Corrosion Resistance of Boride Cladding Layer on Surface of 304 Stainless Steel

doi:10.11902/1005.4537.2020.163

Journal of Chinese Society for Corrosion and protection

2021, Vol. 41

Issue (6): 843-848 DOI: 10.11902/1005.4537.2020.163

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Corrosion Resistance of Boride Cladding Layer on Surface of 304 Stainless Steel

ZHENG Shien¹, PAN Yingjun¹(

), ZHANG Heng², KE Deqing¹, YANG Ling¹, ZHU Xingyu¹

^1.College of Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
^2.Wuhan Chunhe Technology Co, Ltd. , Wuhan 430223, China

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Abstract

A ternary boride cermet coating was prepared on 304 stainless steel by plasma cladding technique. The microstructure and phase composition of the cladding layer were characterized by optical microscope, scanning electron microscope and X-ray diffraction. The hardness distribution of the cladding layer was measured with a micro-hardness tester, and the corrosion resistance of the cladding layer was also studied. The results showed that the boride cladding layer forms a good metallurgical bond with the 304 stainless steel, and no defects such as macro cracks and holes were found at the interface. The average microhardness of the cladding layer was 630.4 HV_0.5, which was three times higher than 304 stainless steel (HV_0.5≤200), effectively improving the surface hardness of 304 stainless steel. After immersion test in 10%HNO₃+3%HF acidic solution for 48 h, the maximum corrosion depth ratio of the bare 304 stainless steel and the cladding layer is 77 and 9 μm respectively, so the corrosion resistance of the cladding layer is better than that of 304 stainless steel.

Key words: 304 stainless steel plasma cladding boride coating corrosion resistance hardness

Received: 16 September 2020

ZTFLH:

TG174

Fund: Youth Fund of State Key Laboratory of Refractory and Metallurgy, Wuhan University of Science and Technolog(2018QN04);Open Fund of Iron and Steel Metallurgy and Resource Utilization Department Co-construction of the Ministry of Education Key Laboratory, Wuhan Universityof Science and Technology(FMRUlab17-7)

Corresponding Authors: PAN Yingjun E-mail: hbwhpyj@163.com

About author: PAN Yingjun, E-mail: hbwhpyj@163.com

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Cite this article:

ZHENG Shien, PAN Yingjun, ZHANG Heng, KE Deqing, YANG Ling, ZHU Xingyu. Corrosion Resistance of Boride Cladding Layer on Surface of 304 Stainless Steel. Journal of Chinese Society for Corrosion and protection, 2021, 41(6): 843-848.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2020.163 OR https://www.jcscp.org/EN/Y2021/V41/I6/843

Fig.1 Metallographic structure of boride cladding layer on 304 stainless steel surface

Fig.2 XRD pattern of cladding surface of 304 stainless steel

Fig.3 Hardness curves of annealed cladding at different temperatures

Fig.4 Corrosion morphologies of 304 stainless steel (a, b) and clading layer (c, d) mixed with acid after soaking for 48 h

Fig.5 Interface morphology of cladding layer/304 stainless steel and element line scan

Fig.6 Microstructure of cladding layer

Table 1 EDS analysis of each point in Fig.6

Fig.7 Polarization curves of cladding layer and 304 stainless steel under acidic conditions (a) and neutral conditions (b)

Table 2 Polarization curve fitting results of 304 stainless steel and boride cladding layer

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