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中国腐蚀与防护学报  2024, Vol. 44 Issue (4): 847-862     CSTR: 32134.14.1005.4537.2023.369      DOI: 10.11902/1005.4537.2023.369
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超高速激光熔覆制备耐腐蚀涂层研究进展
杨海云1, 刘春泉1(), 熊芬1(), 陈敏纳1, 谢岳林1, 彭龙生2, 孙胜3, 刘海洲3
1.湖南工学院材料科学与工程学院 衡阳 421002
2.湖南力方轧辊有限公司(湖南省高耐磨合金材料先进制造工程技术研究中心) 衡阳 421681
3.新余华峰特钢有限公司 新余 338099
Research Progress on Preparation of Corrosion-resistant Coatings by Extreme High-speed Laser Material Deposition
YANG Haiyun1, LIU Chunquan1(), XIONG Fen1(), CHEN Minna1, XIE Yuelin1, PENG Longsheng2, SUN Sheng3, LIU Haizhou3
1. School of Materials Science and Engineering, Hunan Institute of Technology, Hengyang 421002, China
2. Hunan Lifang Roll Co., Ltd., (Hunan Advanced Manufacturing Engineering Technology Research Center of High Wear-resistant Alloy Materials), Hengyang 421681, China
3. Xin Yu Hua Feng Te Gang Co., Ltd., Xingyu 338099, China
引用本文:

杨海云, 刘春泉, 熊芬, 陈敏纳, 谢岳林, 彭龙生, 孙胜, 刘海洲. 超高速激光熔覆制备耐腐蚀涂层研究进展[J]. 中国腐蚀与防护学报, 2024, 44(4): 847-862.
Haiyun YANG, Chunquan LIU, Fen XIONG, Minna CHEN, Yuelin XIE, Longsheng PENG, Sheng SUN, Haizhou LIU. Research Progress on Preparation of Corrosion-resistant Coatings by Extreme High-speed Laser Material Deposition[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(4): 847-862.

全文: PDF(29646 KB)   HTML
摘要: 

首先总结了涂层材料元素组成对耐腐蚀性能的影响；其次，从钝化膜、显微组织、位错、低角度晶界、热腐蚀动力学等几个方面总结了其与耐腐蚀性的联系；第三，综述了EHLA与场外辅助技术结合对所制备涂层耐腐蚀性的影响；最后，总结和展望了超高速激光熔覆所制备涂层耐腐蚀性能的强化方法。
关键词 ： 超高速激光熔覆,  腐蚀行为,  涂层    
Abstract：

With the rapid advancement of industrial technology in recent years, there are higher requirements in better surface related performance, such as wear resistance, heat resistance, corrosion resistance etc. for some key industrial equipment components. Extreme high-speed laser material deposition, as an emerging surface treatment technology, it subverts the traditional metal surface treatment process, using high-energy laser as the heat source, alloy powder as the cladding material. It realizes a significant increase in cladding efficiency through the optimal coupling of powder and laser, and improves the surface properties of the workpiece by cladding coating with special properties with high efficiency and excellent surface accuracy, which also provides many advantages for the preparation of corrosion-resistant coatings. This paper firstly summarizes the influence of the chemical composition of coating materials on the corrosion resistance of coatings. Secondly, it summarizes the relation between passivation film, microstructure, dislocations, low-angle grain boundaries, and thermal corrosion kinetics. Thirdly, it reviews the effect of EHLA combined with off-site assisted technology on corrosion resistance. Lastly, it summarizes and outlooks on the enhancement methods of the corrosion resistance of the coatings prepared by ultrahigh-speed laser melting and cladding.
Key words： extreme high-speed laser material deposition    corrosion behavior    coating
收稿日期: 2023-11-21      32134.14.1005.4537.2023.369
ZTFLH:  TG178  
基金资助:湖南省科技人才托举工程(2023TJ-X10);湖南省自然科学基金(2023JJ50108);湖南省创新型省份建设专项科普专题(2023ZK4316);湖南省高耐磨合金材料先进制造工程技术研究中心创新能力提升项目(2023ZYQ030);湖南省应用特色学科材料科学与工程学科(湘教通〔2022〕351号);衡阳市“小荷”科技人才项目(衡市科协字〔2022〕68号);湖南省“机械工程”学科科技创新平台开放课题(KFKA2205);湖南工学院自科培育项目(2022HY007);国家级大学生创新创业训练计划项目(S202311528056X)
通讯作者: 刘春泉，E-mail: liuchunquan@hnit.edu.cn，研究方向为特殊钢制备新工艺研究、激光增材制造及再制造；
熊芬，E-mail: xiongfen@hnit.edu.cn，研究方向为金属基新型材料的制备工艺研究
Corresponding author: LIU Chunquan, E-mail: liuchunquan@hnit.edu.cn;
作者简介: 杨海云，男，2002年生，本科生
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链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2023.369      或      https://www.jcscp.org/CN/Y2024/V44/I4/847

图1  熔覆速率为100 m/min时涂层的显微组织与成分的STEM分析 [16]
图2  CoCrFeNiTiAlx高熵合金涂层SEM显微结构分析[29]
图3  EHLA制备的Ni/316L合金涂层不同温度热处理后进行动电位极化测试后的表面形貌 [26]
图4  不同涂层中Cr、Fe、Ni、O元素的分布 [13]
图5  不同扫描速率下EHLA涂层的循环电位动态极化图[39]
图6  各试样在75%Na2SO4 + 25%NaCl熔盐中900℃、60 h的热腐蚀动力学曲线 [28]
图7  CLA和EHLA涂层以及基材的Tafel曲线[41]
图8  100 m/min熔覆速率下涂层的HAADF-STEM 图像及上表面相应的EDS面扫，HAADF-STEM 图像和相应的钝化膜 EDS面扫，上表面形成的钝化膜的AFM形貌，钝化膜的HRTEM像，相应的FFT图和涂层的SAED图，枝晶间的钝化膜及EDS面扫，枝晶核上的钝化膜及EDS面扫描[4,16]
图9  钝化膜形成示意图 [16]
图10  不同熔覆速率下极化测试后涂层表面的腐蚀形貌[14]
图11  钝化膜成核及形成过程示意图[15]
图12  EHLA涂层的TEM图[36]
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