Please wait a minute...
中国腐蚀与防护学报  2006, Vol. 26 Issue (1): 43-47     
  研究报告 本期目录 | 过刊浏览 |
有机防腐涂层在流动条件下的加速失效行为
魏英华;张立新;柯伟
中国科学院金属研究所; 金属腐蚀与防护国家重点实验室
ACCELERATING DEGRADATION OF ORGANIC PROTECTION COATING UNDER FLOW STATE
Yinghua Wei;Lixin Zhang;Wei Ke
中国科学院金属研究所; 金属腐蚀与防护国家重点实验室
全文: PDF(240 KB)  
摘要: 选用熔融结合环氧粉末(FBE)涂层作为研究对象,用电化学阻抗谱法(EIS)考察流动的和静止的涂层在3% NaCl溶液介质中的失效行为,以此探讨流动条件对涂层的失效行为的影响.结果表明,涂层在流动的条件下加速失效,失效的原因是液体的流动加速了溶液中离子,而不是水分子向涂层中的渗透.这为考核涂层提供了一种新的加速实验方法.
关键词 电化学阻抗FBE涂层流动失效    
Abstract:Fusion-bonded epoxy (FBE) powder coating on steel was selected to investigate the effect of flowing condition on coating degradation in 3% NaCl aqueous solution at 60℃ by EIS.The immersion tests in flowing condition were conduct ed by using a rotating cylinder apparatus.The relative permittivity calculated from the high frequency value of impedance spectra,was used as the index to monitor properties variation with immersion time.The results obtained from EIS measurements and visual examination showed that the flowing immersion condition brought much greater destruction to the coatings than the corresponding static condition.This results can be explained that the introduction of flowing condition accelerated the ions,not water molecules,into the coatings.The present investi gation provides an accelerating test way to evaluate degradation of excellent coating.
Key wordsEIS    FBE powder coatings    Flow    Degradation
收稿日期: 2004-11-23     
ZTFLH:  TG172  
通讯作者: 魏英华     E-mail: yhwei@imr.ac.cn
Corresponding author: Yinghua Wei     E-mail: yhwei@imr.ac.cn

引用本文:

魏英华; 张立新; 柯伟 . 有机防腐涂层在流动条件下的加速失效行为[J]. 中国腐蚀与防护学报, 2006, 26(1): 43-47 .
Yinghua Wei, Lixin Zhang, Wei Ke. ACCELERATING DEGRADATION OF ORGANIC PROTECTION COATING UNDER FLOW STATE. J Chin Soc Corr Pro, 2006, 26(1): 43-47 .

