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MONITORING INITIAL PITTING CORROSION OF 45 STEEL IN NaHCO3-NaCl SOLUTION BY ESPI |
WANG Meifeng1;2; DU Nan2; LI Xiaogang1; ZHAO Qing2; LIU Gang2 |
1. Corrosion and Protection Center; University of Science and Technology Beijing; Beijing 100083
2. Key Laboratory of Nondestructive Testing (Nanchang Hangkong University); Ministry of Education; Nanchang 330063 |
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Abstract ESPI were firstly used to monitor the real-time, in-situ corrosion behavior of 45 steel in 0.5 mol/L NaHCO3+0.05 mol/L NaCl solution during anodic polarization. By comparison between the ESPI image and the digital photo of the sample surface; it was found that at the same position where a speckle appeared, a pit appeared after the polarization experiment. It can be concluded that the bright speckles in the ESPI images were caused by the pitting corrosion products. Accordingly, the size, position and time of initial pitting corrosion could be deduced. The pitting potential (Eb) of 45 steel determined by the method under the condition is -0.15 V;\linebreak meanwhile, the polarization current is 12.2 μA. Information of the pitting growth could be obtained by changes of the speckles in ESPI results.
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Fund: 江西省自然科学基金项目(CA200700132),江西省教育厅项目(DB200801230) |
Corresponding Authors:
LI Xiaogang
E-mail: lixiaogang99@263.net
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