Corrosion Resistance of Silane Film Modified by Hexagonal Boron Nitride

doi:10.11902/1005.4537.2020.176

Journal of Chinese Society for Corrosion and protection

2021, Vol. 41

Issue (6): 864-870 DOI: 10.11902/1005.4537.2020.176

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Corrosion Resistance of Silane Film Modified by Hexagonal Boron Nitride

DING Yukang¹, CHEN Guomei², NI Zifeng¹(

), LIU Yaxuan¹, QIAN Shanhua¹, BIAN Da¹, ZHAO Yongwu¹

^1.College of Mechanical Engineering, Jiangnan University, Wuxi 214122, China
^2.School of Mechanical and Electrical Engineering, Wuxi Vocational Institute of Commerce, Wuxi 214122, China

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Abstract

Powders of boron nitride were non-covalently modified with dopamine, and then composite silane coatings dopped with non-covalently modified boron nitride were prepared on 40Cr alloy steel surface via socking method. The modified powder was characterized by SEM, FTIR and TGA. The corrosion resistance of silane composite film was studied by SEM, FTIR, wettability measurement and potentiodynamic polarization curve. The results showed that the polydopamine successfully coats the boron nitride particles and adheres them onto the 40Cr steel surface, the thickness of the mBN-doped silane film increased to 1.812 μm, and the surface contact angle of the mBN/BTESPT silane composite film reached 91.97°. The corrosion current density of the composite film coated steel was 9.187×10^-8 A/cm², which implies that the corrosion resistance of the composite film was about 30 times higher than that of the bare silane film, and it showed also better corrosion resistance in the neutral salt spray test. Through the physical filling and chemical bonding of silane film, mBN hindered the diffusion of corrosion medium and significantly enhanced the corrosion resistance of metal.

Key words: silane film hexagonal boron nitride modification corrosion resistance

Received: 27 September 2020

ZTFLH:

TG174.4

Fund: National Natural Science Foundation of China(51675232)

Corresponding Authors: NI Zifeng E-mail: nizf@jiangnan.edu.cn

About author: NI Zifeng, E-mail: nizf@jiangnan.edu.cn

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	Yukang DING
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	Yaxuan LIU
	Shanhua QIAN
	Da BIAN
	Yongwu ZHAO

Cite this article:

DING Yukang, CHEN Guomei, NI Zifeng, LIU Yaxuan, QIAN Shanhua, BIAN Da, ZHAO Yongwu. Corrosion Resistance of Silane Film Modified by Hexagonal Boron Nitride. Journal of Chinese Society for Corrosion and protection, 2021, 41(6): 864-870.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2020.176 OR https://www.jcscp.org/EN/Y2021/V41/I6/864

Fig.1 SEM images of BN (a) and mBN (b)

Fig.2 FT-IR spectra of BN and mBN

Fig.3 Thermal degradation of BN and mBN

Fig.4 Surface topographies of single silane film (a) and composite silane film (b)

Fig.5 FT-IR spetra of BTESPT film and mBN/BTESPT film

Fig.6 Contact angles of different treated steel surfaces for bare steel (a), BTESPT film (b), BN/BTESPT film (c) and mBN/BTEPST film (d)

Fig.7 Tafel curves of samples doped with different contents (a) and different treatments (b)

Table 1 Tafel potentiodynamic corrosion parameters

Fig.8 Surface morphologies of different samples under salt spray test: (a) alloy steel, (b) BTESPT film, (c) mBN/BTESPT film, (a1~c1) 4 h, (a2~b2) 12 h, (a3~c3) 24 h

Fig.9 Schematic diagram of mBN/BTESPT composite film

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