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中国腐蚀与防护学报  2026, Vol. 46 Issue (2): 450-460     CSTR: 32134.14.1005.4537.2025.124      DOI: 10.11902/1005.4537.2025.124
  研究报告 本期目录 | 过刊浏览 |
C/SiC复合材料的高温自对偶摩擦磨损行为及机制
王姗姗1,2, 庞生洋2, 梁斌2, 高禩洋2, 张伟3, 樊俊铃3, 张帆1, 胡成龙2, 汤素芳2()
1.沈阳工业大学材料科学与工程学院 沈阳 110870
2.中国科学院金属研究所 沈阳 110016
3.中国飞机强度研究所 强度与结构完整性全国重点实验室 西安 710065
High-temperature Friction- and Wear-behavior for Friction-pairs of Identical C/SiC Composite
WANG Shanshan1,2, PANG Shengyang2, LIANG Bin2, GAO Siyang2, ZHANG Wei3, FAN Junling3, ZHANG Fan1, HU Chenglong2, TANG Sufang2()
1.School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
2.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3.National Key Laboratory of Strength and Structural Integrity, Aircraft Strength Research Institute of China, Xi'an 710065, China
引用本文:

王姗姗, 庞生洋, 梁斌, 高禩洋, 张伟, 樊俊铃, 张帆, 胡成龙, 汤素芳. C/SiC复合材料的高温自对偶摩擦磨损行为及机制[J]. 中国腐蚀与防护学报, 2026, 46(2): 450-460.
Shanshan WANG, Shengyang PANG, Bin LIANG, Siyang GAO, Wei ZHANG, Junling FAN, Fan ZHANG, Chenglong HU, Sufang TANG. High-temperature Friction- and Wear-behavior for Friction-pairs of Identical C/SiC Composite[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(2): 450-460.

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摘要: 

采用微纳多孔碳陶瓷化改进反应熔体浸渗技术制备了2D针刺和网胎针刺结构的C/SiC复合材料(SiC体积分数分别为60%和75%),研究了预制体结构和环境温度对该材料高温自对偶摩擦磨损性能的影响。结果表明,两种复合材料的摩擦系数随温度升高均呈现先升高后降低并趋于稳定的趋势,而磨损率呈现先降低后升高的趋势。究其原因,在温度较低时材料表面发生磨粒磨损,磨屑填充表面凹坑中形成摩擦膜,摩擦阻力减小;而当温度升高到一定程度后,材料表面疲劳磨损加剧,摩擦膜生成和脱落过程反复进行。与2D针刺结构相比,网胎针刺C/SiC复合材料在500 ℃时具有较高的摩擦系数(0.53)和较低的磨损率(710.7 mg/cycle),综合摩擦性能较好,这是因为网胎针刺C/SiC复合材料中SiC含量较高,高温摩擦导致大量摩擦膜脱落,磨损表面摩擦阻力较大。此外,在载荷为30 N,转速为80 r/min,摩擦磨损时间为1800 s的测试条件下,尽管在相同温度下两种C/SiC复合材料的磨损机制基本一致,但它们的磨损机制随温度变化而不同。25 ℃下两种复合材料表面犁沟效应明显,对应磨粒磨损;200 ℃下两种复合材料表面出现裂纹和少量剥落坑,对应磨粒磨损和疲劳磨损;400~500 ℃下两种复合材料氧化导致表面裂纹和剥落坑数量增加,对应磨粒磨损、氧化磨损和疲劳磨损。

关键词 C/SiC复合材料摩擦磨损环境温度预制体结构SiC含量反应熔体浸渗陶瓷化    
Abstract

Carbon fiber reinforced silicon carbide composites (C/SiC) have low density and thermal expansion coefficient, and excellent resistance to wear and oxidation, and they have become one of the important materials for braking systems. However, there are few reports on the friction- and wear-performance for friction-pairs of identical C/SiC material, resulting in the lack of reliable theoretical support in engineering design. In this work, needle-punched weftless and needle-punched nonwoven composite materials of C/SiC (with SiC content of 60% and 75%, respectively) were prepared by improved reaction melt infiltration through the ceramization of micro-nano porous carbon. The influence of preform structures and testing temperatures (25, 200, 400 and 500 ℃) on the friction- and wear-performance for friction-pairs of the two C/SiC composite materials respectively were investigated by means of X-ray diffraction, scanning electron microscopy and laser scanning confocal microscopy after high-temperature pin-disk friction and wear tests. The results show that with the increasing temperatures, the friction coefficients of the two C/SiC composite materials first increase and then decrease until they stabilize, while the wear rates first decrease and then increase. Such behaviour may be ascribed to that the abrasive wear occurs at lower temperatures on the materials surface, while the formed wear debris fill in the surface depressions resulting the friction film formation, and thus frictional resistance decreases; with the further increasing temperature the fatigue wear may emerge, resulting in the alternative formation and detachment of friction films. In addition, when the temperature reaches up to 500 ℃, compared with the needle-punched weftless C/SiC, the needle-punched nonwoven C/SiC composite has a higher friction coefficient of 0.53 and lower wear rate of 710.7 mg/cycle, suggesting better friction and wear performance. It is due to the higher content of SiC in the needle-punched nonwoven C/SiC composite.

Key wordsC/SiC composites    friction and wear    experimental ambient temperatures    preform structures    SiC content    reaction melt infiltration    ceramization
收稿日期: 2025-04-22      32134.14.1005.4537.2025.124
ZTFLH:  TB332  
基金资助:国家自然科学基金(52272075);国家自然科学基金(52402095);国家自然科学基金(52472053)
通讯作者: 汤素芳,E-mail:sftang@imr.ac.cn,研究方向为碳基和陶瓷基复合材料
作者简介: 王姗姗,女,2000年生,硕士生
图1  2D针刺和网胎针刺结构的碳纤维织物以及相应C/SiC复合材料的微观形貌
图2  2D针刺和网胎针刺C/SiC复合材料的XRD谱
SampleDensity / g·cm-3Open porosity / %Volume fraction / %
SiCCarbon fiberPyC
NWS2.43 ± 0.043.68 ± 0.4260 ± 1287 ± 1
NNS2.46 ± 0.036.05 ± 0.6675 ± 199 ± 1
表1  2D针刺和网胎针刺C/SiC复合材料的物理参数
图3  2D针刺和网胎针刺C/SiC复合材料在不同温度摩擦测试过程中瞬时摩擦系数变化曲线
图4  2D针刺C/SiC复合材料在不同实验环境温度下的磨损表面形貌和EDS分析
图5  网胎针刺C/SiC复合材料在不同实验环境温度下的磨损表面形貌和EDS分析
图6  2D针刺和网胎针刺C/SiC复合材料的平均摩擦系数及磨损率
图7  2D针刺和网胎针刺C/SiC复合材料在不同实验环境温度下摩擦磨损测试后的表面轮廓宏观形貌
图8  2D针刺和网胎针刺C/SiC复合材料在不同环境温度下磨损后的表面光学形貌
图9  不同温度下网胎针刺C/SiC复合材料磨损表面形貌
图10  不同实验环境温度下C/SiC复合材料的自对偶磨损机制示意图
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