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Tribo-corrosion Performance of Atmospheric Plasma Sprayed FeCoCrNiMn High Entropy Alloy Coatings |
CAO Fuyang( ), WANG Haoquan, JI Qian, DING Hengnan, YUAN Zhizhong, LUO Rui |
School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China |
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Cite this article:
CAO Fuyang, WANG Haoquan, JI Qian, DING Hengnan, YUAN Zhizhong, LUO Rui. Tribo-corrosion Performance of Atmospheric Plasma Sprayed FeCoCrNiMn High Entropy Alloy Coatings. Journal of Chinese Society for Corrosion and protection, 2024, 44(6): 1529-1537.
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Abstract Herein, FeCoCrNiMn high entropy alloy coatings were prepared on 304 stainless steel, using atmospheric plasma spraying technique. The tribo-corrosion behavior of the coating was studied in simulated seawater. Results show that the FeCoCrNiMn high entropy alloy coating was composed of single FCC phase with an average hardness 221.1HV0.2, in contrast, that of the 304 stainless steel is 159.1HV0.2. The tribo-corrosion test results showed that in 3.5%NaCl solution, the wear volumes of FeCoCrNiMn high entropy alloy coating under loads 5 N and 10 N differentiated by 17%, which were 1.21 × 10-2 mm3 and 1.42 × 10-2 mm3 respectively. The main wear mechanism was believed to be corrosive wear and oxidative wear. The wear volumes of the coating under loads 5 N and 10 N in deionized water differentiated by 11%, which were 1.15 × 10-2 mm3 and 1.28 × 10-2 mm3 respectively. The main wear mechanism was also adhesive wear and oxidative wear. The wear volume in NaCl solution higher than in deionized water might suggest that the corrosion effect of NaCl solution promote the wear process. Meanwhile, in NaCl solution, the open circuit potential of the wear samples under lower load could be restored to close to the level before friction motion in a short time during the static soaking stage. However, the open circuit potential of wear samples under higher load increased slowly and was difficult to return to the level before friction motion due to more severe mechanical damage. This phenomenon might indicate that the mechanical damage caused by wear would accelerate the corrosion process.
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Received: 26 February 2024
32134.14.1005.4537.2024.060
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Fund: Open Fund of Hubei Longzhong Laboratory(2022KF-11);Innovation and Entrepreneurship Plan of Jiangsu Province(1711220035);Startup Fund for Advanced Talents of Jiangsu University(55012-20008) |
Corresponding Authors:
CAO Fuyang, E-mail: fuyangcao@ujs.edu.cn
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