Corrosion Inhibition of Navel Orange Peel Extract to Stainless Steel in Acidic Medium

doi:10.11902/1005.4537.2022.214

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (3): 619-629 DOI: 10.11902/1005.4537.2022.214

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Corrosion Inhibition of Navel Orange Peel Extract to Stainless Steel in Acidic Medium

ZHOU Kun¹, LIU Xinhua²(

), LIU Shuai²

^1.Hebei Chemical & Pharmaceutical College, Shijiazhuang 050026, China
^2.Department of Chemistry, Tangshan Normal University, Tangshan 063000, China

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Abstract

To promote the rapid development of green plant extract inhibitor, navel orange peel extract (NOPE) was obtained by a simple ethanol-acetone reflux method, which then was assessed as inhibitor for 316L steel in hydrochloric acid medium. The main components of navel orange peel extract (NOPE) and its stability in hydrochloric acid were confirmed by infrared spectroscopy (FTIR) and ultraviolet spectroscopy (UV). The corrosion inhibition performance of NOPE to 316L steel in 0.5 mol/L HCl solution was investigated using mass loss method, dynamic potential polarization method (PDP), linear polarization method (LPR) and electrochemical impedance spectroscopy (EIS). Their adsorption properties were calculated with items of $Δ G a d s 0$ , $Δ H a d s 0$ and $Δ S a d s 0$ . The results show that with the increase of the concentration of NOPE, the steel corrosion rate is reduced, the anode current is reduced and the active corrosion site is blocked, so the inhibition efficiency is improved. When the concentration of NOPE was 0.5 g/L, the maximum corrosion inhibition efficiency was 90.5% (masslessness method) and 87.3% (electrochemical method) respectively. Compared with the blank system, the thermodynamic activation parameter (activation energy) E_a significantly increased in the system with NOPE, and the difference of (E_a- $Δ H a 0$ ) was about equal to the average value of RT (2.64 kJ/mol). Therefore, it can be inferred that the corrosion process was a single molecule reaction. The adsorption process on the steel surface was fitted by Langmuir isotherm, which further proved that the adsorption was monolayer adsorption. The better corrosion inhibition performance of NOPE for L316 steel in 0.5 mol/L HCl solution system can also be proved by the observation and detection with scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). In sum, the NOPE is a green inhibitor with a good application prospect in the field of pickling and can provide certain guidance for the development of plant extract inhibitor.

Key words: navel orange peel extract corrosion inhibitor polarization impedance surface analysis

Received: 29 June 2022 32134.14.1005.4537.2022.214

ZTFLH:

TG174

Fund: Natural Science Foundation of Hebei Province(D2022105004);Fund of Tangshan Normal University(2022C42)

Corresponding Authors: LIU Xinhua, E-mail: hualiyiwang@163.com

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Cite this article:

ZHOU Kun, LIU Xinhua, LIU Shuai. Corrosion Inhibition of Navel Orange Peel Extract to Stainless Steel in Acidic Medium. Journal of Chinese Society for Corrosion and protection, 2023, 43(3): 619-629.

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.214 OR https://www.jcscp.org/EN/Y2023/V43/I3/619

Fig.1 FTIR diagram (a) of NOPE and UV diagram (b) of NOPE without and with hydrochloric acid medium

Fig.2 Structural formula of hesperidin (a) and flavonoid (b)

Table 1 Calculated values of V_i and ƞ_i by weight-loss method

Fig.3 Arrhenius (a) and transition-state (b) plots for dissolution reactions of 316L steel in 0.5 mol/L HCl solutions without and with NOPE

ContentC_inh / mg·h^-1	Amg·h^-1·cm^-2	E_akJ·mol^-1	ΔH $a 0$ kJ·mol^-1	ΔS $a 0$ J·mol^-1·K^-1
0	7.56×10⁶	58.30	55.66	-139.35
30	3.89×10⁸	70.18	67.54	-89.34
50	1.34×10⁹	73.79	71.15	-79.07
100	1.98×10¹⁰	81.52	78.88	-56.68
200	2.81×10¹⁰	82.75	80.11	-53.78
300	5.47×10¹¹	91.40	88.76	-29.07
500	3.32×10¹²	96.54	93.90	-14.08

Table 2 Thermodynamic activation parameters for 316L steel 0.5 mol/L HCl solutions without and with NOPE

Fig.4 Langmuir isotherm for NOPE adsorption on 316L steel in 0.5 mol/L HCl solution

T / K	K_ads / L·g^-1	R²	$Δ G a d s 0$ / kJ·mol^-1
303	35.97	0.9987	-26.43
313	25.38	0.9977	-26.39
323	18.38	0.9937	-26.37
333	14.31	0.9958	-26.49

Table 3 Thermodynamic parameters for adsorption of NOPE on 316L steel in 0.5 mol/L HCl solution at different temperatures

Fig.5 lnK_ads vs. T^-1 plot for adsorption of NOPE on 316L steel in 0.5 mol/L HCl solution

Fig.6 E_OCP-t curves of 316L steel in 0.5 mol/L HCl solutions with various concentrations of NOPE

Table 4 Potentiodynamic polarization and linear polarization data of 316L steel in 0.5 mol/L HCl solutions with different concentrations of NOPE

Fig.7 Potentiodynamic polarization curves of 316L steel in 0.5 mol/L HCl solutions with different concentrations of NOPE

Fig.8 Schematic diagram of blocking active sites of NOPE

Fig.9 Nyquist (a) and Bode (b) diagrams of 316L steel in 0.5 mol/L HCl solutions with different concen-trations of NOPE, and corresponding equivalent circuit (c)

Table 5 Fitting parameters of EIS of 316L steel in 0.5 mol/L HCl solutions with different concentrations of NOPE

Fig.10 SEM surface morphologies (a1-c1) and EDS results (a2-c2) of 316L steel: (a1, a2) New, (b1, b2) Blank, (c1, c2) NOPE

Fig.11 Proposed corrosion inhibition mechanism for 316L steel in 0.5 mol/L HCl solution containing NOPE

Table 6 Comparison of extract corrosion inhibitors for steels in HCl solution

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