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中国腐蚀与防护学报  2023, Vol. 43 Issue (1): 13-21     CSTR: 32134.14.1005.4537.2022.186      DOI: 10.11902/1005.4537.2022.186
  综合评述 本期目录 | 过刊浏览 |
醋酸环境下金属材料腐蚀行为的研究进展
刘明明1,2, 杨小兵3, 陈晓琪3, 王政彬2(), 郑玉贵2, 贺春林4
1.沈阳大学师范学院 沈阳 110044
2.中国科学院金属研究所 中国科学院核用材料与安全评价重点实验室 沈阳 110016
3.南通醋酸纤维有限公司 南通 226008
4.沈阳大学 辽宁省先进材料制备技术重点实验室 沈阳 110044
Research Progress on Corrosion Behavior of Metallic Materials in Acetic Acid Environment
LIU Mingming1,2, YANG Xiaobing3, CHEN Xiaoqi3, WANG Zhengbin2(), ZHENG Yugui2, HE Chunlin4
1.Normal College, Shenyang University, Shenyang 110044, China
2.CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3.Nantong Cellulose Fibers Co. Ltd., Nantong 226008, China
4.Liaoning Provincial Key Laboratory of Advanced Materials, Shenyang University, Shenyang 110044, China
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摘要: 

以醋酸环境下金属部件的腐蚀失效案例为导向,总结了金属材料在醋酸环境下的腐蚀机理、影响因素 (如醋酸温度、浓度、杂质等) 及防护措施,旨在为醋酸环境用金属材料的选择以及制定合理的防腐方案提供一定指导。

关键词 醋酸金属材料腐蚀机理影响因素防护措施    
Abstract

Acetic acid is an important raw material and plays an important role in the modern chemical industry. However, acetic acid is highly corrosive, which can easily cause corrosion of metallic components, threatening the service safety of equipment. In order to better understanding and preventing the corrosion induced by acetic acid, this paper summarizes the mechanisms, influencing factors (temperature, acetic acid concentration and impurities) and protection measures for corrosion of metals in acetic acid, on the basis of practical corrosion failure cases. It is expected to provide some guidance for selecting proper materials and taking effective measures to protect components serving in acetic acid environments from corrosion.

Key wordsacetic acid    metals    corrosion mechanism    influencing factor    prevention measure
收稿日期: 2022-06-08      32134.14.1005.4537.2022.186
ZTFLH:  TG174  
作者简介: 刘明明,女,1986年生,讲师

引用本文:

刘明明, 杨小兵, 陈晓琪, 王政彬, 郑玉贵, 贺春林. 醋酸环境下金属材料腐蚀行为的研究进展[J]. 中国腐蚀与防护学报, 2023, 43(1): 13-21.
Mingming LIU, Xiaobing YANG, Xiaoqi CHEN, Zhengbin WANG, Yugui ZHENG, Chunlin HE. Research Progress on Corrosion Behavior of Metallic Materials in Acetic Acid Environment. Journal of Chinese Society for Corrosion and protection, 2023, 43(1): 13-21.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2022.186      或      https://www.jcscp.org/CN/Y2023/V43/I1/13

图1  金属材料表面醋酸吸附率与未解离醋酸浓度间的关系[6]
图2  N80碳钢在含HAc的CO2溶液中缝隙腐蚀机理示意图[21]
Material90% HAc (boiling)50% HAc+10% HCOOH (boiling)50%HAc+25% HCOOH (boiling)50%HAc+50% HCOOH (boiling)HAc:Cl-=1:1 (70 ℃)HAc:Cl-=2:1 (boiling)HAc+Br-(80 ℃)
3040.5-1.0>0.1------<0.10.1-1.02.05
316L0.01-0.10.1-1.00.1-1.0---<0.1<0.11.67
2205---<0.10.1-1.00.1-1.0<0.1<0.1Pitting
904L------0.1-1.00.1-1.0<0.1<0.10.47
254SMO---<0.1<0.1<0.1<0.1<0.10.36
表1  不锈钢在不同醋酸溶液中的腐蚀速率
图3  奥氏体和双相不锈钢在含不同比例甲酸的50%醋酸溶液中的腐蚀速率[25]
MaterialHAcHAc+Cl-/Br-HAc+HCOOH+Cl-HAc+Cl-+Br-
<65 ℃65~135 ℃>135 ℃<105 ℃105~135 ℃>135 ℃<100 ℃>120 ℃Oxygen enrichmentLack of oxygen
304
316L
904L
254SMO
TA2
C276
表2  金属材料在不同醋酸溶液中的使用建议
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