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中国腐蚀与防护学报  2015, Vol. 35 Issue (5): 379-385    DOI: 10.11902/1005.4537.2014.228
  本期目录 | 过刊浏览 |
含杂质超临界CO2输送管线腐蚀的研究进展
孙冲1,王勇1,孙建波1(),蒋涛1,赵卫民1,张彦春2
2. 廊坊中油朗威工程项目管理有限公司 廊坊 065000
Investigation Progress on Corrosion Behavior of Supercr-itical CO2 Transmission Pipelines Containing Impurities in CCS
Chong SUN1,Yong WANG1,Jianbo SUN1(),Tao JIANG1,Weimin ZHAO1,Yanchun ZHANG2
1. School of Mechanical & Electronic Engineering, China University of Petroleum, Qingdao 266580, China
2. China Petroleum LONGWAY Engineering Project Management Co. Ltd., Langfang 065000, China
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摘要: 

综述了目前超临界CO2输送管线腐蚀的研究成果,分析了超临界CO2输送管线潜在的腐蚀风险和腐蚀的影响因素,阐述了杂质对超临界CO2流体的相行为、水化学性质、腐蚀产物膜特征及腐蚀机理的影响,并指出了现有研究中不足之处和亟待解决的科学问题。
关键词 ： 碳捕集与封存,  超临界CO2,  杂质,  腐蚀膜,  腐蚀机理    
Abstract：

A range of impurities may exist in supercritical CO2 stream of transmission pipelines for carbon capture and storage (CCS) process, which are the potential corrosive factors to induce operational risks of the supercritical CO2 transmission pipeline. The impurities induced inner side corrosion of supercritical CO2 pipelines may become the bottleneck restricting the development and application of CCS. This paper reviews the recent research progress on the corrosion behavior of pipelines for supercritical CO2 transmission. The potential corrosion risks and the impact factors on corrosion are analyzed. The influence of impurities on the phase behavior, water chemistry characteristics, corrosion scales and the corrosion mechanism of transmission pipelines is also discussed. The shortcomings in the present investigations and the key scientific problems for further research are also pointed out.
Key words： carbon capture and storage    supercritical CO2    impurity    corrosion scale    corrosion mechanism
    
ZTFLH:     
基金资助:国家自然科学基金项目(51471188)和中央高校基本科研业务费专项资金项目(15CX06057A) 资助
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孙冲
王勇
孙建波
蒋涛
赵卫民
张彦春

引用本文:

孙冲, 王勇, 孙建波, 蒋涛, 赵卫民, 张彦春. 含杂质超临界CO2输送管线腐蚀的研究进展[J]. 中国腐蚀与防护学报, 2015, 35(5): 379-385.
Chong SUN, Yong WANG, Jianbo SUN, Tao JIANG, Weimin ZHAO, Yanchun ZHANG. Investigation Progress on Corrosion Behavior of Supercr-itical CO2 Transmission Pipelines Containing Impurities in CCS. Journal of Chinese Society for Corrosion and protection, 2015, 35(5): 379-385.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2014.228      或      https://www.jcscp.org/CN/Y2015/V35/I5/379

Ref. CO2 H2O O2 SOx NOx H2S CH4 N2 CO
DYNAMIS[6] ＞95.5 0.05 Aquifer＜4, EOR＜0.01~0.1 0.01 0.01 0.02 Aquifer＜4, EOR＜2 ＜4 0.2
Kinder Morgan[11] 95 0.063 0.001 --- --- 0.001~0.02 5 4 ---
Weyburn[11] 96 0.002 ＜0.007 --- --- 0.9 0.7 ＜0.03 0.1
Sheep Moutain[11] 96.8~97.4 0.0315 --- --- --- --- 1.7 0.6~0.9 ---
Central Basin[11] 98.5 0.063 ＜0.001 --- --- ＜0.002 0.2 1.3 ---
Literature data[12] 90~95 0.001~0.063 0.001~0.1 0.01~0.15 0.01~0.15 0.01~1.50 ＜5 ＜4 0.01~4
表1  超临界CO2输送管线流体组分质量要求
Steel Temperature ℃ Pressure MPa Volume fraction of H2O / % Volume fraction of O2 / % Volume fraction of SO2 / % Volume fraction of NO2 / % Corrosion rate mma-1
X65[4] 50 4~8 Saturability 0 0 0 ~0.2
X70[14] 22 6.3 0.149 0 0 0 No
X70[14] 22 6.3 0.244 0 0 0 Slight
X65[15] 20 10 0.122 0 0 0 No
X65[16] 50 8 Saturability 0 0 0 0.38
X65[16] 50 8 Saturability 4 1 0 ＞7
1010[17] 45 7.58 0.244 0.01 0 0 2.3
1010[17] 45 7.58 0.244 0 0.01 0 4.6
1010[17] 45 7.58 0.244 0 0 0.01 11.6
X65[18] 50 8 0.159 4 1 0 3.7
X70[19] 50 10 Saturability 0.1 0.2~2 0 0.2~0.9
X65[20] 25 10 0.0488 0 0.01~0.0344 0.0096~0.0478 0.005~1.6
X70[21] 50 10 RH: 50~60% 0.1 2 0 ~0.1
表2  近年来CO2输送管线腐蚀研究结果
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