Research Progress on Carbon Dots in Field of Metal Corrosion and Protection

doi:10.11902/1005.4537.2022.351

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (6): 1237-1246 DOI: 10.11902/1005.4537.2022.351

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Research Progress on Carbon Dots in Field of Metal Corrosion and Protection

FAN Yufang¹^,²^,³, ZHANG Yafei⁴, YIN Liusen¹^,²^,³, ZHAO Conghui¹^,²^,³, HE Yanbin¹^,²^,³, ZHANG Chuanxiang¹^,²^,³(

)

^1.School of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454003, China
^2.Henan Key Laboratory of Coal Green Conversion, Jiaozuo 454000, China
^3.Collaborative Innovation Center of Coal Safety Production and Clean and Efficient Utilization Jointly Built by the Ministry and the Province, Jiaozuo 454000, China
^4.Ningbo Lvdong Fuel Cell Co., Ltd., Ningbo 315300, China

Cite this article:

FAN Yufang, ZHANG Yafei, YIN Liusen, ZHAO Conghui, HE Yanbin, ZHANG Chuanxiang. Research Progress on Carbon Dots in Field of Metal Corrosion and Protection. Journal of Chinese Society for Corrosion and protection, 2023, 43(6): 1237-1246.

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Abstract

How to avoid metal corrosion has became a key issure due to the widespread applications of various metals, therefore, it is urgent to develop the low toxicity and high-efficiency anticorrosive materials. Carbon dots (CDs), as a new zero-dimensional member of the carbon family, possesses the advantages of strong adsorption capacity, low toxicity, high solubility, good stability, and abundant surface functional groups, attract extensive attentions of researchers in the field of corrosion and protection of metallic materials. Herein, this work systematically elaborates the research progress of carbon dots especially as water-phase corrosion inhibitors and coating fillers. This review introduces corrosion inhibition effect about different heteroatom-doped carbon dots (nitrogen doped carbon dots, cerium and nitrogen co-doped carbon dots and nitrogen and sulfur co-doped carbon dots) on various metals. The corresponding corrosion inhibition mechanism can be summarized as that the protective film is formed through adsorption of CDs (physical adsorption or chemical adsorption) on surface of metals. Furthermore, we summarize the anti-corrosion mechanisms and research achievements of carbon dots as solvent-based and water-based coating fillers. By virtue of its small size and plentiful of functional groups, CDs can fill into micropores and fix the defects of coating so that to improve the comprehensive anti-corrosion performances of the composite coating. Finally, the challenges that carbon dots face in the field of corrosion and protection are also discussed.

Key words: carbon dots inhibitors filler for coating anticorrosion

Received: 14 November 2022 32134.14.1005.4537.2022.351

ZTFLH:

TG174.4

Fund: National Natural Science Foundation of China(52074109)

Corresponding Authors: ZHANG Chuanxiang, E-mail: zcx223@163.com

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	FAN Yufang
	ZHANG Yafei
	YIN Liusen
	ZHAO Conghui
	HE Yanbin
	ZHANG Chuanxiang

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.351 OR https://www.jcscp.org/EN/Y2023/V43/I6/1237

Fig.1 Corrosion inhibition mechanism of N-CDs on carbon steel^[56]

Fig.2 Morphologies of N-CDs1 (a), N-CDs2 (b),N-CDs3 (c) and schematic illustration of inhibition mechanism of N-CDs2 (d)^[58]

Fig.3 Corrosion inhibition mechanism of N-CDs on Cu^[69]

Fig.4 Corrosion inhibition experiment of Ce@N-CDs on carbon steel: (a) schematic representation of the protective mechanism, (b) Langmuir adsorption plot, (c) Tafel curves^[61]

Table 1 Corrosion inhibition efficiency of CDs

Fig.5 Corrosion inhibition mechanism of N,S-CDs on carbon steel (a) and Cu (b)^[83,85]

Fig.6 Corrosion inhibition mechanism of N,S-CDs on Al (a) and Mg (b)^{[48, 87]}

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