High-temperature Oxidation Behavior and Wear Resistance of Copper-based Composites with Reinforcers of C, ZrSiO4 and Fe

doi:10.11902/1005.4537.2019.227

Journal of Chinese Society for Corrosion and protection

2020, Vol. 40

Issue (2): 191-198 DOI: 10.11902/1005.4537.2019.227

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High-temperature Oxidation Behavior and Wear Resistance of Copper-based Composites with Reinforcers of C, ZrSiO₄ and Fe

ZHENG Yanxin¹, LIU Ying¹, SONG Qingsong¹, ZHENG Feng¹, JIA Yuchuan², HAN Peide¹(

)

1 College of Materials Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China
2 Luoyang Pengfei Abrasion Resistant Material Company Limited, Luoyang 471200, China

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Abstract

Composites of Cu matrix with reinforcers of graphite, ZrSiO₄ and Fe were prepared via powder metallurgy, then their high temperature oxidation behavior and wear performance were assessed in air at 25, 250, 350 and 450 ℃. The results show that the size and distribution of Fe particles in Cu-matrix affect the oxidation resistance and wear resistance of Cu-based friction materials. With the increasing temperature, the formed oxidation product of Cu on the surface of copper-based friction materials is Cu₂O, but that of Fe changed from Fe₂O₃ to Fe₃O₄, and the thickness of oxide scale increased gradually. When Fe particles of small size distribute uniformly in the Cu-matrix, it is more conducive to improving the overall oxidation resistance of the Cu-matrix, in the range of 350~450 ℃, the formation of stable oxide scale was beneficial to reduce the adhesive wear, demonstrating better high-temperature wear resistance. However, when the Fe particles in the Cu-matrix were of large size, the phenomenon of heterogeneous oxidation can be observed, which is not conducive to improving the high-temperature wear resistance.

Key words: Cu-based friction material Fe high-temperature oxidation high-temperature wear resistance

Received: 26 April 2019

ZTFLH:

TF124

Fund: National Natural Science Foundation of China(U1860204);National Natural Science Foundation of China(51871159);Henan Province Science and Technology Cooperation Project(182106000014)

Corresponding Authors: HAN Peide E-mail: hanpeide@126.com

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	Yanxin ZHENG
	Ying LIU
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	Yuchuan JIA
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Cite this article:

ZHENG Yanxin, LIU Ying, SONG Qingsong, ZHENG Feng, JIA Yuchuan, HAN Peide. High-temperature Oxidation Behavior and Wear Resistance of Copper-based Composites with Reinforcers of C, ZrSiO₄ and Fe. Journal of Chinese Society for Corrosion and protection, 2020, 40(2): 191-198.

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https://www.jcscp.org/EN/10.11902/1005.4537.2019.227 OR https://www.jcscp.org/EN/Y2020/V40/I2/191

Table 1 Components of copper-based friction materials

Fig.1 Optical microstructures of sample 1 (a), sample 2 (b), and corresponding EDS results of points 1 (c), 2 (d), 3 (e) and 4 (f) in Fig.1a

Fig.2 Microstructures of unworn surfaces of sample 1 (a1~d1) and sample 2 (a2~d2) at 25 ℃ (a1, a2), 250 ℃ (b1, b2), 350 ℃ (c1, c2) and 450 ℃ (d1, d2)

Fig.3 SEM images and EDS mapping analysis of sample 1 at 250 ℃ (a), 350 ℃ (b) and sample 2 at 350 ℃ (c)

Fig.4 XRD pattern of surfaces of samples before and after high temperatures friction

Fig.5 Schematic diagram of oxidation at high temperature of sample 1 and sample 2

Fig.6 Friction coefficient (a) and wear rate (b) of samples at different temperatures

Fig.7 Worn surfaces of sample 1 (a1~d1) and sample 2 (a2~d2) at 25 ℃ (a1, a2), 250 ℃ (b1, b2), 350 ℃ (c1, c2) and 450 ℃ (d1, d2)

Fig.8 Three-dimensional worn surfaces of sample 1 (a1~d1) and sample 2 (a2~d2) at 25 ℃ (a1, a2), 250 ℃ (b1, b2), 350 ℃ (c1, c2) and 450 ℃ (d1, d2)

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