317L/FH40复合板在不同温度下摩擦-腐蚀耦合作用机理研究

doi:10.11902/1005.4537.2022.013

中国腐蚀与防护学报

2023, Vol. 43

Issue (1): 69-76 CSTR: 32134.14.1005.4537.2022.013 DOI: 10.11902/1005.4537.2022.013

研究报告

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317L/FH40复合板在不同温度下摩擦-腐蚀耦合作用机理研究

孙士斌¹, 赵子铭¹, 高珍鹏², 宫旭辉², 王东胜³, 强强¹, 常雪婷³(

)

^1.上海海事大学物流工程学院上海 201306
^2.中国船舶重工集团第七二五研究所洛阳 471000
^3.上海海事大学海洋科学与工程学院上海 201306

Friction-corrosion Performance of Steels and Their Welding Zone for Composite Plate of 317L Stainless Steel/FH40 Low-temperature Marine Steel in Simulated Sea Waters at Different Temperatures

SUN Shibin¹, ZHAO Ziming¹, GAO Zhenpeng², GONG Xuhui², WANG Dongsheng³, QIANG Qiang¹, CHANG Xueting³(

)

^1.Logistics Engineering College, Shanghai Maritime University, Shanghai 201306, China
^2.Luoyang Ship Material Research Institute, Luoyang 471000, China
^3.School of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China

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摘要:

针对在极地环境使用的特殊海水-海冰摩擦-腐蚀耦合作用环境，使用UMT-2型多功能摩擦磨损实验机分别测试了新型FH40级低温钢板、抗海水腐蚀性能优异的317L不锈钢以及两种钢板焊接部位在不同条件下的往复摩擦-腐蚀耦合行为；使用金相显微镜、白光干涉仪以及扫描电子显微镜表征了钢样的显微组织形貌和磨痕形貌。结果表明：随着环境温度从20 ℃降低到-20 ℃，FH40钢及焊缝处的摩擦系数和磨损量都明显增加，而317L不锈钢变化不大；值得关注的是，在海水环境中进行摩擦测试时，可见317L不锈钢的整体损失量远远低于FH40钢及焊缝处的，证明317L不锈钢可应用于极地破冰船船体外表面。另外，使用电化学阻抗、极化技术测试了钢材耐蚀性能，以期确定低温环境对复合钢板耐蚀性的影响。结果证明复合板焊缝处在常温及低温条件下，腐蚀速率皆低于FH40低温钢，两种钢板复合仍保持良好耐蚀性。

关键词 ：不锈钢, 低温钢, 摩擦磨损, 低温, 不锈钢复合板

Abstract：

The performance of friction and corrosion of FH40 steel, 317L stainless steel and their welding zone of the explosive formed composite plate of FH40 steel/317L stainless steel was studied via UMT-2 multifunctional friction-wear tester with a grinding ball of alumina (Al₂O₃) in simulated environments of sea water and sea ice, respectively at different temperatures. Their microstructure and wear morphology were characterized by metallographic microscope, white light interferometer and scanning electron microscope. The results showed that with the decrease of temperature, from 20 ℃ to -20 ℃, the friction coefficient and wear loss of FH40 steel and the welding zone increase significantly, while 317L stainless steel changed only little. It should be emphasized on that the wear and corrosion loss of 317L stainless steel is much lower than that of FH40 steel and the welding zone in sea water, which confirmed the feasibility of 317L stainless steel as the shell material for icebreaker. In addition, the corrosion resistance of the steels was also assessed by means of measurements of electrochemical impedance and polarization curves in order to determine the effect of low temperature environment on the corrosion resistance of composite steel plate. The results showed that the corrosion rate of the welding zone was lower than FH40 steel both at room temperature and low temperature.

Key words： stainless steel FH40 steel friction and wear low temperature clad sheet

收稿日期: 2022-01-09 32134.14.1005.4537.2022.013

ZTFLH:

TG174

基金资助:上海市科委技术标准项目(21DZ2205700);上海市教委“曙光”计划(19SG46);科技部国际合作交流项目(CU03-29);上海深海材料工程技术中心项目(19DZ2253100)

作者简介: 孙士斌，男，1982年生，博士，副教授

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引用本文:

孙士斌, 赵子铭, 高珍鹏, 宫旭辉, 王东胜, 强强, 常雪婷. 317L/FH40复合板在不同温度下摩擦-腐蚀耦合作用机理研究[J]. 中国腐蚀与防护学报, 2023, 43(1): 69-76.
Shibin SUN, Ziming ZHAO, Zhenpeng GAO, Xuhui GONG, Dongsheng WANG, Qiang QIANG, Xueting CHANG. Friction-corrosion Performance of Steels and Their Welding Zone for Composite Plate of 317L Stainless Steel/FH40 Low-temperature Marine Steel in Simulated Sea Waters at Different Temperatures. Journal of Chinese Society for Corrosion and protection, 2023, 43(1): 69-76.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2022.013 或 https://www.jcscp.org/CN/Y2023/V43/I1/69

图1 实验所用复合钢板金相及取样方法

图2 FH40低温船用钢材及317L不锈钢金相形貌

图3 FH40低温钢、焊缝处与317L不锈钢在不同温度/介质条件下的摩擦系数

表1 FH40低温钢、317L不锈钢及焊缝处在不同温度/介质条件下的平均摩擦系数

图4 FH40低温钢、焊缝处及317L不锈钢磨痕轮廓与磨损量

图5 焊缝处磨痕形貌SEM照片

图6 不同温度/介质条件下焊缝处磨痕形貌

图7 FH40低温钢、焊缝处及317L不锈钢在海水中的开路电位

图8 复合钢板海水腐蚀电化学阻抗拟合电路示意图及不同腐蚀周期阻抗谱

表2 海水腐蚀10 d后等效电路拟合参数

图9 海水腐蚀10 d后动电位极化曲线

表3 3种材料海水腐蚀10 d后的极化曲线拟合结果

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