|
|
|
| Thermal Conductivity and Corrosion Resistance of Epoxy Composite Coatings with Polydopamine Modified Mult-scale Boron Nitrides |
LIU Suyun1, LI Wanting2, ZHOU Runqi1, LIU Rui2( ), DONG Zhijun1, LIU Li2, WANG Fuhui2 |
1.Institute of Technology for Future Industry, Shenzhen University of Information Technology, Shenzhen 518172, China 2.Corrosion and Protection Center, School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China |
|
Cite this article:
LIU Suyun, LI Wanting, ZHOU Runqi, LIU Rui, DONG Zhijun, LIU Li, WANG Fuhui. Thermal Conductivity and Corrosion Resistance of Epoxy Composite Coatings with Polydopamine Modified Mult-scale Boron Nitrides. Journal of Chinese Society for Corrosion and protection, 2026, 46(3): 767-776.
|
|
|
Abstract The effect of the addition of polydopamine modified multi-scale boron nitrides (PDA-BN) on the thermal conductivity and corrosion resistance of epoxy resin composite coatings was assessed, special attention was paid to the influence of the addition of polydopamine modified multi-scale BN with different ratios on the performance of epoxy composite coating, then the optimal ratio for different dopamine modified multi-scale BNs was acquired. The results showed that the addition of the multi-scale PDA-BN can improve the thermal conductivity of epoxy coatings. The optimal ratio of PDA-BN (5-10 μm) to PDA-BN (1-2 μm) is 5:1, and when the total addition amount of PDA-BNs is 10%, the thermal conductivity can reach 0.3748 W·m-1·K-1. In addition, the thermal conductivity of the coatings increases with the increase of the amount of multi-scale PDA-BN addition. When the amount is low (5%-20%), the multi-scale PDA-BN are uniformly dispersed, which can improve the protective performance of the epoxy composite coatings. When the addition reaches 30%, aggregations defects appear inside the coatings, and the protective performance of PDA-BN epoxy composite coatings sharply decreases. 15% multi-scale PDA-BN addition in the composite coatings has a higher thermal conductivity (0.4207 W·m-1·K-1) and the optimal protective performance (|Z|0.01 Hz of the coatings maintained 1.47 × 109 Ω·cm2) even after immersion in 3.5%NaCl solution for 14 d.
|
|
Received: 10 June 2025
32134.14.1005.4537.2025.177
|
|
|
| Fund: Shenzhen Science and Technology Program(JCYJ20241202130800001);Shenzhen Science and Technology Program(KCXFZ20240903094159005);Shenzhen Science and Technology Program(20220817212651001);Guangdong Provincial Department of Education Project(2023KTSCX323) |
Corresponding Authors:
LIU Rui, E-mail: liurui@mail.neu.edu.cn
|
| [1] |
Che J, Sun W, Wang L D, et al. Study on thermal conductivity and corrosion resistance of BTA-loaded mesoporous SiO2-graphene/epoxy coating [J]. Mod. Chem. Ind., 2023, 43(3): 78
|
|
车 建, 孙 文, 王立达 等. BTA@介孔SiO2-石墨烯/环氧涂层的导热防腐性能研究 [J]. 现代化工, 2023, 43(3): 78
|
| [2] |
Yang Z Q. Investigation on the corrosion protection performance of fluorinated graphene/polymer functional coatings [D]. Dalian: Dalian University of Technology, 2021
|
|
杨政清. 氟化石墨烯/聚合物功能涂层的防腐性能研究 [D]. 大连: 大连理工大学, 2021
|
| [3] |
Xu F, Ye P, Peng J W, et al. Cerium methacrylate assisted preparation of highly thermally conductive and anticorrosive multifunctional coatings for heat conduction metals protection [J]. Nano-Micro Lett., 2023, 15: 201
doi: 10.1007/s40820-023-01163-w
pmid: 37596381
|
| [4] |
