吐温<strong>-80</strong>对一种冷轧钢在氨基磺酸溶液中的缓蚀性能及机理研究

doi:10.11902/1005.4537.2024.076

中国腐蚀与防护学报

2024, Vol. 44

Issue (6): 1538-1546 CSTR: 32134.14.1005.4537.2024.076 DOI: 10.11902/1005.4537.2024.076

研究报告

本期目录 | 过刊浏览

吐温-80对一种冷轧钢在氨基磺酸溶液中的缓蚀性能及机理研究

唐莉清¹, 李向红¹, 朱平¹^,², 武中发¹, 雷然¹, 徐娟¹(

)

1.西南林业大学材料与化学工程学院林业生物质资源高效利用技术国家地方联合工程研究中心昆明 650224
2.云南省特种设备安全检测研究院昆明 650228

Corrosion Inhibition Performance and Mechanism of Tween-80 on a Cold Rolled Steel in NH₂SO₃H Solution

TANG Liqing¹, LI Xianghong¹, ZHU Ping¹^,², WU Zhongfa¹, LEI Ran¹, XU Juan¹(

)

1. National Joint Engineering Research Center for Highly-Efficient Utilization Technology of Forestry Resources, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China
2. Yunnan Provincial Special Equipment Safety Testing and Research Institute, Kunming 650228, China

引用本文:

唐莉清, 李向红, 朱平, 武中发, 雷然, 徐娟. 吐温-80对一种冷轧钢在氨基磺酸溶液中的缓蚀性能及机理研究[J]. 中国腐蚀与防护学报, 2024, 44(6): 1538-1546.
Liqing TANG, Xianghong LI, Ping ZHU, Zhongfa WU, Ran LEI, Juan XU. Corrosion Inhibition Performance and Mechanism of Tween-80 on a Cold Rolled Steel in NH₂SO₃H Solution[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(6): 1538-1546.

全文: PDF(4956 KB) HTML

摘要:

通过失重法、动电位极化曲线法、原子力显微镜(AFM)和X射线光电子能谱(XPS)以及缓蚀溶液体系电导率和表面张力等研究了吐温-80在氨基磺酸溶液中的缓蚀机理。结果表明：在氨基磺酸溶液中吐温-80对冷轧钢具有良好的缓蚀效果。30℃时，在0.10 mol/L 氨基磺酸溶液中吐温-80的缓蚀率可高达94.33%；在冷轧钢表面，标准吸附Gibbs自由能(ΔG)为-29.94~-33.79 kJ/mol，说明吐温-80是以化学吸附为主的混合吸附，且其吸附服从Langmuir吸附等温式；吐温-80是混合抑制型缓蚀剂；在添加吐温-80后的溶液表面张力急剧降低；缓蚀后的电导率上升且趋于平缓，略低于浸泡前；AFM观察表明在添加吐温-80后能有效的抑制NH₂SO₃H对冷轧钢的腐蚀；XPS结果证实吐温-80能在钢片表面形成一层吸附膜层从而达到缓蚀的效果。

关键词 ：吐温-80, 氨基磺酸, 冷轧钢, 吸附, 缓蚀

Abstract：

The corrosion inhibition performance of Tween-80 for a cold rolled steel in amino sulfonic acid solution was studied by mass loss method, potentiodynamic polarization measurement, atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS), as well as measuring the conductivity and surface tension of corrosion inhibitor containing solutions. The results showed that Tween-80 had a good corrosion inhibition effect on cold-rolled steel in amino sulfonic acid solution. The corrosion inhibition efficiency of Tween-80 in 0.10 mol/L amino sulfonic acid solution at 30^oC can reach as high as 94.33%. The standard adsorption Gibbs free energy (ΔG) is -29.94~-33.79 kJ/mol for the inhibitor adsorption on the surface of cold-rolled steel, it indicates that Tween-80 is a mixed adsorption dominated by chemisorption, and it follows the Langmuir adsorption isotherm equation. Therefore, Tween-80 is a mixed inhibitory corrosion inhibitor. After adding Tween-80, the surface tension of the solution decreases sharply. With the progress of corrosion inhibition of the steel, the conductivity of the solution increases, then gradually decreases and tends to be flat, which finally slightly lower than the conductivity before the steel immersion in the solution. AFM and XPS results confirmed that Tween-80 can effectively suppress the corrosion, while form an adsorption film on the surface of steel to achieve corrosion inhibition effect.

