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中国腐蚀与防护学报  2013, Vol. 33 Issue (4): 257-264    
  研究报告 本期目录 | 过刊浏览 |
晶粒尺寸对耐热钢在高温水蒸汽中的氧化行为的影响
袁军涛1 吴细毛2 王 文1 朱圣龙1 王福会1
1. 中国科学院金属研究所 金属腐蚀与防护国家重点实验室 沈阳 110016
2. 东北电力科学研究院有限公司 沈阳 110006
Effect of Grain Size on Oxidation of Heat-resistant Steels in High Temperature Water Steam
YUAN Juntao1, WU Ximao2, WANG Wen1, ZHU Shenglong1, WANG Fuhui1
1. State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016,China;
2. Northeast Electric Power Research Institute Co. Ltd., Shenyang 110006, China
全文: PDF(5842 KB)  
摘要: 

从氧化动力学、氧化膜相组成及微观结构方面,研究了晶粒尺寸对18Cr-8Ni耐热钢在700 ℃下的高温水蒸汽中氧化行为的影响。结果表明:晶粒细化提高了耐热钢的抗水蒸汽氧化性能,降低了其氧化增重,推迟了失稳氧化的发生;晶粒细化改变了耐热钢氧化膜的微观结构,减小了“弹坑”区的尺寸且促进了“弹坑”区与合金界面上富Cr氧化物层的形成;晶粒细化对耐热钢抗水蒸汽氧化性能的改善主要归因于其对氧化物的形核和Cr向氧化膜/合金界面扩散的促进作用。

关键词 晶粒尺寸耐热钢水蒸汽高温氧化    
Abstract

Effect of grain size on oxidation of 18Cr-8Ni heat-resistant steels in high temperature water steam was studied at 700 ℃. Oxidation kinetics was obtained by weighting specimens at intervals. After oxidation, all the samples were investigated using field emission scanning electron microscopy (FE-SEM) in terms of plain and cross section views, the chemical composition was analyzed by X-ray energy dispersive analysis (EDS), and the oxide phases were identified by X-ray diffraction (XRD). The results show that grain refinement improves the oxidation resistance of steels to high temperature water steam by lowering the mass gains and postponing the onset of breakaway oxidation; grain refinement alters the microstructure of oxide scale by reducing the size of “crater” oxide region and promoting the formation of Cr-rich layer at scale/alloy interface; the beneficial effects of grain size on oxidation of steels are ascribed to the promotion of oxide nucleation and Cr transport towards scale/alloy interface.

Key wordsgrain size    heat-resistant steel    water steam    high temperature oxidation
    
ZTFLH:  TG172  

引用本文:

袁军涛, 吴细毛, 王文, 朱圣龙, 王福会. 晶粒尺寸对耐热钢在高温水蒸汽中的氧化行为的影响[J]. 中国腐蚀与防护学报, 2013, 33(4): 257-264.
YUAN Juntao, WU Ximao, WANG Wen, ZHU Shenglong, WANG Fuhui. Effect of Grain Size on Oxidation of Heat-resistant Steels in High Temperature Water Steam. Journal of Chinese Society for Corrosion and protection, 2013, 33(4): 257-264.

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2013/V33/I4/257

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