Review on Relationship Between Hot Functional Test Water Chemistry and Corrosion Behavior of Related Component Materials in Pressurized Water Reactor Nuclear Power Plants

doi:10.11902/1005.4537.2023.180

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (3): 529-539 DOI: 10.11902/1005.4537.2023.180

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Review on Relationship Between Hot Functional Test Water Chemistry and Corrosion Behavior of Related Component Materials in Pressurized Water Reactor Nuclear Power Plants

PENG Liyuan¹^,², WU Xinqiang¹(

), ZHANG Ziyu¹, TAN Jibo¹

1. CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2. School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China

Cite this article:

PENG Liyuan, WU Xinqiang, ZHANG Ziyu, TAN Jibo. Review on Relationship Between Hot Functional Test Water Chemistry and Corrosion Behavior of Related Component Materials in Pressurized Water Reactor Nuclear Power Plants. Journal of Chinese Society for Corrosion and protection, 2024, 44(3): 529-539.

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Abstract

Hot functional test (HFT) involves a number of pre-operational exercises without fuel performed to confirm the operability of newly constructed nuclear power plants in the conditions expected during both normal and off-normal operations of a pressurized water reactor (PWR). HFT water chemistry provides an opportunity to produce a stable and protective oxide scale on the key equipment in the primary coolant of PWR which can greatly reduce the corrosion rate of the substrate, the release of the metal ions and the incorporation of activated corrosion products during the subsequently long-term normal operations, and furthermore, relief the dose rate and decrease the corrosion rates of the related component materials for the nuclear power plants. HFT water chemistry adopted in PWR nuclear power plants and the evaluation methods for the HFT water chemistry optimization are reviewed in the present work. The effect of boric acid, lithium hydroxide, pH_T, dissolved hydrogen and Zn injection on the corrosion behavior of key components materials are analyzed. Challenges and trends for HFT water chemistry optimization in the future are also addressed.

Key words: PWR nuclear power plants hot functional test water chemistry dose rate corrosion rate

Received: 29 May 2023 32134.14.1005.4537.2023.180

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52171085)

Corresponding Authors: WU Xinqiang, E-mail: xqwu@imr.ac.cn

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.180 OR https://www.jcscp.org/EN/Y2024/V44/I3/529

Fig.1 Water chemistry parameters at each stage of the step-by-step HFT process^[8]

Fig.2 HFT water chemistry parameters in Tomari Unit 3 and reference plant (the concentration of Zn in Tomari Unit 3 is not shown)^[16]

Table 1 Comparison of the typical and Zn-injected step-by-step HFT water chemistry parameters^[19]

Fig.3 XPS depth profiles of the pre-films formed on 304H stainless steel (a) and alloy 690 (b) after exposure to HFT water chemistry of the AP1000 plant (Zn-injected step-by-step HFT water chemistry)^[19]

Fig.4 Variations of Ni/NiO phase boundary with DH concentration and temperature^[36,37]: (a) Attanasiol, (b) Peter

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