Key words： Tween-80 NH₂SO₃H cold rolled steel adsorption corrosion relief

收稿日期: 2024-03-08 32134.14.1005.4537.2024.076

ZTFLH:

TG174

基金资助:国家自然科学基金(52161016);云南省基础研究计划杰出青年基金(202001AV070008);云南省农业基础研究联合专项重点项目(202101BD070001-017);西南林业大学林业生物质资源高效利用技术国家地方联合工程研究中心(2023-GC09);云南省大学生创新创业训练计划(20210153041)

通讯作者: 徐娟，E-mail:58045846@qq.com，研究方向为缓蚀剂

Corresponding author: XU Juan, E-mail: 58045846@qq.com

作者简介: 唐莉清，女，2000年生，硕士生

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	唐莉清
	李向红
	朱平
	武中发
	雷然
	徐娟
44.8K

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2024.076 或 https://www.jcscp.org/CN/Y2024/V44/I6/1538

图1 吐温-80的结构式

图2 冷轧钢在不同温度下0.10 mol/L NH2SO3H溶液中的腐蚀速率和缓蚀率随吐温-80浓度的变化

图3 不同温度下冷轧钢的c/θ-c拟合直线

表1 c/θ-c 线性拟合参数

图4 冷轧钢在含有不同浓度的吐温-80的0.10 mol/L NH2SO3H中的lnv-T-1和ln(v/T)-T-1曲线的线性拟合

图5 吐温-80浓度对冷轧钢的腐蚀动力学参数的影响

图6 冷轧钢在30℃下含不同浓度吐温-80的0.10 mol/L NH2SO3H溶液中的动电位极化曲线

表2 冷轧钢的极化曲线拟合参数

图7 30℃时吐温-80浓度对冷轧钢在不同溶液中浸泡前后的表面张力(σ)及电导率(к)的影响

图8 冷轧钢在30℃下0.10 mol/L NH2SO3H溶液中浸泡12 h后的AFM表面形貌

表3 冷轧钢表面的AFM粗糙度参数

图9 冷轧钢在30℃下含100 mg/L 吐温-80的0.10 mol/L NH2SO3H溶液中浸泡12 h后的XPS分析

图10 吐温-80在冷轧钢表面的缓蚀机理

1	Byrne C, D’Alessandro O, Selmi G J, et al. Primers based on tara and quebracho tannins for poorly prepared steel surfaces [J]. Prog. Org. Coat. 2019, 130: 244 doi: 10.1016/j.porgcoat.2019.02.003
2	Hou B R, Li X G, Ma X M, et al. The cost of corrosion in China [J]. npj Mater. Degrad., 2017, 1: 4
3	Tang B, Chen X Y. Study of corrosion inhibitors in acid Pickling [J]. Clean. World, 2006, 22(2): 22
3	(汤兵, 陈欣义. 酸洗过程中的缓蚀剂 [J]. 清洗世界, 2006, 22(2): 22)
4	Zhu Y K, Free M L, Woollam R, et al. A review of surfactants as corrosion inhibitors and associated modeling [J]. Prog. Mater. Sci., 2017, 90: 159
5	Wang J. The synergistic effects of Dodecane Phenol Polyethylene and potassium iodide on the inhibition of A3 steel in hydrochloric [D]. Guangzhou: Guangdong University of Technology, 2007
5	(王静. 盐酸介质中十二烷基酚聚氧乙烯醚与碘化钾对A3钢缓蚀协同效应的研究 [D]. 广州: 广东工业大学, 2007)
6	Li X H, Mu G N. Tween-40 as corrosion inhibitor for cold rolled steel in sulphuric acid: weight loss study, electrochemical characterization, and AFM [J]. Appl. Surf. Sci., 2005, 252: 1254
7	Mu G N, Li X M, Liu G H. Synergistic inhibition between tween 60 and NaCl on the corrosion of cold rolled steel in 0. 5M sulfuric acid [J]. Corros. Sci., 2005, 47: 1932
8	Zhou Q H, Zeng A X, Zhu Z P, et al. Inhibitory effect of Tween-80 on carbon steel in sulfuric acid [J]. J. Changsha Univ. Sci. Technol. (Nat. Sci.), 2005, 2(3): 89
8	(周琼花, 曾爱香, 朱志平等. 吐温-80对碳钢在硫酸溶液中的缓蚀作用研究 [J]. 长沙理工大学学报(自然科学版), 2005, 2(3): 89)
9	Zhang J, Liu Z, Liu J, et al. Synthesis and inhibition performance of Polyethylene Glycol(Peg) Lauric Acid Monoester Schiff Bases of non-ionic surface active ggent [J]. Corros. Prot., 2014, 35: 775
