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Journal of Chinese Society for Corrosion and protection  2026, Vol. 46 Issue (3): 629-640    DOI: 10.11902/1005.4537.2025.208
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Research Progress on Corrosion and Protection of Metallic Materials in Polar Marine Environments
LI Liang1, YIN Wenchang1, GAO Awang1, HAN Xiaole2(), YANG Yange2
1.Unit 92228, People's Liberation Army, Beijing 100072, China
2.Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
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LI Liang, YIN Wenchang, GAO Awang, HAN Xiaole, YANG Yange. Research Progress on Corrosion and Protection of Metallic Materials in Polar Marine Environments. Journal of Chinese Society for Corrosion and protection, 2026, 46(3): 629-640.

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Abstract  

The requirements of corrosion protection for marine engineering materials are relatively high in the polar marine environments due to its low temperature, strong ultraviolet radiation, freeze-thaw cycles, and complex electrochemical environment. This review paper introduces the current research progress on corrosion and protection of Fe, Al, Cu, Zn, and their alloys in the cold-temperate marine atmosphere and seawater environments. It focuses on analyzing the corrosion mechanism of metallic materials in conditions of low temperature, atmospheric pollutants, ultraviolet radiation, and the effect of cold-temperate marine microorganisms. Moreover, it introduces the research progress in corrosion protection of metallic materials in Antarctic and Arctic regions from three aspects: coating protection technology, sacrificial anode alloy design, and metal surface modification technology. Finally, future research on the corrosion and protection of metals in polar marine environments is proposed based on the problems and development trends encountered in the research on the corrosion and protection of metallic materials in the polar marine environments.
Key words:  polar marine environment      low temperature      metals      corrosion and protection     
Received:  01 July 2025      32134.14.1005.4537.2025.208
ZTFLH:  TG174  
Corresponding Authors:  HAN Xiaole, E-mail: xlhan@imr.ac.cn
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LI Liang
YIN Wenchang
GAO Awang
HAN Xiaole
YANG Yange

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https://www.jcscp.org/EN/10.11902/1005.4537.2025.208     OR     https://www.jcscp.org/EN/Y2026/V46/I3/629

MaterialExposure siteTest period / aCorrosion rate / μm·a-1
Mild steelJubany base138.1
Marsh base124.1
Artigas base165.8
Steel St3Mirnyi station17.8
Q235Zhongshan station116.3
Q460Zhongshan station110.8
Q960Zhongshan station115.8
Ni-Cr-Mo-V steelZhongshan station113.0
AluminiumJubany base14.03
Marsh base13.65
Artigas base12.49
CopperJubany base12.03
Artigas base12.16
Mirnyi station11.1
ZincJubany base11.89
Artigas base12.11
Table 1  Corrosion rates of metals in polar atmospheric environments[21,22]
Fig.1  SEM images (a, b) and corrosion rates (c) of -80 ℃ cooling treated and 25 ℃ untreated EH40 steel after 3 d of immersion corrosion test[25]
Fig.2  Aspect of aluminium surface weathered in marine Antarctic atmospheres[21]: (a) Jubany, 1 a; (b) Jubany, 2 a; (c) Artigas, 1 a; (d) Artigas 2 a
Fig.3  Skyward (a) and groundward (b) morphologies of Q235 steel after 1 a exposure in Antarctic atmosphere and XRD pattern of corrosion products (c)[30]
Fig.4  Corrosion rate changes of EH36 (a) and Q235 (b) steels under dark and UV irradiation[33,34]
Fig.5  EDS analysis on the surfaces of the Zn coupled (a) and uncoupled (b) with 316L stainless steel in 3.5%NaCl solution at -23 ℃: (a1, b1) SEM images, (a2, b2) Zn EDS-mapping, (a3, b3) O EDS-mapping, (a4, b4) atomic percentage of Zn and O elements[42]
Fig.6  Optical profilometry images of the pit morphologies and mass loss of EH40 steel immersed in experimental solutions for 30 d: (a) abiotic, (b) P. cibarius, (c) H. meridiana, (d) mass loss rate histogram[46]
Fig.7  Average rust creep from scribe after 4200 h ageing resistance testing according to ISO 20340[55]
Fig.8  Potential distribution map of micro-region on surface of Al-Zn-In-Mg-Ti-Ga-Mn sacrificial anode: (a) two-dimensional, (b) three-dimensional[77]
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