Yang Z Q, Che J, Zhang Z Z, et al. High-efficiency graphene/epoxy composite coatings with outstanding thermal conductive and anti-corrosion performance [J]. Composites, 2024, 181A: 108152
|
| [5] |
Liu S Y, Liu L, Guo H X, et al. Electrochemical polymerization of polyaniline-reduced graphene oxide composite coating on 5083 Al alloy: Role of reduced graphene oxide [J]. Electrochem. Commun., 2019, 98: 110
doi: 10.1016/j.elecom.2018.12.004
|
| [6] |
Chen S R, Chen W G, Qian Y, et al. Preparation and perfromance of rare earth cerium modified graphene oxide/waterborne epoxy resin composite coating [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 107
|
|
陈施润, 陈文革, 钱 颖 等. 稀土铈改性石墨烯/水性环氧树脂复合涂料涂装技术研究 [J]. 中国腐蚀与防护学报, 2024, 44: 107
|
| [7] |
Wang T, Gao K, Zhong S N, et al. Research progress on hydrophobic modification of polyurethane coatings [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 823
|
|
王 汀, 高 坤, 钟赛男 等. 聚氨酯涂层的疏水改性研究进展 [J]. 中国腐蚀与防护学报, 2024, 44: 823
|
| [8] |
Qian Y X. Research on thermal conductive and electromagnetic wave absorption properties of three-dimensional network structure epoxy resin-based composites [D]. Wuhan: Huazhong University of Science and Technology, 2024
|
|
钱勇鑫. 三维网络结构环氧树脂基复合材料导热吸波性能研究 [D]. 武汉: 华中科技大学, 2024
|
| [9] |
Wu X D. Study on the preparation and properties of modified boron nitride/epoxy resin thermal conductive and insulative composites [D]. Hangzhou: Zhejiang University, 2024
|
|
吴旭东. 改性氮化硼/环氧树脂导热绝缘复合材料的制备与性能研究 [D]. 杭州: 浙江大学, 2024
|
| [10] |
Liu Z Q, Yin X C, Zhang H, et al. Efficient preparation of BN/UHMWPE composites with oriented thermal conductivity by powder solid-state extrusion [J]. Composites, 2023, 172A: 107598
|
| [11] |
Shi N Q, Li H Y, Li X, et al. ZIF-8 and benzimidazole co-modified h-BN for enhancing anti-corrosion performance of epoxy coatings [J]. Prog. Org. Coat., 2023, 183: 107808
|
| [12] |
Shi N Q, Li Z K, Li X, et al. H-BN base triple-functional filler enhances the anti-corrosion performance of epoxy coating [J]. Polymer, 2024, 300: 126975
doi: 10.1016/j.polymer.2024.126975
|
| [13] |
Wang K, Shen L, Wen N B, et al. Designing BN@CF hybrid to enhance the epoxy resin towards outstanding anti-corrosion and anti-wear performances [J]. Compos. Sci. Technol., 2022, 228: 109646
doi: 10.1016/j.compscitech.2022.109646
|
| [14] |
Luo X H, Chen B, Li Z, et al. Enhanced thermal conductivity and anticorrosion capabilities of epoxy composite coating with quercetin-modified boron nitride [J]. Prog. Org. Coat., 2024, 197: 108773
|
| [15] |
Cui M J, Ren S M, Qin S L, et al. Processable poly(2-butylaniline)/hexagonal boron nitride nanohybrids for synergetic anticorrosive reinforcement of epoxy coating [J]. Corros. Sci., 2018, 131: 187
doi: 10.1016/j.corsci.2017.11.022
|
| [16] |
Li Y, Qian Y X, Jiang Q H, et al. Thermally conductive polymer-based composites: Fundamentals, progress and flame retardancy/anti-electromagnetic interference design [J]. J. Mater. Chem. C, 2022, 10: 14399
doi: 10.1039/D2TC03306B
|
| [17] |
Li C, Wang X, Zhang M, et al. Fluoro-substituted polyaniline deeply incorporation with inert h-BN for interface improvement in anti-corrosion [J]. Prog. Org. Coat., 2022, 170: 106993
|
| [18] |
Yang X, Zhang R H, Pu J B, et al. 2D graphene and h-BN layers application in protective coatings [J]. Corros. Rev., 2021, 39: 93
doi: 10.1515/corrrev-2020-0080
|
| [19] |
