Preparation and Properties of Slippery Anti-corrosion Coating Based on SiO2 with Coral Cluster Morphology

doi:10.11902/1005.4537.2022.398

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (6): 1319-1328 DOI: 10.11902/1005.4537.2022.398

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Preparation and Properties of Slippery Anti-corrosion Coating Based on SiO₂ with Coral Cluster Morphology

ZHANG Kaili¹, DU Lili¹, TAN Jun², LIU Xiangzhou², MA Ji¹, QIU Ping¹(

)

^1.College of New Energy and Materials, China University of Petroleum Beijing, Beijing 102249, China
^2.The Third Gas Production Plant, PetroChina Changqing Oilfield Company, Ordos 017300, China

Cite this article:

ZHANG Kaili, DU Lili, TAN Jun, LIU Xiangzhou, MA Ji, QIU Ping. Preparation and Properties of Slippery Anti-corrosion Coating Based on SiO₂ with Coral Cluster Morphology. Journal of Chinese Society for Corrosion and protection, 2023, 43(6): 1319-1328.

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Abstract

The work aims to improve the stability and mechanical wear resistance of the lubricating layer of the slippery coating, which are the key problems to be solved for long-term service of the coating. The SiO₂ with coral cluster morphology was prepared by water-oil two-phase method, and then porous micro-nanostructures were constructed by mixing SiO₂ with acrylic polyurethane resin and spraying. Meanwhile the influence of substrate morphology with different SiO₂ content on the storage capacity of dimethyl silicone oil of the coating surface was studied. The mechanical abrasion resistance, self-cleaning and anti-corrosion properties of the slippery coatings were also assessed. The results showed that with the increased of SiO₂ content, the roughness of the substrate increased, and the disordered substrate morphology was more uniform, which was more conducive to improving the stability of the silicon oil layer. The sliding angle of SiO₂-25 was 5.4°. And the SiO₂-25 even had excellent lyophobicity and self-cleaning property after wear test. Due to the influence of fillers on the pore structure of the coating, the |Z|_{0.01 Hz} of SiO₂-25 was still as high as 6.62×10⁹ Ω·cm² after 20 d of immersion in 3.5%NaCl solution, higher than SiO₂-30. Among others, the coating of SiO₂-25 has the best corrosion resistance for carbon steel for the long-term.

Key words: slippery coating SiO₂ mechanical abrasion resistance anti-corrosion Q235

Received: 15 December 2022 32134.14.1005.4537.2022.398

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52071335);National Natural Science Foundation of China(2462020YXZZ016);Funding of China University of Petroleum (Beijing)(2462015YQ0602)

Corresponding Authors: QIU Ping, E-mail: qiuping@cup.edu.cn

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	ZHANG Kaili
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https://www.jcscp.org/EN/10.11902/1005.4537.2022.398 OR https://www.jcscp.org/EN/Y2023/V43/I6/1319

Fig.1 Flow chart for preparation of super-lubricative coating

Fig.2 SEM morphologies of porous coral clustered SiO₂ (a) and intermediate coatings containing 20% (b), 25% (c) and 30% (d) SiO₂, the insets show static contact angles of simethicone drop

Fig.3 Laser scanning images and 3D surface structures of intermediate coatings containing 20% (a, d), 25% (b, e) and 30% (c, f) SiO₂

Fig.4 Optical images and static contact angles of SiO₂-20 (a), SiO₂-25 (b), and SiO₂-30 (c) super-lubricative coatings

Table 1 Static contact angles and sliding angles of the coatings before and after silicone oil injection

Fig.5 Comparison of the mass losses of three super-lubricative coatings after abrasion for different cycles

Table 2 Mass loss increments of three super-lubricative coatings after abrasion for different cycles

Fig.6 Comparison of the static contact angles (a) and sliding angles (b) of three super-lubricative coatings after abrasion for different cycles

Fig.7 Sliding tests of bentonite solution (a) and soil solution (b) on three super-lubricative coatings

Fig.8 Sliding process of coffee drops on three super-lubricative coatings before (a) and after (b) abrasion for 40 cycles

Fig.9 Bode plots of SiO₂-20 (a), SiO₂-25 (b), and SiO₂-30 (c) super-lubricative coatings and comparison diagram of |Z|_{0.01 Hz} values (d)

