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GALVANIC CORROSION BEHAVIORS OF Q235-304L COUPLE IN Na2S SOLUTION |
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北京科技大学材料学院 |
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Abstract Galvanic corrosion behaviors of Q235-304L couple with various cathode/anode area ratios in three different concentrations of Na2S solutions were studied by the potentiodynamic polarization curves,galvanic method and immersion test.Surface morphologies of the samples were also analyzed by SEM after rust cleaning.The results showed that:both the cathodic and anodic processes of 304L were controlled by the electrochemical step,while the anodic process of Q235 exhibited an apparent characteristics of activation-diffusion mixed contro
l;a cathodic process as well as an anodic process took place on the surface of Q235 after coupled and the dissolution current of Q235 was much more above the galvanic current got by galvanic corrosion method;as the area ratio increases,the galvanic effect increases;and with the elevation of the concentration of S2-,the corrosion rate of Q235 creased,so did the galvanic effect.
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Received: 26 July 2004
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[1]Mansfeld F.The relationship between galvanic current and dissolu-tion rates[J].Corrosion,1973,29(10):403-405 [2]Akid R,Mills D J.A comparison between conventional macroscopicand novel microscopic scanning electrochemical methods to evaluategalvanic corrosion[J].Corros.Sci.,2001,43:1203-1216 [3]Abreu C M,Cristoóbal M J,Montemor M F.Galvanic coupling be-tween carbon steel and austenitic stainless steel in alkaline media[J].Electrochi.Acta,2002,47:2271-2279 [4]Tahara Akira,Kodama Toshiaki.Potential distribution measure-ment in galvanic corrosion of Zn/Fe couple by means of Kelvinprobe[J].Corros.Sci.,2000,42:655-673 [5]Varela F E,Kurata Y,Sanada N.The influence of temperature onthe galvanic corrosion of a cast iron-stainless steel couple(predic-tion by boundary element method)[J].Corros.Sci.,1997,39(4):775-788 [6]Zahran R P,Sedahmed F H.Galvanic corrosion of zinc in turbulent-ly moving saline water containing drag reducing polymers[J].Mater.Lett.,1997,31(5):29-33 [7]Huang G Q,Yu C J,Li L S.Study on galvanic corrosion of steelcouples in seawater[J].J.Chin.Soc.Corros.Prot.,2001,21(1):46-53(黄桂桥,郁春娟,李兰生.海水中钢的电偶腐蚀研究[J].中国腐蚀与防护学报,2001,21(1):46-53) [8]Sun D B,Li T,Yu H Y.Formation and effect of tribo-cell for Fe-Cr alloy[J].Electrochemistry,1998,4(3):307-312(孙冬柏,李涛,俞宏英.铁铬合金摩擦破损微电偶的形成及作用[J].电化学,1998,4(3):307-312) [9]Zhang X Y,Du Y L.Effect of iron sulfide scale on corrosion behav-ior of UNS G11180 steel in 5%NaCl solution containing H2S[J].Corros.Sci.Prot.Technol.,1997,9(1):19-23(张学元,杜元龙.Fe的硫化物膜对UNS G11180钢在含H2S的NaCl溶液中的腐蚀行为的影响[J].腐蚀科学与防护技术,1997,9(1):19-23) [10]Mansfeld F.Galvanic interaction between active and passive titani-um[J].Corrosion,1973,29(2):56-58 [11]Mansfeld F.Area relationships in galvanic corrosion[J].Corrosion,1971,27(10):436-442 [12]Bellucci F.Galvanic corrosion between nonmetallic composites andmetals:ⅠEffects of metal and of temperature[J].Corrosion,1991,47(10):808-819 [13]Jiang T,Zuo Y,Xiong J P.Effect of several sulfur containing an-ions on pitting mild steel[J].Corros.Sci.Prot.Technol.,2001,13(5):249-253(姜涛,左禹,熊金平.含S阴离子对低碳钢孔蚀的影响[J].腐蚀科学与防护技术,2001,13(5):249-253) [14]Ke W,Chen J W.Development of corrosion research for petroleumprocessing industry[J].Petrochem.Corros.Prot.,1997,14(2):1-11(柯伟,陈进伟.炼油工业中腐蚀研究的进展[J].石油化工腐蚀与防护,1997,14(2):1-11) |
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