Wang W, Wang H L, Zhao J, et al. Self-healing performance and corrosion resistance of graphene oxide-mesoporous silicon layer-nanosphere structure coating under marine alternating hydrostatic pressure [J]. Chem. Eng. J., 2019, 361: 792
doi: 10.1016/j.cej.2018.12.124
|
| [20] |
Wang N, Diao X L, Zhang J, et al. Corrosion resistance of waterborne epoxy coatings by incorporation of dopamine treated mesoporous-TiO2 particles [J]. Coatings, 2018, 8: 209
doi: 10.3390/coatings8060209
|
| [21] |
Jiang F, Cui S Q, Song N, et al. Hydrogen bond-regulated boron nitride network structures for improved thermal conductive property of polyamide-imide composites [J]. ACS Appl. Mater. Interfaces, 2018, 10: 16812
doi: 10.1021/acsami.8b03522
|
| [22] |
Bashir A, Maqbool M, Usman A, et al. Enhancing thermal conductivity and mechanical strength of TPU composites through modulating o-PDA-BN/rGO heterointerface networks [J]. Composites, 2023, 173A: 107676
|
| [23] |
Xing W Y, Chen L, Zhou M T, et al. Preparation of boron nitride/graphene composite thermal conductive filler and study on flame retardant, thermal conductivity and insulation properties of epoxy resin composites [J]. Sci. Sin. Chem., 2023, 53: 207
|
|
邢伟义, 陈 亮, 周慕天 等. 氮化硼/石墨烯复合导热填料的制备及其环氧树脂复合材料阻燃导热绝缘性能的研究 [J]. 中国科学: 化学, 2023, 53: 207
|
| [24] |
Xu W J, Yang C, Su W M, et al. Effective corrosion protection by PDA-BN@CeO2 nanocomposite epoxy coatings [J]. Colloids Surf., 2023, 657A: 130448
|
| [25] |
Wan P Y, Zhao N, Qi F G, et al. Synthesis of PDA-BN@f-Al2O3 hybrid for nanocomposite epoxy coating with superior corrosion protective properties [J]. Prog. Org. Coat., 2020, 146: 105713
|
| [26] |
Cui M J, Ren S M, Zhao H C, et al. Polydopamine coated graphene oxide for anticorrosive reinforcement of water-borne epoxy coating [J]. Chem. Eng. J., 2018, 335: 255
doi: 10.1016/j.cej.2017.10.172
|
| [27] |
Yang N, Yang T, Wang W, et al. Polydopamine modified polyaniline-graphene oxide composite for enhancement of corrosion resistance [J]. J. Hazard. Mater., 2019, 377: 142
doi: S0304-3894(19)30607-7
pmid: 31158583
|
| [28] |
Hu B Y, Guo H, Liu J, et al. Vertically oriented boron nitride/silicon carbide scaffold for thermal-conductive and electrical-insulating phase change composites [J]. Composites, 2023, 168A: 107460
|
| [29] |
Xie A, Wang Y X, Jiang P K, et al. Nondestructive functionalization of carbon nanotubes by combining mussel-inspired chemistry and RAFT polymerization: Towards high dielectric nanocomposites with improved thermal management capability [J]. Compos. Sci. Technol., 2018, 154: 154
doi: 10.1016/j.compscitech.2017.11.022
|
| [30] |
Liu R, Yao Q, Liu L, et al. Studies of different acid doped polyaniline incorporated into epoxy organic coatings on the Mg alloy [J]. Prog. Org. Coat., 2022, 166: 106774
|
| [31] |
Chen L J, Chao L W, Zhao J M. Preparation of CeO2@Zr-MOF composites and their effect on corrosion protectiveness of epoxy coatings on galvanized steel plate [J]. J. Chin. Soc. Corros. Prot., 2025, 45: 664
|
|
陈丽娟, 晁刘伟, 赵景茂. CeO2@Zr-MOF复合材料的制备及其对环氧涂层保护性能的提升作用 [J]. 中国腐蚀与防护学报, 2025, 45: 664
doi: 10.11902/1005.4537.2024.150
|
| [32] |
Liu S Y, Wang X W, Yin Q, et al. A facile approach to fabricating graphene/waterborne epoxy coatings with dual functionalities of barrier and corrosion inhibitor [J]. J. Mater. Sci. Technol., 2022, 112: 263
doi: 10.1016/j.jmst.2021.07.061
|
| No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
| |
Shared |
|
|
|
|
| |
Discussed |
|
|
|
|