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J Chin Soc Corr Pro  2005, Vol. 25 Issue (1): 44-47     DOI:
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PENETRATION OF Al ELECTROLYTE INTO TiB2 COATING
Bing Li;Zhuxian Qiu;Jun Li;Jinfu Xv
华东理工大学资源与环境工程学院金属材料工程专业379信箱
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Abstract  TiB2 coating was electrodeposited on graphite substrate from molten salts.The penetration of sodium and electrolyte into the TiB2 coating,cathode block used as cathode of Al electrolysis and graphite was tested.After four-hour electrolysis,the examinations by phenolphthalein reagent indicated that the penetration depth of sodium into TiB2 coating is zero,while into cathode block is 16mm and into graphite is 4mm.The EPM analysis showed that Na and F element penetrate slightly into the TiB2 coating, and Al element penetrates relatively more. TiB2 coating hinders sodium formation and decelerates sodium penetrtion,but the penetration mechanism has not been changed.Meanwhile the TiB2 coating has good coherence with the substrate and is well wetted by aluminum.
Key words:  TiB2coating      penetration      Na      electrolysis      
Received:  01 August 2003     
ZTFLH:  TQ134.11  
Corresponding Authors:  Bing Li     E-mail:  drlibing@163.com

Cite this article: 

Bing Li; Zhuxian Qiu; Jun Li; Jinfu Xv. PENETRATION OF Al ELECTROLYTE INTO TiB2 COATING. J Chin Soc Corr Pro, 2005, 25(1): 44-47 .

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https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2005/V25/I1/44

[1]LiuYX .Theresearchprogressoftheinertanodeandwettedcath odeofaluminiumelectrolysis[J].LightMetal,2001,5:26-29(刘业翔.铝电解惰性阳极和可湿润阴极的研究进展[J].轻金属,2001,5:26-29)
[2]LiB .Studyonpenetrationofelectrolysisintocathodematerialsofaluminumelectrolysis[D].DoctoralDissertation,NortheastUniver sity,2001(李冰.铝电解质对阴极材料渗透的研究[D].博士学位论文,东北大学,2001)
[3]MakytaM ,DanekV .Electrodepositionoftitaniumdiboridefromfusedsalts[J].JAppliedElectrochemistry,1996,26:319-324
[4]GerhardEtt,ElisabeteJPessine.PulsecurrentplatingofTiB2 inmoltenfluoride[J].ElectrochimicaActa,1999,44:2859-2870
[5]LiB ,ZhouF ,QiuZX .PreparationofTiB2 coatedcathodeofAlelectrolysis[J].J.Mater.Sci.Technol.,2001,17:S171-S173
[6]LiB ,YaoGC ,QiuZX .ElectrodepositionofTiB2 coatingfrommoltenstlats[A].ProceedingsoftheSeventhJapan-ChinaBilater alConferenceonMoltenSaltsChemistryandTechnology[C].Japan,2000,December
[7]LiB ,WangJQ ,GaoBL ,QiuZX .Studyonpenetrationphenomen-onofcathodeblockinaluminumelectrolysis[J].LightMetals,2001,7:37-40(李冰,王俊青,高炳亮,邱竹贤.铝电解阴极碳块渗透现象的研究[J].轻金属,2001,7:37-40)
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