OXIDATION OF TWO Fe-Nb ALLOYS UNDER LOW OXYGEN PRESSURES AT 600~800℃

J Chin Soc Corr Pro

1996, Vol. 16

Issue (2): 107-114 DOI:

Current Issue | Archive | Adv Search

OXIDATION OF TWO Fe-Nb ALLOYS UNDER LOW OXYGEN PRESSURES AT 600~800℃

Download:

PDF(2701KB)
Export: BibTeX | EndNote (RIS)

Abstract The oxidation of two Fe-Nb alloys containing 15 and 30 wt% Nb respectively was studied at 600~800℃finder low oxygen pressures, similar to the environments prevailing in coal gasification. The main reaction was internal oxidation of niobium with the formation of niobium oxides (NbO2 and Nb2O5) and in some cases of a double Fe-Nb oxide. The kinetics of this reaction was very slow at 600℃ but rather fast at 700and 800℃. A peculiar feature of the internal oxidation of these alloys was that the distribution of the internal oxides was the same as that of the Nb-rich phase in the original two-phase alloys. This behavior and the lack of formation of external scales of niobium oxides were mainly the result of the limited solubility of niobium in iron and of the consequent. presence of two phases in the alloys under examination.

Key words: Fe-Nb alloys High temperature Oxidation Low oxygen pressure

Received: 25 April 1996

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors

Cite this article:

Niu Yan;Rebelo M C;Gesmundo F; Rizzo F C(State Key Laboratory of Corrosion and Protection; Institute of Corrosion and Protection of Metals;Chinese Academy of Sciences; Shengyang 110015 )(Depertamento de Ciencia dos Materiais e Metolurgia; Poritificia Univ. OXIDATION OF TWO Fe-Nb ALLOYS UNDER LOW OXYGEN PRESSURES AT 600~800℃. J Chin Soc Corr Pro, 1996, 16(2): 107-114.

URL:

https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y1996/V16/I2/107

1NiuY,GesmundoF,VianiF．Corros．Sci．,1994,36:8832NiuY,GesmundoF,VianiFCorros、Sci．,1994,36:18853WangG,CarterR,DouglassDL．Oxid．Met．,1989,32:2734KaiW,DouglassDL,GesmundoFOxid．Met．,1992,37:1895BinaryAlloyPhaseDiagrams,MassalskiTB,MurryJL,BennettLH,BakerH．Eds．ASM,MaterialsPark,19866GesmundoF,NiuY,VianiF,RizzoF,tobepublished7LupisCHP．ChemicalThermodynamicofMaterials,NewYorkNorthholland1983,Ch．WII8RothRS,DennisJR,McMurdieHF．PhaseDiagramsforCeranusts,TheAmericanCeramicSociety．Westerville,1987,Vo．VI9KubaschewskiO．HighTemp．-HighPress,1972,4:110GesmundoF,VianiF;NiuY．Oxid．Met．,1994,42(5//6):40911GesmundoF,NiuY,VianiFOxidMet．,acceptedforPublic．12RappRACorrosion,1965,21:38213MontelroMJ,NiuY,fuzzoF,GesmundoF．tobepublished14MrowecS．GasCorroslonofMetals,Warsaw:NationalBureauofStandards,197815BredesenR,KofstadP．OxidMet,1990,34:361;1991,35:107;1991,36:27