Fig.10 Bode plots of SiO₂-25 intermediate coating and its super-lubricative coating after immersion in 3.5%NaCl solution for 0 d (a) and 20 d (b)

Fig.11 Corrosion morphologies of three super-lubricative coatings after salt spray test: (a) SiO₂-20, (b) SiO₂-25, (c) SiO₂-30

Table 3 Comparison of corrosion resistance of different kinds of slippery/superhydrophobic coatings

1	Wong T S, Kang S H, Tang S K Y, et al. Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity [J]. Nature, 2011, 477: 443 doi: 10.1038/nature10447
2	Liu M M, Hou Y Y, Li J, et al. Transparent slippery liquid-infused nanoparticulate coatings [J]. Chem. Eng. J., 2018, 337: 462 doi: 10.1016/j.cej.2017.12.118
3	Zhang H, Wang P, Zhang D. Designing a transparent organogel layer with self-repairing property for the inhibition of marine biofouling [J]. Colloids Surf., 2018, 538A: 140
4	Tuo Y J, Zhang H F, Chen W P, et al. Corrosion protection application of slippery liquid-infused porous surface based on aluminum foil [J]. Appl. Surf. Sci., 2017, 423: 365 doi: 10.1016/j.apsusc.2017.06.170
5	Liu X L, Chen H W, Zhao Z H, et al. Slippery liquid-infused porous electric heating coating for anti-icing and de-icing applications [J]. Surf. Coat. Technol., 2019, 374: 889 doi: 10.1016/j.surfcoat.2019.06.077
6	Manna U, Raman N, Welsh M A, et al. Slippery liquid-infused porous surfaces that prevent microbial surface fouling and kill non-adherent pathogens in surrounding media: a controlled release approach [J]. Adv. Funct. Mater., 2016, 26: 3599 doi: 10.1002/adfm.201505522 pmid: 28713229
7	Gulfam R, Orejon D, Choi C H, et al. Phase-change slippery liquid-infused porous surfaces with thermo-responsive wetting and shedding states [J]. ACS Appl. Mater. Interfaces, 2020, 12: 34306 doi: 10.1021/acsami.0c06441
8	Xiang T F, Zheng S L, Zhang M, et al. Bioinspired slippery zinc phosphate coating for sustainable corrosion protection [J]. ACS Sustainable Chem. Eng., 2018, 6: 10960 doi: 10.1021/acssuschemeng.8b02345
9	Han X M, Dou W W, Chen S G, et al. Stable slippery coating with structure of tubes and pyramids for inhibition of corrosion induced by microbes and seawater [J]. Surf. Coat. Technol., 2020, 388: 125596 doi: 10.1016/j.surfcoat.2020.125596
10	Vogel N, Belisle R A, Hatton B, et al. Transparency and damage tolerance of patternable omniphobic lubricated surfaces based on inverse colloidal monolayers [J]. Nat. Commun., 2013, 4: 2176 doi: 10.1038/ncomms3176
11	Kim P, Kreder M J, Alvarenga J, et al. Hierarchical or not? Effect of the length scale and hierarchy of the surface roughness on omniphobicity of lubricant-infused substrates [J]. Nano Lett., 2013, 13: 1793 doi: 10.1021/nl4003969 pmid: 23464578
12	Cao J Y, Zhnag H Y, Yang W J, et al. Preparation and properties of KCC-1/PVDF superhydrophobic and ultra-slip surfaces [J]. Surf. Technol., 2020, 49(6): 152
	曹京宜, 张海永, 杨文静等. KCC-1/PVDF超疏水与超滑表面的制备及其性能研究 [J]. 表面技术, 2020, 49(6): 152
13	Zhang M L, Yu J, Chen R R, et al. Highly transparent and robust slippery lubricant-infused porous surfaces with anti-icing and anti-fouling performances [J]. J. Alloy. Compd., 2019, 803: 51 doi: 10.1016/j.jallcom.2019.06.241
14	Zhang F M, Zeng Z X, Wang G, et al. Fabrication and anti-corrosion performance of superhydrophobic surface film on Q235 steel substrate [J]. J. Chin. Soc. Corros. Prot., 2016, 36: 617
	张方铭, 曾志翔, 王刚等. Q235钢超疏水表面制备及耐蚀性能研究 [J]. 中国腐蚀与防护学报, 2016, 36: 617 doi: 10.11902/1005.4537.2016.182
15	Qiu Z H, Qiu R, Xiao Y M, et al. Slippery liquid-infused porous surface fabricated on CuZn: a barrier to abiotic seawater corrosion and microbiologically induced corrosion [J]. Appl. Surf. Sci., 2018, 457: 468 doi: 10.1016/j.apsusc.2018.06.139
16	Song F, Wu C Q, Chen H L, et al. Water-repellent and corrosion-resistance properties of superhydrophobic and lubricant-infused super slippery surfaces [J]. RSC Adv., 2017, 7: 44239 doi: 10.1039/C7RA04816E
17	Nie X H, Du C W, Li X G. Influence of temperature on the corrosion behavior and mechanism of Q235 steel in Dagang soil [J]. J. Univ. Sci. Technol. Beijing, 2009, 31: 48
	聂向晖, 杜翠薇, 李晓刚. 温度对Q235钢在大港土中腐蚀行为和机理的影响 [J]. 北京科技大学学报, 2009, 31: 48
18	Chen T C, Xiang J H, Jiang L F, et al. High-temperature corrosion behavior of Q235 steel in oxidizing atmosphere containing chlorine [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 560
	陈土春, 向军淮, 江龙发等. Q235钢在氧化性含Cl气氛中的高温腐蚀行为 [J]. 中国腐蚀与防护学报, 2021, 41: 560 doi: 10.11902/1005.4537.2020.129
19	Ouyang Y B, Cao Q, Li B Z, et al. Nanofluid-infused slippery surface: bioinspired coating on Zn with high corrosion inhibition performance [J]. Colloids Surf., 2021, 608A: 125492
20	Xie J, Hu J, Lin X D, et al. Robust and anti-corrosive PDMS/SiO₂ superhydrophobic coatings fabricated on magnesium alloys with different-sized SiO₂ nanoparticles [J]. Appl. Surf. Sci., 2018, 457: 870 doi: 10.1016/j.apsusc.2018.06.250
21	Deng R, Shen T, Chen H L, et al. Slippery liquid-infused porous surfaces (SLIPSs): a perfect solution to both marine fouling and corrosion? [J]. J. Mater. Chem., 2020, 8A: 7536
22	Xing K, Li Z X, Wang Z R, et al. Slippery coatings with mechanical robustness and self-replenishing properties as potential application on magnesium alloys [J]. Chem. Eng. J., 2021, 418: 129079 doi: 10.1016/j.cej.2021.129079
23	Zhao S R, Shen T, Li Y T, et al. Epoxy-resin-based slippery liquid infused anti-icing coating based on breath figure [J]. Acta Polym. Sin., 2021, 52: 1622
	赵书瑞, 申婷, 李玉堂等. 基于呼吸图法的环氧树脂基超滑液体灌注防冰涂层 [J]. 高分子学报, 2021, 52: 1622
24	Yao W H, Chen Y H, Wu L, et al. Preparation of slippery liquid-infused porous surface based on MgAlLa-layered double hydroxide for effective corrosion protection on AZ31 Mg alloy [J]. J. Taiwan Inst. Chem. Eng., 2022, 131: 104176 doi: 10.1016/j.jtice.2021.104176
25	Yang P G, Zheng Y, Peng R C, et al. Fabrication and corrosion resistance of superhydrophobic PDMS-SiO₂/PANI coating on A3 steel [J]. Mater. Prot., 2018, 51(5): 12
	杨品高, 郑玉, 彭瑞超等. A3碳钢表面PDMS-SiO₂/PANI超疏水膜的制备及其防腐蚀性能 [J]. 材料保护, 2018, 51(5): 12
26	Tong W, Xiong D S, Zhou H J. TMES-modified SiO₂ matrix non-fluorinated superhydrophobic coating for long-term corrosion resistance of aluminium alloy [J]. Ceram. Int., 2020, 46: 1211 doi: 10.1016/j.ceramint.2019.08.251

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