9	(张菁, 刘峥, 刘进等. 聚乙二醇月桂酸单酯席夫碱基非离子型表面活性剂的合成及缓蚀性能 [J]. 腐蚀与防护, 2014, 35: 775)
10	Chen X A. Application of amino sulfonic acid in supercritical boiler cleaning [J]. Clean. World, 2015, 31(5): 5
10	(陈学安. 氨基磺酸在超临界锅炉清洗中的应用 [J]. 清洗世界, 2015, 31(5): 5)
11	Du P F, Lei R, Li X H. Corrosion Inhibition effect of Mikania Micrantha Kunth Extract on cold rolled steel in Sulfamic Acid solution [J]. Corros. Prot., 2023, 44(4): 15
11	(杜鹏飞, 雷然, 李向红. 薇甘菊提取物对冷轧钢在氨基磺酸溶液中的缓蚀效果 [J]. 腐蚀与防护, 2023, 44(4): 15)
12	Liao Q Q, Chen Y Q, Yan A J, et al. The corrosion inhibition of alkyl imidazoline on carbon steel in amidosulphuric acid solution [J]. J. Chin. Soc. Corros. Prot., 2011, 31: 356
12	(廖强强, 陈亚琼, 闫爱军等. 氨基磺酸溶液中烷基咪唑啉对碳钢的缓蚀作用 [J]. 中国腐蚀与防护学报, 2011, 31: 356)
13	Zeng Y C, Fu C Y. Surface adsorption and corrosion inhibition behaviors of N-Cinnamylidene Methylamine Schiff Base on Q235 Steel in Sulfamic Acid [J]. Mater. Prot., 2017, 50(12): 19
13	(曾永昌, 付朝阳. 氨基磺酸中肉桂醛缩甲胺席夫碱对Q235钢的缓蚀吸附行为 [J]. 材料保护, 2017, 50(12): 19)
14	Wang P J, Song Y H, Fan L, et al. Inhibition of Q235 Steel in 1 mol/L HCl solution by a new efficient Imidazolium Schiff Base corrosion inhibitor [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 59
14	(王鹏杰, 宋昱灏, 樊林等. 新型高效咪唑希夫碱缓蚀剂对Q235钢在1 mol/L HCl溶液中的缓蚀作用 [J]. 中国腐蚀与防护学报, 2024, 44: 59)
15	Chen W, Huang D X, Wei F. Inhibition effect of Brainea Insignis extract against carbon steel corrosion in HCl solution [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 376
15	(陈文, 黄德兴, 韦奉. 铁蕨提取物对碳钢在盐酸中的缓蚀行为研究 [J]. 中国腐蚀与防护学报, 2021, 41: 376)
16	Wei G F, Lei R, Li X H. Inhibition action of Hexadecylpyridinium bromide on cold rolled steel in Cl₃CCOOH solution [J]. Chem. Res. Appl., 2022, 34: 1994
16	(魏高飞, 雷然, 李向红. 溴代十六烷基吡啶对冷轧钢在三氯乙酸中的缓蚀性能 [J]. 化学研究与应用, 2022, 34: 1994)
17	Branzoi V, Branzoi F, Baibarac M. The inhibition of the corrosion of Armco iron in HCl solutions in the presence of surfactants of the type of N-alkyl quaternary ammonium salts [J]. Mater. Chem. Phys., 2000, 65: 288
18	Pareek S, Jain D, Hussain S, et al. A new insight into corrosion inhibition mechanism of copper in aerated 3.5 wt.% NaCl solution by eco-friendly Imidazopyrimidine Dye: experimental and theoretical approach [J]. Chem. Eng. J., 2019, 358: 725
19	Chen S J, Tao A N, Zhang H, et al. Study on corrosion inhibition behavior of Photinia Leaf Extracts for Q235 steel in HCl medium [J]. Mater. Prot., 2024, 57(2): 51
19	(陈书军, 陶爱宁, 张海等. 石楠叶提取物在盐酸中对Q235钢的缓蚀行为研究 [J]. 材料保护, 2024, 57(2): 51)
20	Zakaria K, Hamdy A, Abbas M A, et al. New organic compounds based on siloxane moiety as corrosion inhibitors for carbon steel in HCl solution: weight loss, electrochemical and surface studies [J]. J. Taiwan Inst. Chem. Eng., 2016, 65: 530
