode (b, d, f, h) plots of potential variation under 0 mg/L (a, b), 50 mg/L (c, d), 100 mg/L (e, f) and 200 mg/L (g, h) S^2- concentrations

Fig.5 Equivalent circuit model for interpreting the impedance spectra of 316L stainless steel passive film: (a) Model 1, (b) Model 2

Table 1 Fitting parameters of values equivalent circuit model

Fig.6 XPS spectra of the main elements in the passive film formed by 316L strainless steel at -0.1 V_SCE potential: (a) with a sulfide concentration of 0 mg/L: (a1) Cr2p_3/2, (a2) Fe2p_3/2, (a3) O1s, (b) with a sulfide concentration of 200 mg/L: (b1) Cr2p_3/2, (b2) Fe2p_3/2, (b3) O1s, (b4) S2P_3/2

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