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中国腐蚀与防护学报  2026, Vol. 46 Issue (2): 491-499     CSTR: 32134.14.1005.4537.2025.113      DOI: 10.11902/1005.4537.2025.113
  研究报告 本期目录 | 过刊浏览 |
(Ni, Pt)AlNiCoCrAlYTa涂层对镍基单晶高温合金DD6抗热腐蚀性能的影响
彭文雅1, 李帅2(), 李璞1, 赵春玲1, 鲍泽斌2
1.中国航发湖南动力机械研究所 株洲 412002
2.中国科学院金属研究所 师昌绪先进材料创新研究中心 沈阳 110016
Hot Corrosion Resistance of (Ni, Pt)Al- and NiCoCrAlYTa-coating Prepared on Ni-based Single Crystal Alloy DD6
PENG Wenya1, LI Shuai2(), LI Pu1, ZHAO Chunling1, BAO Zebin2
1.AECC Hunan Aviation Powerplant Research Institute, Zhuzhou 412002, China
2.Shi -Changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
引用本文:

彭文雅, 李帅, 李璞, 赵春玲, 鲍泽斌. (Ni, Pt)AlNiCoCrAlYTa涂层对镍基单晶高温合金DD6抗热腐蚀性能的影响[J]. 中国腐蚀与防护学报, 2026, 46(2): 491-499.
Wenya PENG, Shuai LI, Pu LI, Chunling ZHAO, Zebin BAO. Hot Corrosion Resistance of (Ni, Pt)Al- and NiCoCrAlYTa-coating Prepared on Ni-based Single Crystal Alloy DD6[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(2): 491-499.

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摘要: 

分别采用电镀Pt和化学气相渗铝与真空电弧镀在第二代镍基单晶高温合金DD6表面制备了(Ni, Pt)Al和NiCoCrAlYTa涂层。通过800和900 ℃涂盐热腐蚀试验评估了两种涂层的抗热腐蚀性能,并利用扫描电子显微镜、X射线衍射等手段对涂层物相及元素分布进行分析。结果表明,于800和900 ℃在混合盐膜Na2SO4 + 5% (质量分数) NaCl下经300 h腐蚀后,NiCoCrAlYTa涂层均完全失效,表面生成了防护性能较差的混合氧化膜,且发生大量剥落,腐蚀透过涂层进入基体内部;相较而言,(Ni, Pt)Al涂层经300 h腐蚀后在涂层表面生成单一Al2O3膜,且剥落区域相对较少,腐蚀仅局限在涂层内部,仍能观察到涂层内残留有尚未耗尽的NiAl相。换言之,(Ni, Pt)Al涂层表现出比NiCoCrAlYTa涂层更为优异的抗热腐蚀性能。

关键词 (Ni, Pt)Al涂层NiCoCrAlYTa涂层热腐蚀熔融盐    
Abstract

(Ni, Pt)Al- and NiCoCrAlYTa-coating were deposited on the second-generation nickel-based single crystal superalloy DD6 by electroplating Pt + chemical vapor aluminizing, and arc ion plating respectively. The hot corrosion resistance of two coatings was assessed beneath a deposited film of salts mixture Na2SO4 + 5%NaCl in air at 800 and 900 ℃. The phase constituents and element distribution of the coatings before and after test were characterized by using scanning electron microscopy and X-ray diffraction. The results show that after 300 h of hot corrosion at 800 and 900 ℃, the NiCoCrAlYTa coatings completely failed, with the formation of a mixed oxide scale with poor protective performance on the surface, and a large amount of spalling occurred, with the corrosion penetrating the coating and entering the interior of the substrate. In the contrast, a single Al2O3 scale with relatively few spallations was formed on the surface of (Ni, Pt)Al coating, while certain among of NiAl phase was still retained within the coating. In other word, the (Ni, Pt)Al coatings exhibited superior hot corrosion resistance rather than the NiCoCrAlYTa coatings.