21	Zhang Q B, Hua Y X. Corrosion inhibition of Aluminum in Hydrochloric Acid solution by Alkylimidazolium Ionic liquids [J]. Mater. Chem. Phys., 2010, 119: 57
22	Khadiri A, Saddik R, Bekkouche K, et al. Gravimetric, electrochemical and quantum chemical studies of some pyridazine derivatives as corrosion inhibitors for mild steel in 1 M HCl solution [J]. J. Taiwan Ins. Chem. Eng., 2016, 58: 552
23	Zhou L X, Zhang L P, Tang Y, et al. Preparation of Zinc Phytate and its effect on corrosion behavior of carbon steel [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 396
23	(周兰欣, 张丽萍, 汤燕等. 植酸锌的制备及其对Q235钢腐蚀行为的影响 [J]. 中国腐蚀与防护学报, 2024, 44: 396) doi: 10.11902/1005.4537.2023.159
24	Zhou K, Liu X H, Liu S. Corrosion inhibition of Navel Orange Peel extract to stainless steel in acidic medium [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 619
24	(周坤, 柳鑫华, 刘帅. 在酸性介质中脐橙皮提取物对不锈钢的缓蚀作用 [J]. 中国腐蚀与防护学报, 2023, 43: 619)
25	Luo W P, Luo X, Shi Y T, et al. Preparation and corrosion inhibition of super hydrophobic adsorption film of lotus leaf extract on mild steel [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 903
25	(罗为平, 罗雪, 石悦婷等. Q235钢表面的超疏水吸附层形成与缓蚀研究 [J]. 中国腐蚀与防护学报, 2022, 42: 903) doi: 10.11902/1005.4537.2021.296
26	Wei G F, Deng S D, Li X H. Eupatorium Adenophora (Spreng.) leaves extract as a highly efficient eco-friendly inhibitor for steel corrosion in Trichloroacetic acid solution [J]. Int. J. Electrochem. Sci., 2022, 17: 221182
27	Li X H, Deng S D, Du G B. Nonionic surfactant of coconut Diethanolamide as a novel corrosion inhibitor for cold rolled steel in both HCl and H₂SO₄ solutions [J]. J. Taiwan Inst. Chem. Eng. 2022, 131: 104171
28	Lei R, Li X H, Shi C J, et al. Inhibition mechanism of Fagopyrum Esculentum Moench. Extract on steel in HCl media [J]. Surf. Technol., 2023, 52(1): 162
28	(雷然, 李向红, 石成杰等. 荞麦提取物对钢在HCl介质中的缓蚀机理 [J]. 表面技术, 2023, 52(1): 162)
29	Zeng Y C. Study on the corrosion inhibitor of carbon steel in sulfamic acid [D]. Wuhan: Huazhong University of Science and Technology, 2017
29	(曾永昌. 氨基磺酸中碳钢腐蚀缓蚀剂研究 [D]. 武汉: 华中科技大学, 2017)
30	Zhang F, Deng S D, Wei G F, et al. Alternanthera philoxeroides extract as a corrosion inhibitor for steel in Cl₃CCOOH solution [J]. Int. J. Electrochem. Sci., 2023, 18: 100057
31	Aramaki K, Hagiwara M, Nishihara H. The synergistic effect of anions and the ammonium cation on the inhibition of iron corrosion in acid solution [J]. Corros. Sci., 1987, 27: 487
32	Zhou Y, Zhao X, Hu N, et al. A method for rapid analysis of Polysorbate 80 components [J]. J. China Pharm. Univ., 2022, 53: 192
32	(周颖, 赵恂, 胡楠等. 一种快速分析聚山梨酯80组分的方法 [J]. 中国药科大学学报, 2022, 53: 192)