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2006/V26/I1/43

[1]Bierwagen G P,Ed.Organic Coatings for Corrosion Control,ACSSymposium Series 689[M].Washington DC,American ChemicalSociety,1998,151-160
[2]Van der Weijde D H,Van Westing E P M,De Wit J H W.Moni-toring the effect of environmental changes on coating propertieswith EIS[J].Materials Science Forum,1998,289-292:237-246
[3]Mansfeld F.Use of electrochemical impedance spectroscopy for thestudy of corrosion protection by polymer coatings[J].J.Appl.Elec-trochem.,1995,25:187-202
[4]Scully J R.Electrochemical impedance of organic-coated steel:cor-relation of impedance parameters with long-term coating deterio-ration[J].J.Electrochem.Soc.,1989,136:979-990
[5]Bonora P L,Deflorian F,Fedrizzi L.Electrochemical impedancespectroscopy as a tool for investigating underpaint corrosion[J].Electrochim.Acta,1996,41:1073-1082
[6]Mansfeld F,Han L T,Lee C C.Evaluation of corrosion protectionby polymer coatings using electrochemical impedance spectroscopyand noise analysis[J].Electrochim.Acta,1998,43:2933-2945
[7]Oliveira C G,Ferreira M G S.Ranking high-quality paint systemsusing EIS.Part I:intact coatings[J].Corros.Sci.,2003,45:123-138
[8]Mansfeld F,Tsai C H.Determination of coating deterioration withEIS I.basic relationships[J].Corrosion,1991,47:958-965
[9]Walter G W.A review of impedance plot methods used for corro-sion performance analysis of painted metals[J].Corros.Sci.,1986,26:681-703
[10]Ruggeri R T,Beck T R.An analysis of mass transfer in filiformcorrosion[J].Corrosion,1983,39:452-465
[11]Miskovic-Stankovic V B,Drazic D M,Teodorovic M J.Elec-trolyte penetration through epoxy coatings electrodeposited on steel[J].Corros.Sci.,1995,37:241-252
[12]Miskovic-Stankovic V B,Maksimovic M D,Kacarevic-PopovicZ.The sorption characteristics and thermal stability of epoxy coat-ings electrodeposited on steel and steel electrochemically modifiedby Fe-P alloys[J].Prog.Org.Coat.,1998,33:68-75
[13]Bierwagen G P,He L,Li J.Study of a new accelerated evaluationmethod for coating corrosion resistance-thermal cycling testing[J].Prog.Org.Coat.,2000,39:67-78
[1] 胡露露, 赵旭阳, 刘盼, 吴芳芳, 张鉴清, 冷文华, 曹发和. 交流电场与液膜厚度对A6082-T6铝合金腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2020, 40(4): 342-350.
[2] 孙硕, 杨杰, 钱薪竹, 常人丽. Ni-Cr-P化学镀层的制备与电化学腐蚀行为[J]. 中国腐蚀与防护学报, 2020, 40(3): 273-280.
[3] 曹京宜, 王智峤, 李亮, 孟凡帝, 刘莉, 王福会. 深海压力交变加速条件下改性石墨烯有机涂层的失效机制[J]. 中国腐蚀与防护学报, 2020, 40(2): 139-145.
[4] 赵书彦,童鑫红,刘福春,翁金钰,韩恩厚,郦晓慧,杨林. 环氧富锌涂层防腐蚀性能研究[J]. 中国腐蚀与防护学报, 2019, 39(6): 563-570.
[5] 王贵容,郑宏鹏,蔡华洋,邵亚薇,王艳秋,孟国哲,刘斌. 环氧防腐涂料在模拟海水干湿交替条件下的失效过程[J]. 中国腐蚀与防护学报, 2019, 39(6): 571-580.
[6] 王霞,任帅飞,张代雄,蒋欢,古月. 豆粕提取物在盐酸中对Q235钢的缓蚀性能[J]. 中国腐蚀与防护学报, 2019, 39(3): 267-273.
[7] 达波,余红发,麻海燕,吴彰钰. 等效电路拟合珊瑚混凝土中钢筋锈蚀行为的电化学阻抗谱研究[J]. 中国腐蚀与防护学报, 2019, 39(3): 260-266.
[8] 达波,余红发,麻海燕,吴彰钰. 阻锈剂的掺入方式对全珊瑚海水混凝土中钢筋锈蚀的影响[J]. 中国腐蚀与防护学报, 2019, 39(2): 152-159.
[9] 刘丽,于思荣. 添加Gd对AM60镁合金耐腐蚀性能的影响[J]. 中国腐蚀与防护学报, 2019, 39(2): 185-191.
[10] 蓝秀玲,刘光明,周街胜,刘志雷,彭叔森,李茂东. 有机硅/SiO2杂化溶胶改性丙烯酸树脂及性能研究[J]. 中国腐蚀与防护学报, 2018, 38(6): 601-606.
[11] 邓培昌, 刘泉兵, 李子运, 王贵, 胡杰珍, 王勰. X70管线钢在热带海水-海泥跃变区的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2018, 38(5): 415-423.
[12] 邓三喜, 闫小宇, 柴柯, 吴进怡, 史洪微. 假单胞菌对聚硅氧烷树脂清漆涂层分解及防腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2018, 38(4): 326-332.
[13] 姚望, 周和荣, 肖葵, 刘鹏洋, 但佳永, 吴润. 中性盐雾环境中DC06超深冲钢的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2018, 38(3): 241-247.
[14] 曹海娇, 魏英华, 赵洪涛, 吕晨曦, 毛耀宗, 李京. Q345钢预热时间对熔结环氧粉末涂层防护性能的影响II:涂层体系失效行为分析[J]. 中国腐蚀与防护学报, 2018, 38(3): 255-264.
[15] 桂琪, 郑大江, 宋光铃. 醇酸清漆保护性的电化学加速评价[J]. 中国腐蚀与防护学报, 2018, 38(3): 274-282.