Key wordsPt-modified aluminide coating    NiCoCrAlYTa coating    hot corrosion    molten salts
收稿日期: 2025-04-07      32134.14.1005.4537.2025.113
ZTFLH:  TG174.2  
通讯作者: 李 帅,E-mail:sli17s@imr.ac.cn,研究方向为高性能高温防护涂层
作者简介: 彭文雅,女,1990年生,硕士,高级工程师
图1  两种涂层试样制备态截面形貌
图2  两种涂层试样制备态XRD图谱
图3  两种涂层在800 ℃下Na2SO4 + 5%NaCl混合盐中的质量变化曲线
图4  两种涂层在800 ℃下Na2SO4 + 5%NaCl混合盐中热腐蚀200和300 h后的XRD谱图
图5  两种涂层在800 ℃下Na2SO4 + 5%NaCl混合盐中腐蚀不同时间后的宏观形貌演变
图6  两种涂层在800 ℃下Na2SO4 + 5%NaCl混合盐中热腐蚀300 h后的表面形貌
图7  两种涂层在800 ℃下Na2SO4 + 5%NaCl中热腐蚀300 h后的截面形貌
图8  两种涂层在900 ℃下Na2SO4 + 5%NaCl混合盐中的质量变化曲线
图9  两种涂层在900 ℃下热腐蚀200 h和300 h后的XRD图谱
图10  两种涂层在900 ℃下Na2SO4 + 5%NaCl混合盐中腐蚀不同时间后的宏观形貌演变
图11  两种涂层在900 ℃下Na2SO4 + 5%NaCl混合盐中热腐蚀300 h后的表面形貌
图12  两种涂层在900 ℃下Na2SO4 + 5%NaCl混合盐中热腐蚀300 h后的截面形貌
图13  热腐蚀过程中硫化物及氯化物形成的Gibbs自由能随温度的变化
[1] Sun R, Wang T G, Li W, et al. Hot corrosion behavior of Pt modified gradient NiCrAlY coatings [J]. Mater. Prot., 2024, 57(3): 28
[1] 孙 日, 王铁钢, 李 伟 等. Pt改性梯度NiCrAlY涂层的热腐蚀行为研究 [J]. 材料保护, 2024, 57(3): 28
[2] Zhang H, Liu X Z, Huang A H, et al. Manufacturing and research progress in metallic bond coats for thermal barrier coatings [J]. J. Chin. Soc. Corros. Prot., 2025, 45: 20
[2] 张 晗, 刘轩溱, 黄爱辉 等. 热障涂层金属粘结层制备与研究进展 [J]. 中国腐蚀与防护学报, 2025, 45: 20
[3] Yang H B, Wang Y S, Wang X, et al. Research progress of hot corrosion and protection technology of gas turbine under marine environment [J]. Surf. Technol., 2020, 49(1): 163
[3] 杨宏波, 王源升, 王 轩 等. 燃气轮机在海洋环境下的热腐蚀与防护技术研究进展 [J]. 表面技术, 2020, 49(1): 163
[4] Whittle D P, Stringer J. Improvements in high temperature oxidation resistance by additions of reactive elements or oxide dispersions [J]. Philos. Trans. Roy. Soc., 1980, 295A: 309
[5] Hou P Y, Izumi T, Gleeson B. Sulfur segregation at Al2O3/γ-Νi + γ′-Ni3Al interfaces: Effects of Pt, Cr and Hf additions [J]. Oxid. Met., 2009, 72: 109
[6] Saharkhiz R, Valefi Z, Mirjani M, et al. Comprehensive study on the effect of HVOF processing parameters and particle size on high-temperature properties of NiCoCrAlYTa coatings [J]. Surf. Coat. Technol., 2023, 473: 129951
[7] Aristu D, Berlanga-Labari C, Alberro M, et al. A comprehensive study on hot corrosion resistance of NiCoCrAlYTa and NiCrAl thermal-sprayed coatings for CSP applications [J]. J. Energy Storage, 2023, 74: 109346
[8] Xie S M, Dai M J, Lin S S, et al. Effect of bias voltage on the oxidation resistance of NiCoCrAlYTa coatings prepared by arc ion plating [J]. Corros. Sci., 2019, 147: 330
[9] Koochaki-Abkenar A, Malekan A, Bozorg M, et al. Hot corrosion and oxidation behavior of Pt-aluminide and Pt-Rh-aluminide coatings applied on nickle-base and cobalt-base substrates [J]. Met. Mater. Int., 2024, 30: 2466
[10] Zhang C Y, Li S, Bao Z B, et al. Stripping and refurbishment of (Ni, Pt)Al coating after service for different oxidation durations [J]. J. Chin. Soc. Corros. Prot., 2025, 45: 201
[10] 张彩云, 李 帅, 鲍泽斌 等. 氧化不同时间(Ni, Pt)Al涂层的退除及再涂覆行为研究 [J]. 中国腐蚀与防护学报, 2025, 45: 201
[11] Yang Y F, Ren S X, Ren P, et al. Hot corrosion and cyclic oxidation performance of a (Ni, Pt)Al2-dispersed (Ni, Pt)Al coating prepared by low-activity high-temperature aluminizing [J]. J. Alloy. Compd., 2022, 911: 164978
[12] Yang Y F. Preparation and performance investigation of Pt-modified aluminide coatings [D]. Hefei: University of Science and Technology of China, 2017
[12] 阳颖飞. Pt改性铝化物涂层的制备科学及性能研究 [D]. 合肥: 中国科学技术大学, 2017
[13] Jiang Y M, Li S, Huang D, et al. Surface corrosion behavior of β-(Ni, Pt)Al coating: α-Al2O3 decohesion-induced failure mechanism [J]. Appl. Surf. Sci., 2024, 669: 160548
[14] Yang Y F, Liu Z L, Ren P, et al. Hot corrosion behavior of Pt + Hf co-modified NiAl coating in the mixed salt of Na2SO4-NaCl at 900  ℃ [J]. Corros. Sci., 2020, 167: 108527
[15] Malacarne R, Mathieu S, Siblani M, et al. On the sulfation reaction of protective and transient oxides at 650 ℃ and its role in the low temperature hot corrosion mechanism [J]. Corros. Sci., 2023, 218: 111186
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