[1]	穆显菊, 李向红, 雷然, 邓书端. 咖啡果皮提取物对钢在三氯乙酸溶液中的缓蚀性能[J]. 中国腐蚀与防护学报, 2024, 44(6): 1465-1475.
[2]	程学雨, 叶桓, 郭程皓, 卢立新, 李伟哲. 苯骈三氮唑与苯甲酸钠在气相防锈膜中扩散机理的分子动力学模拟研究[J]. 中国腐蚀与防护学报, 2024, 44(5): 1323-1331.
[3]	李鑫, 韦博鑫, 鲁仰辉, 孙晨, 于文涛, 徐猛, 刘伟. 临氢环境下管线钢氢损伤机理研究进展[J]. 中国腐蚀与防护学报, 2024, 44(5): 1125-1133.
[4]	石成杰, 雷然, 邓书端, 徐娟, 邵丹丹, 郭青青, 李向红. 小蓬草提取物对钢在HCl介质中的缓蚀作用[J]. 中国腐蚀与防护学报, 2024, 44(5): 1189-1199.
[5]	吴浩天, 张天遂, 李广芳, 刘宏芳. 中性水系锌离子电池负极缓蚀剂研究进展[J]. 中国腐蚀与防护学报, 2024, 44(5): 1089-1099.
[6]	冯礼奎, 程一杰, 宋小宁, 于志勇, 严梓轩, 张大全. 1, 2, 4-三唑在模拟调相机转子内冷却水中对铜的缓蚀作用[J]. 中国腐蚀与防护学报, 2024, 44(3): 772-780.
[7]	欧阳嘉露, 王茜茜, 韩霞, 王子明. 油水交替环境中咪唑啉对CO₂ 腐蚀的抑制作用研究[J]. 中国腐蚀与防护学报, 2024, 44(3): 707-715.
[8]	解辉, 于超, 花靖, 蒋秀. NH⁺₄浓度对N80钢在饱和CO₂ 的3%NaCl溶液中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2024, 44(3): 745-754.
[9]	魏高飞, 邓书端, 邵丹丹, 徐娟, 李向红. 滇润楠叶提取物对铝在HCl中的缓蚀性能[J]. 中国腐蚀与防护学报, 2024, 44(3): 601-611.
[10]	周龙, 鲁骏, 丁文珊, 李昊, 陶涛, 师超, 邵亚薇, 刘光明. 不同植酸盐对Q235钢腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2024, 44(3): 669-678.
[11]	龙武剑, 唐杰, 罗启灵, 丘章鸿, 王海龙. 生物质碳点对Q235钢的缓蚀性能研究[J]. 中国腐蚀与防护学报, 2024, 44(3): 807-814.
[12]	柳泽邦, 冉博元, 裴恒, 罗凯林, 赵智斌, 韩鹏, 强玉杰. 金属铝用复配缓蚀剂协同缓蚀作用研究[J]. 中国腐蚀与防护学报, 2024, 44(2): 312-322.
[13]	周文彬, 李梦冉, 周欣, 孙海静, 孙杰. 油溶性曼尼希碱缓蚀剂对紫铜在变压器油中的缓蚀行为研究[J]. 中国腐蚀与防护学报, 2024, 44(2): 453-461.
[14]	周兰欣, 张丽萍, 汤燕, 陈柯宇, 周剑军, 师超, 邵亚薇, 刘光明. 植酸锌的制备及其对Q235钢腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2024, 44(2): 396-404.
[15]	王鹏杰, 宋昱灏, 樊林, 邓宽海, 李忠慧, 梅宗斌, 郭雷, 林元华. 新型高效咪唑希夫碱缓蚀剂对Q235钢在1 mol/L HCl溶液中的缓蚀作用[J]. 中国腐蚀与防护学报, 2024, 44(1): 59-70.

Viewed

Full text

Abstract

Cited

Shared

Discussed