[1]	REN Yan, QIAN Yuhai, ZHANG Xintao, XU Jingjun, ZUO Jun, LI Meishuan. Effect of Thermal Shock on Mechanical Properties of Siliconized Graphite with ZrB₂-SiC-La₂O₃/SiC Coating[J]. 中国腐蚀与防护学报, 2021, 41(1): 29-35.
[2]	WEI Zheng, MA Baoji, LI Long, LIU Xiaofeng, LI Hui. Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 117-124.
[3]	WANG Lei, DONG Junhua, HAN Da, LIANG Jiankun, LI Quan, KE Wei. Phenonmenon of Cu Segregation in Cu-containing steel During Soaking at 1150 ℃[J]. 中国腐蚀与防护学报, 2020, 40(6): 545-552.
[4]	LIU Xiao, WANG Hai, ZHU Zhongliang, LI Ruitao, CHEN Zhenyu, FANG Xudong, XU Fanghong, ZHANG Naiqiang. Oxidation Characteristics of Austenitic Heat-resistant Steel HR3C and Sanicro25 in Supercritical Water for Power Station[J]. 中国腐蚀与防护学报, 2020, 40(6): 529-538.
[5]	XIE Dongbai, HONG Hao, WANG Wen, PENG Xiao, DUO Shuwang. Oxidation Behavior of Stainless Steel 1Cr11Ni2W2MoV in a Simulated Kerosene Combustion Environment[J]. 中国腐蚀与防护学报, 2020, 40(4): 358-366.
[6]	WANG Haiwei, CHANG Sen, LUAN Xin'gang, SONG Xuemei, WANG Zhen, LI Yanzhang, CHEN Jianli, ZHANG Jirong, HAN Ming, QIU Dangui. Preparation and Properties of Ceramics Composed of Nano-Al₂O₃ and Polysiloxane-polyborosilicate-TiB₂ Modified Polysilborazane as High Temperature Adhesive for SiC Based Ceramics[J]. 中国腐蚀与防护学报, 2020, 40(4): 367-372.
[7]	CAO Jingyi, FANG Zhigang, CHEN Jinhui, CHEN Zhixiong, YIN Wenchang, YANG Yange, ZHANG Wei. Preparation and Properties of Micro-arc Oxide Film with Single Dense Layer on Surface of 5083 Aluminum Alloy[J]. 中国腐蚀与防护学报, 2020, 40(3): 251-258.
[8]	ZHANG Zhen, WU Xinqiang, TAN Jibo. *Review of Electrochemical Noise Technique for in situ* Monitoring of Stress Corrosion Cracking**[J]. 中国腐蚀与防护学报, 2020, 40(3): 223-229.
[9]	FANG Xudong, LIU Xiao, XU Fanghong, LI Ruitao, ZHU Zhongliang, ZHANG Naiqiang. Oxidation Behavior in Supercritical Water of Domestic Austenitic Steel C-HRA-5 for Uultra-supercritical Power Stations[J]. 中国腐蚀与防护学报, 2020, 40(3): 266-272.
[10]	ZHENG Yanxin, LIU Ying, SONG Qingsong, ZHENG Feng, JIA Yuchuan, HAN Peide. High-temperature Oxidation Behavior and Wear Resistance of Copper-based Composites with Reinforcers of C, ZrSiO₄ and Fe[J]. 中国腐蚀与防护学报, 2020, 40(2): 191-198.
[11]	XU Xunhu,HE Cuiqun,XIANG Junhuai,WANG Ling,ZHANG Honghua,ZHENG Xiaodong. High Temperature Oxidation Behavior of Co-20Re-25Cr-1Si Alloy in 0.1 MPa Pure Oxygen[J]. 中国腐蚀与防护学报, 2020, 40(1): 75-80.
[12]	JIANG Dongxue,FU Ying,ZHANG Junwei,ZHANG Wei,XIN Li,ZHU Shenglong,WANG Fuhui. Preparation and Properties of Alumina Ceramic Film on Ti-alloy Surface[J]. 中国腐蚀与防护学报, 2019, 39(6): 469-476.
[13]	XIAO Jintao,CHEN Yan,XING Mingxiu,JU Pengfei,MENG Yingen,WANG Fang. Effect of Process Parameters on Corrosion Resistance of Anodizing Film on 2195 Al-Li Alloy[J]. 中国腐蚀与防护学报, 2019, 39(5): 431-438.
[14]	AI Peng,LIU Lixiang,LI Xiaogang,JIANG Wentao. Influence of TiAlSiN Coatings on High Temperature Oxidation Resistance of γ-TiAl Based Alloys[J]. 中国腐蚀与防护学报, 2019, 39(4): 306-312.
[15]	Yunhai MA. Effect of Shot Peening on Oxidation Resistance of Super 304H Steel in Supercritical Steam[J]. 中国腐蚀与防护学报, 2019, 39(3): 245-252.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed