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EFFECT OF Cr PARTICLE SIZE ON THE OXIDATION BEHAVIOUR OF ELECTRODEPOSITED Ni-Cr COMPOSITE COATINGS |
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Abstract Ni-7.5Cr,、Ni-10.9Cr、Ni-12.4Cr composites were prepared by means of co-electrodeposition of Ni matrix with three kinds of Cr particles in average size of 21 nm,39 nm, and 2.4µm, respectively. Compared to the electrodeposited microparticles-dispered composite coating (EMCC), the electrodeposited nanoparticles-dispered nanocomposite coatings (ENNCs) exhibits more homogeneous distribution of Cr particles and the interparticle spacing is approximately two orders of magnitude lower. The ENNCs have a very low oxidation rate at 900℃, due to the rapid formation of a continuous and compact chromia scale, whereas the EMCC exhibits a very poor oxidation resistance, due to the formation of porous NiO scale. For the ENNCs, the finer the Cr particles codeposited, the better the oxidation performance. The particles size effect on the oxidation behaviour of electrodeposited Ni-Cr composites is also discussed.
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Received: 16 March 2005
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[1]Atkinson H V.A review of the role of short-circuit diffusion inthe oxidation of nickel,chromium and nickel-chromium alloys[J].Oxid.Met.,1985,24:177-197 [2]Goward G W.Overview protective coatings-purpose role and de-sign[J].Mater.Sci.Technol.,1986,2:194-199 [3]Peng X,Ping D,Li T,et al.Oxidation behaviour of a Ni-La2O3codeposited film on nickel[J].J.Electrochem.Soc.,1998,145:389-398 [4]Goward G W,Boone D H.Mechansims of formation of diffusionaluminide coatings on nickel-base superalloys[J].Oxid.Met.,1971,3:475-481 [5]Nicholls J R,Hancocl P,Al-Yasiri L H.Optimising oxidation re-sistance of MCrAl coating systems using vapour phase alloy design[J].Mater.Sci.Technol.,1989,5:799-808 [6]Wang F,Lou H.Oxidation behaviour and scale morphology of nor-mal-grained CoCrAl alloy and its sputtered microcrystalline coat-ing[J].Mater.Sci.Eng.,1990,A129:279-285 [7]Lou H,Zhu S,Wang F,et al.Rehealing ability of oxide scaleformed on microcrystalline K38G coating[J].Oxid.Met.,1995,43:317-329 [8]Zhang Y,Peng X,Wang F.Development and oxidation at 800℃ofa novel electrodeposited Ni-Cr nanocomposite film[J].Mater.Lett.,2004,58:1134-1138 [9]Zhou Y,Peng X,Wang F.Oxidation of a novel electrodeposited Ni-Al nanocomposite film at 1050℃[J].Scr.Mater.,2004,50:1429-1423 |
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