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中国腐蚀与防护学报  2013, Vol. 33 Issue (2): 153-158    
  研究报告 本期目录 | 过刊浏览 |
时效处理工艺对1975合金腐蚀性能的影响
赵 凯 尹志民 段佳琦 邓 英
中南大学材料科学与工程学院 长沙 410083
Effects of Aging Treatment on Corrosion Properties of 1975 Aluminum Alloy
ZHAO Kai, YIN Zhimin, DUAN Jiaqi, DENG Ying
School of Material Science and Engineering, Central South University, Changsha 410083, China
全文: PDF(4606 KB)  
摘要: 采用恒温浸泡、极化曲线、金相、扫描电镜和透射电镜技术研究不同时效处理工艺对1975铝合金的晶间腐蚀、剥落腐蚀和应力腐蚀行为的影响。结果表明,1975铝合金单级时效后的晶间腐蚀、剥落腐蚀和应力腐蚀的敏感性变化规律为:欠时效(120 ℃/12 h)>峰时效(120 ℃/24 h)>过时效(120 ℃/36 h)。合金的腐蚀敏感性与晶界析出相η (MgZn2)和无沉淀析出带(PFZ)的特征有关,析出相分布越不连续,尺寸越大,无沉淀析出带越宽化,合金的腐蚀敏感性越低;反之,如果晶界析出相链状分布且尺寸较小,则合金的腐蚀敏感性高。
关键词 1975合金时效处理腐蚀性能    
Abstract:The intergranular corrosion, exfoliation corrosion, stress corrosion properties of 1975 aluminum alloy with different aging treatments were investigated using constant temperature immersion corrosion method, polarization curve measurement, optical microscopy, scanning electronic microscopy (SEM) and transmission electron microscopy (TEM) analysis. The results showed that the sensibility of intergranular corrosion, exfoliation corrosion and stress corrosion of 1975 aluminum alloy arranged in order as followed:underaging (120 ℃/12 h)>peak-aging (120 ℃/24 h)>overaging (120 ℃/36 h), which was attributed to the characteristic of grain boundary precipitation phase η (MgZn2) and precipitation free zone (PFZ). When the equilibrium phase η distributed uncontinuously and had large size as well as the PFZ was wide, the corrosion sensibility was low.In contrast, when the grain-boundary equilibrium phase had continuous distribution and small size, the corrosion sensibility was high.
Key wordsKey words:1975 aluminum alloy    aging treatment    corrosion properties
    
ZTFLH:  TG172.6  

引用本文:

赵 凯 尹志民 段佳琦 邓 英. 时效处理工艺对1975合金腐蚀性能的影响[J]. 中国腐蚀与防护学报, 2013, 33(2): 153-158.
. Effects of Aging Treatment on Corrosion Properties of 1975 Aluminum Alloy. Journal of Chinese Society for Corrosion and protection, 2013, 33(2): 153-158.

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2013/V33/I2/153

[1] Wang Z T, Tian R Z. Handbook of Aluminium Alloy and its Working [M]. Changsha: Central South University Press, 2005
(王祝堂, 田荣璋. 铝合金及其加工手册(第三版) [M]. 长沙: 中南大学出版社, 2005)
[2] Liu C B, Xia C Q,Dai X Y, et al. Present states of research and developing trends of high strength and high toughness aluminum alloy [J]. Mining Metall. Eng., 2003, 23(5): 74-82
(刘昌斌, 夏长清, 戴晓元等. 高强高韧铝合金的研究现状及发展趋势 [J]. 矿冶工程, 2003, 23(5): 74-82)
[3] Yin Z M, Pan Q L, Jiang F, et al. Scandium and its Alloys [M]. Changsha: Central South Univeisity Press, 2007
(尹志民, 潘青林, 姜峰等. 钪和含钪合金 [M]. 长沙: 中南大学出版社, 2007)
[4] Yin Z M, Fang J F, Huang J W, et al. Effects of aging treatment on intergranular corrosion and exfoliation corrosion behavior of 7A52 aluminum alloy [J]. J. Central South Univ. (Sci. Technol.), 2007, 38(4): 617-622
(尹志民, 方家芳, 黄继武等. 时效工艺对7A52铝合金晶间腐蚀和剥蚀行为的影响 [J]. 中南大学学报(自然科学版), 2007, 38(4): 617-622)
[5] Huang L P, Chen K H, Li S, et al. Effect of high-temperature pre-precipitation on stress corrosion cracking of Al-Zn-Mg aluminum alloy plate [J]. Rare Met. Mater. Eng., 2006, 35(12): 1943-1948
(黄兰萍, 陈康华, 李松等. 高温预析出对 Al-Zn-Mg 合金板材应力腐蚀断裂的影响 [J]. 稀有金属材料与工程, 2006, 35(12): 1943-1948)
[6] Zhang X M,You J H,Zhang X Y, et al. Effect of pre-precipitation after solution on mechanical properties and corrosion resistance of aluminum alloy 7A55 [J]. Chin. J. Nonferrous Met., 2007, 17(12): 1922-1927
(张新明, 游江海, 张小艳等. 固溶后析出对7A55铝合金力学及腐蚀性能的影响 [J]. 中国有色金属学报, 2007, 17(12): 1922-1927)
[7] Xiao J M, Cao C N. Materials Corrosion Principles [M]. Beijing: Chemical Industry Press, 2002
(肖纪美, 曹楚南. 材料腐蚀学原理 [M]. 北京: 化学工业出版社, 2002)
[8] Ohnishi T, Ibaraki Y, Ito T. Improvement of fracture toughness in 7475 aluminum alloy by the RRA (retrogression and re-ageing) process [J]. Mater. Trans., JIM, 1989, 30(8): 601-607
[9] Chinese Society for Corrosion and Protection Society editor. Non-ferrous Metal Corrosion Resistance and Its Application [M]. Beijing: Chemical Industry Press, 2002
(中国腐蚀与防护学会主编. 有色金属的耐腐蚀性及其应用 [M]. 北京: 化学工业出版社, 1997)
[10] Liu Y. Progress in the study of stress corrosion cracking of aluminum alloy [J]. J. Beijing Union Univ. (Natur. Sci.), 2006, 20(1): 31-35
(刘洋. 铝合金应力腐蚀开裂的研究进展 [J]. 北京联合大学学报(自然科学版), 2006, 20(1): 31-35)
[11] Du A H, Long J M, Pei H Z, et al. Investigation of stress corrosion cracking of 7xxx series aluminum alloys [J]. J. Chin. Soc. Corros. Prot., 2008, 28(4): 251-256
(杜爱华, 龙晋明, 裴和中等. 高强铝合金应力腐蚀研究进展 [J]. 中国腐蚀与防护学报, 2008, 28(4): 251-256)
[12] Tanguy D, Bayle B, Dif R, et al. Hydrogen effects during IG2 SCC of pure Al-5Mg alloy in NaCl media [J]. Corros. Sci., 2002, 44: 1163-1175
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